白鹏飞,任凤章,殷立涛,石如星,熊毅

• 1:河南科技大学材料科学与工程学院
• 2:中信重工机械股份有限公司铸锻厂

摘要(Abstract)：

中锰钢作为第三代先进高强钢的代表，由于其优异的力学性能已成为一个研究的热点。同一种中锰钢经过不同的轧制和热处理产生不同的微观组织进而导致其力学性能存在差异。因此，研究不同的热加工工艺下其微观组织与力学性能之间的关系至关重要。本文综述了中锰钢在热轧和冷轧退火工艺下的组织演变，重点阐述了微观组织与静拉伸力学性能、抗氢脆性能、低温冲击韧性之间关系方面的研究进展，并对提高中锰钢各种力学性能的方法进行了比较，最后对中锰钢未来的强韧性研究和发展方向进行了展望。

关键词(KeyWords)： 中锰钢;热轧退火;冷轧退火;微观组织

Abstract:

Keywords:

基金项目(Foundation): 河南省重大科技专项(221100230200)

作者(Author): 白鹏飞,任凤章,殷立涛,石如星,熊毅

DOI: 10.13289/j.issn.1009-6264.2023-0249

参考文献(References)：

• [1] Miller R L.Ultrafine-grained microstructures and mechanical properties of alloy steels[J].Metallurgical Transactions,1972,3(4):905-912.
• [2] Lee S,Shin S,Kwon M,et al.Tensile properties of medium Mn steel with a bimodal UFG α + γ and coarse δ-ferrite microstructure[J].Metallurgical & Materials Transactions A,2017,48(4):1678-1689.
• [3] Ma Y.Recent progresses in the study of microstructure and thermomechanical behavior of IP Ti-6Al-4V alloy[J].Materials Science and Technology,2017,33(14):1713-1719.
• [4] Cao W Q,Wang C,Shi J,et al.Microstructures and mechanical properties of high-strength medium-carbon low-alloy pearlitic steels with nanostructured bainitic ferrite[J].Materials Science and Engineering A,2011,528(18):6661-6669.
• [5] Han J.A critical review on medium-Mn steels:Mechanical properties governed by microstructural morphology[J].Steel Research International,2022,94:2200238.
• [6] Kim W S,Yoon J H,Kim J H,et al.Development of 1180 MPa ultra-high strength steel with excellent formability for automotive applications[J].Metals and Materials International,2019,25(1):179-191.
• [7] Lee S,Lee S J,Cooman B.Austenite stability of ultrafine-grained transformation-induced plasticity steel with Mn partitioning[J].Scripta Materialia,2011,65(3):225-228.
• [8] Wang J,Zwaag S V D.Stabilization mechanisms of retained austenite in transformation-induced plasticity steel[J].Metallurgical and Materials Transactions A,2001,32(6):1527-1539.
• [9] Soleimani M,Kalhor A,Mirzadeh H.Transformation-induced plasticity (TRIP) in advanced steels:A review[J].Materials Science and Engineering A,2020,795:140023.
• [10] Nakada N,Mizutani K,Tsuchiyama T,et al.The effect of a Ni addition on the hydrogen embrittlement behavior of a high-strength maraging steel[J].Acta Materialia,2014,65:251-262.
• [11] Calcagnotto M,Ponge D,Raabe D.Influence of grain size,morphology and crystallographic texture on the mechanical properties of ultrafine grained dual-phase steels[J].Metallurgical and Materials Transactions A,2012,43(1):37-45.
• [12] Cameron B C,Koyama M,Tasan C C.Phase stability effects on hydrogen embrittlement resistance in martensite-reverted austenite steels[J].Metallurgical and Materials Transactions A,2019,50(1):29-34.
• [13] Han J,Nam J H,Lee Y K.The mechanism of hydrogen embrittlement in intercritically annealed medium Mn TRIP steel[J].Acta Materialia,2016,113:1-10.
• [14] Hu B J,Zheng Q Y,Jia C N,et al.Improvement of mechanical properties of a medium-Mn TRIP Steel by precursor microstructure control[J].Acta Metallurgica Sinica (English Letters),2022,35(7):1068-1078.
• [15] Hu B J,Zheng C W,Zheng Q,et al.Ultra-fine heterogeneous microstructure enables high strength-ductility in a cold-rolled medium Mn steel[J].Acta Metallurgica Sinica (English Letters),2022,35(10):1712-1718.
• [16] Tokizane M,Matsumura N,Tsuzaki K,et al.Effect of preheating temperature on the tempering behavior of martensite in a low alloy steel[J].Metallurgical Transactions A,1982,13:1379-1386.
• [17] Han J,Lee S J,Jung J G,et al.The effects of the initial martensite microstructure on the microstructure and tensile properties of intercritically annealed Fe-9Mn-0.05C steel[J].Acta Materialia,2014,78:369-377.
• [18] 樊立峰，亢泽，张志朋，等.逆相变热处理时间对冷轧中锰钢组织和性能的影响[J].材料热处理学报，2022,43(6):110-119.FAN Li-feng,KANG Ze,ZHANG Zhi-peng,et al.Effect of reverse phase transformation heat treatment time on microstructure and properties of cold rolled medium manganese steel[J].Transactions of Materials and Heat Treatment,2022,43(6):110-119.
• [19] Wang T,Li Y,Li W,et al.Stress-induced martensitic transformation in a duplex stainless steel[J].Journal of Alloys and Compounds,2013,577:S654-S657.
• [20] Wang M M,Tasan C C,Ponge D,et al.Spectral TRIP enables ductile 1.1 GPa martensite[J].Acta Materialia,2016,111:262-272.
• [21] Park T M,Kim H J,Um H Y,et al.The possibility of enhanced hydrogen embrittlement resistance of medium-Mn steels by addition of micro-alloying elements[J].Materials Characterization,2020,165:110386.
• [22] Kwok T,Gong P,Rose R,et al.The relative contributions of TWIP and TRIP to strength in fine grained medium-Mn steels[J].Materials Science and Engineering A,2022,855:143864.
• [23] 胡斌，屠鑫，王玉，等.中锰钢塑性失稳现象的研究进展及未来研究展望[J].工程科学学报，2020,42(1):48-59.HU Bin,TU Xin,WANG Yu,et al.Recent progress and future research prospects on the plastic instability of medium-Mn steels:A review[J].Chinese Journal of Engineering,2020,42(1):48-59.
• [24] 邵成伟，惠卫军，张永健，等.一种新型高强度高塑性冷轧中锰钢的组织和力学性能[J].金属学报，2019,55(2):191-201.SHAO Cheng-wei,HUI Wei-jun,ZHANG Yong-jian,et al.Microstructure and mechanical properties of a novel cold rolled medium-Mn steel with superior strength and ductility[J].Acta Metallurgica Sinica,2019,55(2):191-201.
• [25] Cottrell A H,Bilby B A.Dislocation theory of yielding and strain ageing of iron[J].Proceedings of the Physical Society Section A,1949,62(1):49-62.
• [26] Han J,Kang S H,Lee S J,et al.Hydrogen evolution reaction on porous NiP electrode with various pore sizes[J].Journal of Alloys and Compounds,2016,681:580-586.
• [27] Sun B,Ma Y,Vanderesse N,et al.Macroscopic to nanoscopic in situ investigation on yielding mechanisms in ultrafine grained medium Mn steels:Role of the austenite-ferrite interface[J].Acta Materialia,2019,178:10-25.
• [28] Steineder K,Krizan D,Schneider R,et al.On the microstructural characteristics influencing the yielding behavior of ultra-fine grained medium-Mn steels[J].Acta Materialia,2017,139:39-50.
• [29] Yang Y G,Mu W Z,Li X Q,et al.Effects of strain rate on austenite stability and mechanical properties in a 5Mn steel[J].Journal of Iron and Steel Research International:English Edition,2022,29(2):316-326.
• [30] Sun B,Ma Y,Vanderesse N,et al.Macroscopic to nanoscopic in situ investigation on yielding mechanisms in ultrafine grained medium Mn steels:Role of the austenite-ferrite interface[J].Acta Materialia,2019,178:10-25.
• [31] Park T M,Jeong M S,Jung C,et al.Improved strength of a medium-Mn steel by V addition without sacrificing ductility[J].Materials Science and Engineering A,2021,802:140681.
• [32] Xu X D,Song H C,Li J H.Hydrogen-induced cracking susceptibility in a hot-rolled medium-manganese transformation-induced plasticity steel[J].Materials Science and Engineering A,2018,714:120-128.
• [33] 景财年，刘磊，林涛，等.高强韧中锰钢研究现状及发展趋势[J].上海金属，2023,45(2):1-10.JING Cai-nian,LIU Lei,LIN Tao,et al.Research status and development trend of high-strength and high-ductility medium manganese steel[J].Shanghai Metals,2023,45(2):1-10.
• [34] 徐娟萍.成分和组织调控对中锰钢力学行为和抗氢性能的影响[D].北京：北京科技大学，2022.XU Juan-ping.Effects of composition and microstructure adjusting on the mechanical behaviors and hydrogen embrittlement resistance properties of medium-Mn steels[D].Beijing:University of Science and Technology Beijing,2022.
• [35] Andresen P L.The role of microstructure in hydrogen embrittlement of steels[J].Materials Science and Engineering A,2002,336:206-214.
• [36] Han L,Li Z,Lin Y.Effect of cold rolling and annealing on microstructure and properties of Fe-Mn-C alloys[J].Journal of Materials Research,2019,34(8):1476-1486.
• [37] Shen X,Song W,Sevsek S,et al.Influence of microstructural morphology on hydrogen embrittlement in a medium-Mn steel Fe-12Mn-3Al-0.05C[J].Metals-Open Access Metallurgy Journal,2019,9(9):929.
• [38] Jeong I,Ryu K M,Lee D G,et al.Austenite morphology and resistance to hydrogen embrittlement in medium Mn transformation-induced plasticity steel[J].Scripta Materialia,2019,169:52-56.
• [39] Andresen P L.The role of microstructure in hydrogen embrittlement of steels[J].Materials Science and Engineering A,2002,336:206-214.
• [40] Wang M,Tasan C,Koyama M,et al.Transition from Intrinsic to extrinsic size effect in hexagonal close-packed metal micropillars[J].Metallurgical and Materials Transactions A,2015,46(8):3797-3806.
• [41] Cameron B C,Koyama M,Tasan C.Microstructure and texture evolution in high-purity magnesium during uniaxial compression and subsequent annealing[J].Metallurgical and Materials Transactions A,2019,50(1):29-42.
• [42] Li Y,Li W,Min N,et al.Homogeneous elasto-plastic deformation and improved strain compatibility between austenite and ferrite in a co-precipitation hardened medium Mn steel with enhanced hydrogen embrittlement resistance[J].International Journal of Plasticity,2020,133:102805.
• [43] Roberts M J.Effect of transformation substructure on the strength and toughness of Fe-Mn alloys[J].Metallurgical and Materials Transactions B,1970,1(12):3287-3294.
• [44] Edwards B C,Nasim M,Wilson E A.The nature of intergranular embrittlement in quenched Fe-Mn alloys[J].Scripta Metallurgica,1978,12(4):377-380.
• [45] Heo N H,Nam J W,Heo Y U,et al.Grain boundary embrittlement by Mn and eutectoid reaction in binary Fe-12Mn steel[J].Acta Materialia,2013,61(11):4022-4034.
• [46] Kwon K H,Yi I C,Ha Y,et al.Origin of intergranular fracture in martensitic 8Mn steel at cryogenic temperatures[J].Scripta Materialia,2013,69(5):420-423.
• [47] Jiang C,Ma Z,Chen G.Effect of heat treatment on low temperature toughness of low carbon bainitic steel[J].Materials Science and Engineering A,2014,620:21-26.
• [48] Ma N,Wang G,Li Z.An insight into the improvement of low-temperature toughness in a high strength low alloy steel[J].Materials Science and Engineering A,2016,654:63-72.
• [49] Liu Z,Li Y,Liu W,et al.Effect of microstructure on low-temperature toughness of a middle manganese steel[J].Materials Science and Engineering A,2017,693:1-10.
• [50] Hu J,Du L X,Sun G S,et al.Superior mechanical properties and deformation mechanisms of in situ nanoporous copper[J].Scripta Materialia,2015,104:87-90.
• [51] Hu J,Du L X,Sun G S,et al.The determining role of reversed austenite in enhancing toughness of a novel ultra-low carbon medium manganese high strength steel[J].Scripta Materialia,2015,104:87-90.
• [52] Han J,Silva A,Ponge D,et al.The effects of prior austenite grain boundaries and microstructural morphology on the impact toughness of intercritically annealed medium Mn steel[J].Acta Materialia,2017,122:199-206.
• [53] Kuzmina M,Ponge D,Raabe D.Grain boundary segregation engineering and austenite reversion turn embrittlement into toughness:Example of a 9 mass% medium Mn steel[J].Acta Materialia,2015,86:182-192.

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