Ca元素对Zn-1.5Cu-1.2Mg锌合金组织与性能的影响Effect of Ca element content on microstructure and properties of Zn-1.5Cu-1.2Mg zinc alloy
张宇轩,王红星,白允强,顾沈逸,王文鑫,徐道翔,史艳慈,周涛,皮峰瑜
摘要(Abstract):
采用金属型铸造法制备了Zn-1.5Cu-1.2Mg-xCa(x=0、0.1、0.25和0.5, mass%)锌合金,研究了Ca元素添加量对其微观组织、力学性能和耐腐蚀性能的影响。结果表明:未添加Ca时,合金的初生相为η-Zn,强化相为Mg_2Zn_(11)。随着Ca添加量的增加,合金组织中的Mg_2Zn_(11)相和Ca的化合物增加,粗大的枝晶细化,并出现了新相。随着Ca添加量的增加,合金的显微硬度增加,而拉伸强度呈先下降后升高的趋势。添加0.5 mass%Ca时,合金的硬度达到最大,为203 HV,未添加Ca时,合金的拉伸强度达到最大,为199 MPa。当Ca添加量达0.1 mass%时,合金的耐腐蚀性能最佳,腐蚀速率为92.1μm/y。
关键词(KeyWords): 锌合金;微观组织;力学性能;耐腐蚀性能
基金项目(Foundation): 江苏省大学生创新创业训练项目(202311276153H);; 江苏高校优秀科技创新团队
作者(Author): 张宇轩,王红星,白允强,顾沈逸,王文鑫,徐道翔,史艳慈,周涛,皮峰瑜
DOI: 10.13289/j.issn.1009-6264.2023-0588
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