彭寿,操芳芳,金良茂,汤永康,王东,王魏巍,单传丽,倪嘉

• 1:蚌埠玻璃工业设计研究院
• 2:浮法玻璃新技术国家重点实验室

摘要(Abstract)：

采用简单高效的一步多元醇法以FeCl_3·6H_2O为成核控制剂,在低温、静置的条件下成功合成了产量高、形貌尺寸均匀、银线平均长度80~110μm、平均直径为40~80 nm,长径比大于1000的高长径比Ag纳米线。将制得银纳米线通过无水乙醇分散,得到一系列质量体积浓度的银线分散液,利用旋涂装置在PET上制备成膜,得到薄膜方阻仅6Ω/sq、可见光透过率80%左右性能良好的银纳米线透明导电薄膜,并探讨了旋涂层数、旋涂速度对各质量体积浓度薄膜性能的影响。

关键词(KeyWords)： 银纳米线;透明导电膜;高长径比;方块电阻;旋涂

Abstract:

Keywords:

基金项目(Foundation): 安徽省自然科学基金(1408085MKL67,1408085MKL66);; 安徽省科技攻关计划项目(1501021046);; 安徽省科技重大专项计划项目(15czz02004)

作者(Author): 彭寿,操芳芳,金良茂,汤永康,王东,王魏巍,单传丽,倪嘉

DOI: 10.13289/j.issn.1009-6264.2016-X277

参考文献(References)：

• [1]Hecht D S,Hu L,Irvin G.Emerging transparent electrodes based on thin films of carbon nanotubes,graphene,and metallic nanostructures[J].Advanced Materials,2011,23(13),1482-1513.
• [2]Leem D S,Edwards A,Faist M,et al.Efficient organic solar cells with solution-processed silver nanowire electrodes[J].Advanced Materials,2011,23(38),4371-4375.
• [3]De S,Higgins T M,Lyons P E,et al.Silver nanowire networks as flexible,transparent,conducting films:extremely high DC to optical conductivity ratios[J].ACS Nano,2009,3(7),1767-1774.
• [4]Hu L B,Kim H S,Lee J Y,et al.Scalable coating and properties of transparent,flexible,silver nanowire electrodes[J].ACS Nano,2010,4(5),2955-2963.
• [5]Mutiso R M,Sherrott M C,Rathmell A R,et al.Integrating simulations and experiments to predict sheet resistance and optical transmittance in nanowire films for transparent conductors[J].ACS Nano,2013,7(9),7654-7663.
• [6]Sorel S,Lyons P E,De S,et al.The dependence of the optoelectrical properties of silver nanowire networks on nanowire length and diameter[J].Nanotechnology,2012,23,(18):185201-185704.
• [7]Bergin S M,Chen Y H,Rathmell A R,et al.The effect of nanowire length and diameter on the properties of transparent,conducting nanowire films[J].Nanoscale,2012,4:1996-2004.
• [8]Yang T L,Pan C T,Chen Y C,et al.Synthesis and fabrication of silver nanowires embedded in PVP fibers by near-field electrospinning process[J].Optical Materials,2015,39:118-124.
• [9]Yang W L,Li J J,Zhong Y J.Facile Cl-mediated hydrothermal synthesis of large-scale Ag nanowires from Ag Cl hydrosol[J].Cryst Eng Comm,2013,15:2598-2600.
• [10]Pourahmad A,Sohrabnezhad S H.Preparation and characterization of Ag nanowires in mesoporous MCM-41 nanoparticles template by chemical reduction method[J].Journal of Alloys and Compounds,2009,484(1/2):314-316.
• [11]Kumar D,Kavita,Singh K,et al.Microwave-assisted synthesis and characterization of silver nanowires by polyol process[J].Applied Nanoscience,2015,5(7):881-890.
• [12]Riveros G,Green S,Cortes A,et al.Silver nanowire arrays electrochemically grown into nanoporous anodic alumina templates[J].Nanotechnology,2006,17(2):561-570.
• [13]Madaria A R,Kumar A,Ishikawa F N,et al.Uniform,highly conductive,and patterned transparent films of a percolating silver nanowire network on rigid and flexible substrates using a dry transfer technique[J].Nano Research,2010,3(8):564-573.
• [14]Lee J Y,Connor S T,Cui Y,et al.Semitransparent organic photovoltaic cells with laminated top electrode[J].Nano Letters,2010,10(4):1276-1279.
• [15]Lee J Y,Connor S T,Cui Y,et al.Solution-processed metal nanowire mesh transparent electrodes[J].Nano Letters,2008,8(2):689-692.
• [16]Scardaci V,Coull R,Lyons P E,et al.Spray deposition of highly transparent,low-resistance networks of silver nanowires over large areas[J].Small,2011,7:2621-2628.
• [17]Sun Y G,Yin Y D,Mayers B T,et al.Uniform silver nanowires synthesis by reducing Ag NO3 with ethylene glycol in the presence of seeds and poly(vinyl pyrrolidone)[J].Chemistry of Matericals,2002,14(11):4736-4745.
• [18]Chen D P,Qiao X L,Qiu X L,et al.Large-scale synthesis of silver nanowires via a solvothermal method[J].Journal of Materials Science:Materials in Electronics,2011,22(1):6-13.
• [19]Lupu N.Nanowires Science and Technology[M].Vukovar,Croatia:In Tech,c.2010:25-41.

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