固溶处理对Mg-Nd-Zn-Zr系合金生物腐蚀性能的影响Effects of solution treatment on biocorrosion properties of Mg-Nd-Zn-Zr magnesium alloy
程丹丹,文九巴,贺俊光,姚怀,梁明岗
摘要(Abstract):
采用扫描电子显微镜(SEM)、能谱分析(EDS)、X射线衍射(XRD)研究了固溶处理对Mg-2Nd-0.5Zn-0.4Zr和Mg-2Nd-0.5Zn-0.4Zr-3Y两种镁合金显微组织的影响,通过析氢、质量损失测试及电化学方法研究其在模拟体液(SBF)中的生物腐蚀性能;并对比分析了稀土Y的添加对镁合金组织及腐蚀性能的影响。结果表明:经过固溶处理后,合金的大部分析出相溶于基体,其在SBF中腐蚀速率仅为铸态合金的44.35%和46.67%;添加稀土Y使合金中析出相增多,出现新的块状析出相Mg24Y5,合金的耐生物腐蚀性能得到提高。
关键词(KeyWords): 固溶处理;稀土;生物镁合金;生物腐蚀性能
基金项目(Foundation): 河南省“新型有色金属材料”高校科技创新团队支持计划(2012IRTSTHN008);; 洛阳市科技攻关项目(1301001A)
作者(Author): 程丹丹,文九巴,贺俊光,姚怀,梁明岗
DOI: 10.13289/j.issn.1009-6264.2015.01.008
参考文献(References):
- [1]贺亚敏,申龙树,李慧,等.几种生物材料的体内生物相容性评价的实验研究[J].吉林医学,2010,31(14):83-85.HE Ya-min,SHEN Long-shu,LI Hui,et al.Study on in vivo biocompatibility of some materials[J].Jilin Medical Journal,2010,31(14):83-85.
- [2]章晓波,王章忠,袁广银.二次挤压对Mg-Nd-Zn-Zr生物镁合金组织与性能的影响[J].材料热处理学报,2013,34(2):103-107.ZHANG Xiao-bo,WANG Zhang-zhong,YUAN Guang-yin.Effects of double extrusion on microstructure and properties of Mg-Nd-Zn-Zr bio-magnesium alloy[J].Transactions of Materials and Heat Treatment,2013,34(2):103-107.
- [3]隋文渊.镁铝合金及其涂层的生物相容性实验研究[D].南方医科大学,2012.SUI Wen-yuan.Biocompatibility evaluation of magnalium with or without coating in vivo[D].Southern Medical University,2012.
- [4]WEN L,JI Z,LI X.Effect of extrusion ratio on microstructure and mechanical properties of Mg-Nd-Zn-Zr alloys prepared by a solid recycling process[J].Materials Characterization,2008,59(11):1655-1660.
- [5]白雪松,杜鹃,宋春梅.铝与人体健康的研究进展[J].吉林医药学院学报,2008,29(6):355-357.BAI Xue-song,DU Juan,SONG Chun-mei.Progress on effect of Alum inum on human health[J].Journal of Jilin Medical College,2008,29(6):355-357.
- [6]ZHANG X,YUAN G,MAO L,et al.Biocorrosion properties of as-extruded Mg-Nd-Zn-Zr alloy compared with commercial AZ31 and WE43 alloys[J].Materials Letters,2012,66(1):209-211.
- [7]Ng W F,Chiu K Y,Cheng F T.Effect of p H on the vitro corrosion rate of magnesium degradable implant material[J].Materials Science and Engineering C,2010,30(6):898-903.
- [8]刘正,张奎,曾小勤.镁基轻质合金理论基础及其应用[M].机械工业出版社,2002.
- [9]王伟.新型Mg-Zn-RE系高强高韧镁合金的开发[D].兰州理工大学,2008.WANG Wei.Research and development of a new Mg-Zn-RE alloy with high strength and high toughness[D].Lanzhou University of Technology,2008.
- [10]张佳,宗阳,袁广银,等.新型医用Mg-Nd-Zn-Zr镁合金在模拟体液中的降解行为[J].中国有色金属学报,2010,20(10):1989-1997.ZHAGN Jia,ZONG Yang,YUAN Guang-yin,et al.Degradable behavior of new-type medical Mg-Nd-Zn-Zr magnesium alloy in simulated body fluid[J].The Chinese Journal of Nonferrous Metals,2010,20(10):1989-1997.
- [11]丁文江,向亚贞,常建卫,等.Mg-Al系和Mg-Re系合金在Na Cl溶液中的腐蚀电化学行为[J].中国有色金属学报,2009,19(10):1713-1719.DING Wen-jiang,XIANG Ya-zhen,CHANG Jian-wei,et al.Corrosion and electrochemical behaviour of Mg-Al alloys and Mg-RE alloys in Na Cl solution[J].The Chinese Journal of Nonferrous Metals,2009,19(10):1713-1719.
- [12]章晓波,袁广银,王章忠.铸造镁合金Mg-Nd-Zn-Zr的生物腐蚀性能[J].中国有色金属学报,2013(4):905-911.ZHANG Xiao-bo,YUAN Guang-yin,WANG Zhang-zhong.Biocorrosion properties of as-cast Mg-Nd-Zn-Zr magnesium alloy[J].The Chinese Journal of Nonferrous Metals,2013(4):905-911.
- [13]HUANG R,CHEN M A,LU X B.Chemical oxidative polymerization of polypyrrole and its corrosion resistance on the AZ31 magnesium alloy[J].Acta Physico-Chimica Sinica,2011,27(1):113-119.
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