有机官能团离子注入对ZK60镁合金力学性能和耐蚀性的影响Effect of organic functional groups ion implantation on mechanical properties and corrosion resistance of ZK60 magnesium alloy
韦仙,冯中营,杨文锦
摘要(Abstract):
生物可降解镁合金因其优异的生物性能和力学性能,在医学领域表现出巨大的应用潜力。然而,过快的腐蚀速率阻碍了其临床应用。采用有机官能团(羟基(OH~-)和羧基(COOH~+))离子注入对ZK60镁合金进行表面改性,采用X射线光电子能谱(XPS)技术、纳米压痕仪和电化学腐蚀试验等研究了离子注入对ZK60合金的表面结构、力学性能和耐蚀性的影响,并使用等效电路对电化学阻抗谱(EIS)进行拟合,进一步探讨其腐蚀机理。结果表明:羟基和羧基离子注入后,在ZK60镁合金表面分别形成了富含各种化合物的改性层,致使其力学性能和耐蚀性均得到显著增强,此外,羧基注入的试样在力学性能和耐蚀性方面优于羟基注入的试样。
关键词(KeyWords): ZK60镁合金;耐蚀性;有机官能团离子注入;力学性能
基金项目(Foundation): 山西省高校科技创新项目(2021L540);; 太原工业学院青年(后备)学科带头人支持计划;; 山西省基础研究计划青年科学研究项目(20210302124264)
作者(Author): 韦仙,冯中营,杨文锦
DOI: 10.13289/j.issn.1009-6264.2021-0499
参考文献(References):
- [1] Witte F,Hort N,Vogt C,et al.Degradable biomaterials based on magnesium corrosion[J].Current Opinion in Solid State and Materials Science,2009,12(5):63-72.
- [2] Moravej M,Mantovani D.Biodegradable metals for cardiovascular stent application:interests and new opportunities[J].International Journal of Molecular Sciences,2011,12(7):4250-4270.
- [3] Hornberger H,Virtanen S,Boccaccini A R.Biomedical coatings on magnesium alloys-A review[J].Acta Biomaterialia,2012,8(7):2442-2455.
- [4] Nagels J,Stokdijk M,Rozing P M.Stress shielding and bone resorption in shoulder arthroplasty[J].Journal of Shoulder and Elbow Surgery,2003,12(1):35-39.
- [5] Jamesh M,Kumar S,Narayanan T S.Corrosion behavior of commercially pure Mg and ZM21 Mg alloy in Ringer’s solution-long term evaluation by EIS[J].Corrosion Science,2010,53(2):645-654.
- [6] Staiger M P,Pietak A M,Huadmai J,et al.Magnesium and its alloys as orthopedic biomaterials:A review[J].Biomaterials,2006,27(9):1728-1734.
- [7] Catt K,Li H,Cui X T.Poly (3,4-ethylenedioxythiophene) graphene oxide composite coatings for controlling magnesium implant corrosion[J].Acta Biomaterialia,2017,48:530-540.
- [8] Zou J,Liu B,Lin L,et al.Investigation of microstructure and properties of ultrathin graded ZrNx self-assembled diffusion barrier in deep nano-vias prepared by plasma ion immersion implantation[J].Applied Surface Science,2018,427:950-955.
- [9] Lin Z,Zhao Y,Chu P K,et al.A functionalized TiO2/Mg2TiO4 nano-layer on biodegradable magnesium implant enables superior bone-implant integration and bacterial disinfection[J].Biomaterials,2019,219:119372.
- [10] Jin W,Wu G,Feng H,et al.Improvement of corrosion resistance and biocompatibility of rare-earth WE43 magnesium alloy by neodymium self-ion implantation[J].Corrosion Science,2015,94:142-155.
- [11] Xu R,Yang X,Li P,et al.Eelectrochemical properties and corrosion resistance of carbon-ion implanted magnesium[J].Corrosion Science,2014,82:173-179.
- [12] Hou T,Zhang J,Kong L,et al.Morphologies of fibroblast cells cultured on surfaces of PHB films implanted by hydroxyl ions[J].Journal of Biomaterials Science,Polymer Edition,2006,17(7):735-746.
- [13] Li D,Niu L.Cell attachment of polypropylene surface-modified by COOH+ ion implantation[J].Nuclear Instruments and Methods in Physics Research Section B:Beam Interactions with Materials and Atoms,2002,192(4):393-401.
- [14] Zhang Y,Li M,Zhao M,et al.Influence of polar functional groups introduced by COOH+ implantation on cell growth and anticoagulation of MWCNTs[J].Journal of Materials Chemistry B,2013,1(41):5543-5549.
- [15] Gu X N,Zheng Y F,Chen L J.Influence of artificial biological fluid composition on the biocorrosion of potential orthopedic Mg-Ca,AZ31,AZ91 alloys[J].Biomedical Materials,2009,4(6):065011.
- [16] Pobedinskas P,Degutis G,Dexters W,et al.Nanodiamond seeding on plasma-treated tantalum thin films and the role of surface contamination[J].Applied Surface Science,2021,538:148016.
- [17] He X,Li X,Wang J,et al.From diverse polycyclic aromatic molecules to interconnected graphene nanocapsules for supercapacitors[J].Microporous and Mesoporous Materials,2017,245:73-81.
- [18] Aksoy S,Caglar Y,Ilican S,et al.Sol-gel derived Li-Mg co-doped ZnO films:preparation and characterization via XRD,XPS,FESEM[J].Journal of Alloys and Compounds,2012,512(1):171-178.
- [19] Diler E,Lescop B,Rioual S,et al.Initial formation of corrosion products on pure zinc and MgZn2 examinated by XPS[J].Corrosion Science,2014,79:83-88.
- [20] Jung J I,Edwards D D.X-ray photoelectron study on Ba0.5Sr0.5CoxFe1-xO3-δ (BSCF:x=0.2 and 0.8) ceramics annealed at different temperature and pO2[J].Journal of Materials Science,2011,46(23):7415-7422.
- [21] Chen J,Song Y,Shan D,et al.In situ growth process of Mg-Al hydrotalcite conversion film on AZ31 Mg alloy[J].Journal of Materials Science and Technology,2015,31(4):384-390.
- [22] D'Angelo D,Bongiorno C,Amato M,et al.Electron energy-loss spectra of graphene oxide for the determination of oxygen functionalities[J].Carbon,2015,93:1034-1041.
- [23] Ni M,Ratner B D.Differentiating calcium carbonate polymorphs by surface analysis techniques-an XPS and TOF-SIMS study[J].Surface and Interface Analysis,2008,40(10):1356-1361.
- [24] Long Y,Wu L,Pan F,et al.A graphene spin coatings for cost-effective corrosion protection for the magnesium alloy AZ31[J].Journal of Nanoscience and Nanotechnology,2019,19(1):105-111.
- [25] Cáceres D,Vergara I,González R,et al.Hardness and elastic modulus from nanoindentations in nominally pure and doped MgO single crystals[J].Philosophical Magazine A,2002,82(6):1159-1171.
- [26] 刘洪喜,孟春蕾,林波,等.氮钛双离子注入AZ31镁合金的抗腐蚀和力学性能[J].材料热处理学报,2011,32(8):137-142.LIU Hong-xi,MENG Chun-lei,LIN Bo,et al.Corrosion resistance and mechanical property of AZ31 magnesium alloy by N/Ti duplex ion implantation[J].Transactions of Materials and Heat Treatment,2011,32(8):137-142.
- [27] 周必元,郏永强,宋浩,等.Zr离子注入对镁合金表面耐磨耐蚀性能的影响[J].材料热处理学报,2019,40(10):135-142.ZHOU Bi-yuan,JIA Yong-qiang,SONG Hao,et al.Effect of Zr ion implantation on wear resistance and corrosion resistance of magnesium alloy[J].Transactions of Materials and Heat Treatment,2019,40(10):135-142.
- [28] 刘亚,文九巴,李欢,等.Y含量对Mg-Zn-Gd-Y-Zr生物镁合金组织及性能的影响[J].材料热处理学报,2021,42(10):49-55.LIU Ya,WEN Jiu-ba,LI Huan,et al.Effect of Y content on microstructure and properties of Mg-Zn-Gd-Y-Zr biological magnesium alloy[J].Transactions of Materials and Heat Treatment,2021,42(10):49-55.
- [29] Zhang Z Q,Wang L,Zeng M Q,et al.Biodegradation behavior of micro-arc oxidation coating on magnesium alloy-from a protein perspective[J].Bioactive Materials,2020,5(2):398-409.
- [30] 曹楚南,张鉴清.电化学阻抗谱导论[M].北京:科学出版社,2002.
- [31] Park J H,Lee G D,Nishikata A,et al.Anticorrosive behavior of hydroxyapatite as an environmentally friendly pigment[J].Corrosion Science,2002,44(5):1087-1095.
- [32] Chen Y,Wang X H,Li J,et al.Long-term anticorrosion behaviour of polyaniline on mild steel[J].Corrosion Science,2007,49(7):3052-3063.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||