硬质相成分对WC-TiC钢结硬质合金组织及力学性能的影响Effect of hard phase composition on microstructure and mechanical properties of WC-TiC steel bonded carbide
肖逸锋,周年丰,匡雯慧,吴靓,许艳飞,钱锦文,贺跃辉
摘要(Abstract):
以WC、TiC以及Fe粉为原料,通过改变WC-TiC钢结硬质合金的硬质相组成,研究合金组织及力学性能的变化特点。采用X射线衍射(XRD)、扫描电镜(SEM)和能量色散谱仪(EDS)等手段对制备的样品进行表征。结果表明,随着TiC/WC摩尔比值σ的增大,合金出现了明显的环形结构,晶粒先细化后粗化。TiC的添加降低了钢结硬质合金的密度和致密度,合金宏观硬度随σ值的增大而增大,当σ>1.2时,硬度值略有下降。合金的抗弯强度随σ值的增大呈先降低后升高再降低的趋势,当σ值在0.8~1.0范围时合金的综合力学性能最佳。
关键词(KeyWords): WC-TiC钢结硬质合金;摩尔比σ;环形结构;宏观硬度;抗弯强度
基金项目(Foundation): 国家自然科学基金(51271158);; 湖南省教育厅重点项目(17A204);; 湖南省重点研发计划项目(2015WK3021)
作者(Author): 肖逸锋,周年丰,匡雯慧,吴靓,许艳飞,钱锦文,贺跃辉
DOI: 10.13289/j.issn.1009-6264.2016-X249
参考文献(References):
- [1]张焱,尤显卿,田四光,等.钢结硬质合金的发展现状[J].热处理,2008,23(1):12-15.ZHANG Yan,YOU Xian-qing,TIAN Si-guang,et al.Development of steel boned carbide[J].Heat Treatment,2008,23(1):12-15.
- [2]Borgh I,Hedstr9m P,Borgenstam A,et al.Effect of carbon activity and powder particle size on WC grain coarsening during sintering of cemented carbides[J].International Journal of Refractory Metals&Hard Materials,2014,42(1):30-35.
- [3]Hans B,Birgit W.Development of an abrasion resistant steel composite with in situ Ti C particles[J].Wear,2001,51(1/2):1386-1395.
- [4]罗军明,魏峥,苏倩,等.Ti C含量对微波烧结钢结硬质合金组织及性能影响[J].材料热处理学报,2012,33(7):116-121.LUO Jun-ming,WEI Zheng,SU Qian,et al.Effect of content on microstructure and properties of Ti C steel-cemented carbides[J].Transactions of Materials and Heat Treatment,2012,33(7):116-121.
- [5]袁有录,李铸国.等离子熔覆WC-Ni/Fe梯度涂层的组织与性能[J].材料热处理学报,2012,33(11):131-136.YUAN You-lu,LI Zhu-guo.Microstructure and properties of WC-Ni/Fe grandient coating on Q235 steel formed by plasma cladding[J].Transactions of Materials and Heat Treatment,2012,33(11):131-136.
- [6]Lee K H,Cha S I,Kim B K,et al.Effect of WC/Ti C grain size ratio on microstructure and mechanical properties of WC-Ti C-Co cemented carbides[J].International Journal of Refractory Metals&Hard Materials,2006,24(1/2):109-114.
- [7]李重典,时凯华,王海霞,等.烧结工艺对WC-1.0Ti C-3.1Ta C-4.5Co硬质合金性能及微观组织的影响[J].材料工程,2016,44(12):74-79.LI Zhong-dian,SHI Kai-hua,WANG Hai-xia,et al.Effect of sintering process on properties and microstructure of WC-1.0Ti C-3.1Ta C-4.5Co cemented carbides[J].Journal of Materials Engineering,2016,44(12):74-79.
- [8]石丽秋,王晓灵,熊超伟.球磨时间对双晶结构的WC-Ti C-Co/Ni硬质合金组织及性能的影响[J].硬质合金,2016,32(3):155-163.SHI Li-qiu,WANG Xiao-ling XIONG Chao-wei.Effect of milling time on microstructure and properties of WC-Ti C-Co/Ni cemented carbide with dual grain structure[J].Cemented Carbide,2016,32(3):155-163.
- [9]Kwon H J,Suh C Y,Kim W.Microstructure and mechanical properties of(Ti,W)C-Ni cermetprepared using a nano-sized Ti C-WC powder mixture[J].Journal of Alloys and Compounds,2015,639:21-26.
- [10]王丽利,李海艳,刘宁.添加Ti C对WC-Co基硬质合金组织和力学性能的影响[J].热处理,2010,25(3):25-30.WANG Li-li,LI Hai-yang,LIU Ning.Effect of Ti C on microstructures and mechanical properties of WC-Co-based carbides[J].Heat Treatment,2010,25(3):25-30.
- [11]Akhtar F,Humail I S,Tian J J,et al.Effect of WC particle size on the microstructure,mechanical properties and fracture behavior of WC-(W,Ti,Ta)C-6 wt%Co cemented carbides[J].International Journal of Refractory Metals&Hard Materials,2007,25(5/6):405-410.
- [12]张端锋,江垚,吝楠,等.WC-Ti C-Ni硬质合金的制备与性能[J].粉末冶金材料科学与工程,2011,16(2):303-308.ZHANG Duan-feng,JIANG Yao,LIN Nan,et al.preparation and properties of WC-Ti C-Ni cemented carbides[J].Materials Science and Engineering of Powder Metallurgy,2011,16(2):303-308.
- [13]罗军明,魏峥,艾云龙,等.微波烧结温度对WC钢结硬质合金组织性能的影响[J].材料热处理学报,2011,32(7):31-36.LUO Jun-ming,WEI Zheng,AI Yun-long,et al.Effect of microwave sintering temperature on microstructure and properties of WC steel-bonded cemented carbide[J].Transactions of Materials and Heat Treatment,2011,32(7):31-36.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||