王博,孙淑华,郭明伟,时钟平,王振华,傅万堂

• 1:燕山大学亚稳材料制备技术与科学国家重点实验室
• 2:中国第一重型机械集团公司
• 3:燕山大学机械工程学院

摘要(Abstract)：

从固溶渗氮的理论、工艺与技术的发展及应用等几个方面,综述了不锈钢固溶渗氮工艺与技术的研究进展及应用现状,并讨论了该项技术今后的发展趋势。

关键词(KeyWords)： 不锈钢;固溶渗氮;工艺与技术;研究进展

Abstract:

Keywords:

基金项目(Foundation): 河北省杰出青年科学基金(E2011203131);; 国家自然科学基金(51171161)

作者(Author): 王博,孙淑华,郭明伟,时钟平,王振华,傅万堂

DOI: 10.13289/j.issn.1009-6264.2014.06.001

参考文献(References)：

• [1]Berns H,Siebert S.High nitrogen austenitic cases in stainless steels[J].ISIJ International,1996,36(7):927-931.
• [2]Lee H W,Kong J H,Lee D J,et al.A study on high temperature gas nitriding and tempering heat treatment in 17Cr-1Ni-0.5C[J].Materials Design,2009,30(5):1691-1696.
• [3]Berns H.Manufacture and application of high nitrogen steels[J].ISIJ International,1996,36(7):904-909.
• [4]Berns H.Advantages in solution nitrding of stainless steels[J].Metal Science and Heat Treatment,2007,49(12):578-580.
• [5]Berns H,Edenhofer B,Zaugg R.Industrial experience with case hardening of stainless steels by solution nitriding[J].Transactions of Materials and Heat Treatment,2004,25(5):354-359.
• [6]Berns H.Stainless steels suited for solution nitriding[J].Mat-wiss U Werkstofftech,2002,33(1):5-11.
• [7]Berns H,Bouwman J W,Eul U,et al.Solution nitriding of stainless steels for process engineering[J].Mat-wiss U Werkstofftech,2000,31(2):152-161.
• [8]Gazon C M,Tschiptschin A P.New high temperature gas nitriding cycle that enhances the wear resistance of duplex stainless steels[J].Journal of Mater Science,2004,39(23):7101-7105.
• [9]Nakada N,Hirakawa N,Tsuchiyama T,et al.Grain refinement of nickel-free high nitrogen austenitic stainless steel by reversion of eutectoid structure[J].Scripta Materialia,2007,57(2):153-156.
• [10]傅万堂,王博,时钟平,等.一种奥氏体不锈钢分段式加压固溶渗氮催渗方法:中国,CN103088283[P].2013-05-08.
• [11]Tschiptschin A P.Predicting microstructure development during high temperature nitriding of martensitic stainless steels using thermodynamic modeling[J].Materials Research,2002,5(3):257-262.
• [12]Gazon C M,Toro A,Tschiptschin A P.Microstructure and chemical characterization of high temperature nitrided12%Cr stainless steels.Trans Indians Inst Met,2002,55(4):255-263.
• [13]Gazon C M,Tschiptschin A P.Growth kinetics of martensitic layer during high temperature gas nitriding of a ferritic-martensitic stainless steel[J].Materials Science and Technology,2004,20(7):915-918.
• [14]Berns H,Pyzalla A.Microstructure and residual stresses of stainless steels case hardened with nitrogen[J].Surface Engineering,2004,20(6):459-463.
• [15]Gazon C M,Tschiptschin A P.EBSD texture analysis of a high temperature gas nitrided duplex stainless steel[J].Materials Science and Engineering A,2006,411(1-2):230-238.
• [16]Tsuchiyama T,Takebe H,Tsuboi K,et al.Surface-layer microstructure control for metastable austenitic stainless steel to prevent hydrogen permeation[J].Scripta Materialia,2010,62(10):731-734.
• [17]Kuroda D,Hanawa T,Hibaru T,et al.Mechanical properties and microstructures of a thin plate of nickel-free stainless steel with nitrogen absorption treatment[J].Materials Transactions,2003,44(7):1363-1369.
• [18]Kuroda D,Hanawa T,Hibaru T,et al.Mechanical properties of thin wires of nickel-free austenitic stainless steel with nitrogen absorption treatment[J].Materials Transactions,2003,44(8):1577-1582.
• [19]Kuroda D,Hanawa T,Hibaru T,et al.Torsion and tensile properties of thin wires of nickel-free stainless steel with nitrogen absorption treatment[J].Materials Transactions,2004,45(1):112-118.
• [20]Nakanishi T,Tsuchiyama T,Mitsuyasu H,et al.Effect of partial solution nitriding on mechanical properties and corrosion resistance in a type 316L austenitic stainless plate[J].Materials Science and Engineering A,2007,460-461(15):186-194.
• [21]Tsuchiyama T,Fujll Y,Terazawa Y,et al.Factors inducing intergranular fracture in nickel-free high nitrogen austenitic stainless steel produced by solution nitriding[J].ISIJ International,2008,48(6):861-867.
• [22]Onomoto T,Terazawa Y,Tsuchiyama T,et al.Effects of grain refinement on tensile properties in Fe-25Cr-1N alloy[J].ISIJ International,2009,49(8):1246-1252.
• [23]Tsubol K,Tsuchiyama T,Takaki S,et al.Mechanical properties of strength-gradient steel sheets produced by solution nitriding[J].ISIJ International,2012,52(10):1872-1878.
• [24]Sung J H,Joo D W,Kim I N,et al.Phase changes of Fe-20Mn-13Cr-3Co/1.2Ti alloys during solution nitriding[J].Metals and Materials,2005,11(2):157-163.
• [25]Sung J H,Kong J H,Yoo D K,et al.Phase changes of the AISI430 ferritic stainless steels after high-temperature gas nitriding and tempering heat treatment[J].Materials Science and Engineering A,2008,489(1-2):38-43.
• [26]Berns H,Eul U,Heitz E,et al.Corrosion behaviour of solution nitrided stainless steels[J].Materials Science Forum Vols,1999,318-320:517-522.
• [27]Eckstein C,Spies H J,Albercht J.Improvement of the corrosion resistance of high alloyed austenitic Cr-Ni-Mo stainless steels by solution nitriding[J].Transactions of Materials and Heat Treatment,2004,25(5):316-321.
• [28]Suyitno A S,Soekrisno R,Dharmastiti R.Corrosion resistance of AISI 316L after short holding time of high temperature gas nitriding(HTGN)[J].Chemistry and Materials Research,2013,3(2):1-8.
• [29]Paul G,Kpodo H C,Hendry A.Effect of enhancement in surface nitrogen concentration on corrosion and fatigue properties of austenitic steel wire rod[J].ISIJ International,1996,36(7):867-872.
• [30]Santos J F,Garzón C M,Tschiptschin A P.Improvement of the cavitation erosion resistance of an AISI 304L austenitics stainless steel by high temperature gas nitriding[J].Materials Science and Engineering A,2004,382(1-2):378-386.
• [31]Garzon C M,Thomas H,Santos J F,et al.Cavitation erosion resistance of a high temperature gas nitrided duplex stainless steel in substitute ocean water[J].Wear,2005,259(1-6):145-153.
• [32]Mesa D H,Garzón C M,Tschiptschin A P.Influence of cold-work on the cavitation erosion resistance and on the damage mechanisms in high-nitrogen austenitic stainless steels[J].Wear,2011,271(9-10):1372-1377.
• [33]Tschiptschin A P,Garzón C M,Lopez D M.The effect of nitrogen on the scratch resistance of austenitic stainless steels[J].Tribology International,2006,39(2):167-174.
• [34]Berns H,Kühl A.Reduction in wear of sewage pump through solution nitriding[J].Wear,2004,256(1-2):16-20.
• [35]López D,Falleiros N A,Tschiptschin A P.Effect of nitrogen on the corrosion-erosion synergism in an austenitic stainless steel[J].Tribology International,2011,44(5):610-616.
• [36]Toro A,Sinatora A,Tanaka D K,et al.Corrosion-erosioin of nitrogen bearing martensitic stainless steels in seawater-quartz slurry[J].Wear,2001,251(1-12):1257-1264.
• [37]Mesa D H,Toro A,Sinatora A,et al.The effect of testing temperature on corrosion-erosion resistance of martensitic stainless steels[J].Wear,2003,255(1-6):139-145.
• [38]Tsuchiyama T,Takaki S,Ito H,et al.Fabrication of ultra high nitrogen austenitic steels by nitrogen gas absorption into solid solution[J].Metall Mater Trans,2003(34A):2591-2599.
• [39]Kuroda D,Hanawa T,Hibaru T,et al.New manufacturing process of nickel-free austenitic stainless steel with nitrogen absorption treatment[J].Materials Transactions,2003,44(3):414-420.
• [40]Park W L,Jung S M,Sasaki Y.Fabrication of ultra high nitrogen austenitic stainless steel by NH3solution nitriding[J].ISIJ International,2010,50(11):1546-1551.
• [41]Tsuchiyama T,Fukumaru T,Egashira M,et al.Calculation of nitrogen absorption into austenitic stainless steel plate and wire[J].ISIJ International,2004,44(6):1121-1123.
• [42]李光强,张峰,朱诚意.1473K,0.1MPa氮气氛中Fe-Cr-Mn系不锈钢的固态渗氮[J].武汉科技大学学报,2005,28(2):115-118.LI Guang-qiang,ZHANG Feng,ZHU Cheng-yi.Solid state nitriding of Fe-Cr-Mn stainless steel in 0.1 MPa nitrogen atmosphere at 1473 K[J].Journal of Wuhan University of Science Technology,2005,28(2):115
• [43]Fu R D,Zhao P,Wang C Y,et al.Solid solution nitriding technology of 15Cr7.5Mn2.6Mo duplex stainless steel[J].Transactions of Materials and Heat Treatment,2004,25(5):417-421.
• [44]Gavriljuk V,Berns H.High nitrogen steels[M].Berlin:Spreinger,1999.
• [45]Yoo D K,Lee H J,Kang C Y,et al.A study on nitrogen permeation and tempering heat treatment of AISI type 409L ferritic stainless steel[J].Solid State Phenomena,2006,118:149-154.
• [46]王松涛.高氮奥氏体不锈钢的力学行为及氮的作用机理[D].沈阳:中国科学院理化技术研究所,2008.
• [47]汉斯·伯恩.不锈钢中形成高强度奥氏体表面层的表面渗氮方法:中国,CN1107187A[P].1995-8-23.
• [48]Mesa D H,Pinedo C E,Tschiptschin A P.Improvement of the cavitation erosion resistance of UNS S31803 stainless steel by duplex treatment[J].Surface Coating Technology,2010,205(5):1552-1556.
• [49]Ma S H,Chu S J,Zhang Z M,et al.Principle and practice of high nitrogen steel melting by blowing ammonia gas[J].Journal of Iron and Steel Research,International,2010,17(2):6-9.
• [50]Mitsui H,Kurihana S.Solution nitriding treatment of Fe-Cr alloys under pressurized nitrogen gas[J].ISIJ International,2007,47(3):479-485.
• [51]王延来,刘世程,刘德义,等.304奥氏体不锈钢固溶渗氮的研究[J].金属热处理,2005,30(5):8-11.WANG Yan-lai,LIU Shi-cheng,LIU De-yi,et al.Solid solution nitriding of 304 austenitic stainless steel[J].Heat Treatment of Metals,2005;30(5):8-11.
• [52]傅万堂,王博,赵品,等.一种具有双压平衡结构的增压高温渗氮装置:中国,CN103045990A[P].2013-4-17.
• [53]Ando T,Nakashima K,Tsuchiyama T,et al.Microstructure and mechanical properties of a high nitrogen titanium alloy[J].Materials Science and Engineering A,2008,486(1-2):228-234.

文章评论(Comment)：