王晋杰,张文达,陈民涛,白韶斌,赵超,陆海涛,韩涛

• 1:中北大学材料科学与工程学院
• 2:太原重工股份有限公司

摘要(Abstract)：

在“碳达峰”、“碳中和”成为全社会共识的背景下，轻质耐磨高锰钢因具有良好的强韧性、耐磨性以及较低的密度在冶金、矿山等行业中具有广阔应用前景。本文综述了轻质耐磨高锰钢的成分轻量化设计进展，以及基体组织、析出相以及表面改性对其耐磨性能影响，并展望了轻质耐磨高锰钢未来的发展趋势，以期为高锰钢轻量化及耐磨性能的协同提升设计提供参考。

关键词(KeyWords)： 轻质高锰钢;κ-碳化物;耐磨性能

Abstract:

Keywords:

基金项目(Foundation): 2022年度太原重型机械集团有限公司科技计划“揭榜挂帅”项目(2310300045HX)

作者(Author): 王晋杰,张文达,陈民涛,白韶斌,赵超,陆海涛,韩涛

参考文献(References)：

• [1] 杨小禹，李笑笑，徐长静.高压时效处理对耐磨高锰钢组织与力学性能的影响[J].热加工工艺，2022,51(22):134-136.YANG Xiao-yu,LI Xiao-xiao,XU Chang-jing.Effects of high pressure aging treatment on microstructure and mechanical properties of wear-resistant high manganese steel[J].Hot Working Technology,2022,51(22):134-136.
• [2] 张飘，庄文玮，刘汉代.高锰钢磨损及变质处理技术研究概况[J].机电工程技术，2021,7:9-11.ZHANG Piao,ZHUANG Wen-wei,LIU Han-dai.Research on wear and deterioration treatment of high manganese steel[J].M&E Engineering Technology,2021,7:9-11.
• [3] 杨壹，郑志斌，叶志国，等.轻质高锰钢的组织及力学性能[J].钢铁研究学报，2021,33(11):1189-1197.YANG Yi,ZHENG Zhi-bin,YE Zhi-guo,et al.Microstructure and mechanical properties of light weight high manganese steel[J].Journal of Iron and Steel Research,2021,33(11):1189-1197.
• [4] Huang Z,Jiang Y,Hou A,et al.Rietveld refinement,microstructure and high-temperature oxidation characteristics of low-density high manganese steels[J].Journal of Materials Science & Technology,2017,33(12):1531-1539.
• [5] 王金明，万响亮，王红鸿，等.冷变形对高锰奥氏体钢组织以及力学性能的影响[J].材料热处理学报，2019,40(9):100-106.WANG Jin-ming,WAN Xiang-liang,WANG Hong-hong,et al.Effect of cold deformation on microstructure and mechanical properties of high manganese austenite steel[J].Transactions of Materials and Heat Treatment,2019,40(9):100-106.
• [6] Song H,Yoo J,Kim S H,et al.Novel ultra-high-strength Cu-containing medium-Mn duplex lightweight steels[J].Acta Materialia,2017,135:215-225.
• [7] Moon J,Park S J,Jang J H,et al.Investigations of the microstructure evolution and tensile deformation behavior of austenitic Fe-Mn-Al-C lightweight steels and the effect of Mo addition[J].Acta Materialia,2018,147:226-235.
• [8] Zambrano O A.A general perspective of Fe-Mn-Al-C steels[J].Journal of Materials Science,2018,53(20):14003-14062.
• [9] Yang F,Song R,Li Y,et al.Tensile deformation of low density duplex Fe-Mn-Al-C steel[J].Materials & Design,2015,76:32-39.
• [10] Zhang L,Song R,Zhao C,et al.Work hardening behavior involving the substructural evolution of an austenite-ferrite Fe-Mn-Al-C steel[J].Materials Science and Engineering A,2015,640:225-234.
• [11] Abbasi M,Kheirandish S,Kharrazi Y,et al.On the comparison of the abrasive wear behavior of aluminum alloyed and standard Hadfield steels[J].Wear,2010,268(1/2):202-207.
• [12] Zambrano O A,Aguilar Y,Valdés J,et al.Effect of normal load on abrasive wear resistance and wear micromechanisms in FeMnAlC alloy and other austenitic steels[J].Wear,2016,348:61-68.
• [13] Anijdan S H M,Sabzi M,Najafi H,et al.The influence of aluminum on microstructure,mechanical properties and wear performance of Fe-14%Mn-1.05%C manganese steel[J].Journal of Materials Research and Technology,2021,15:4768-4780.
• [14] 李俊阳，姚亮，焦思远，等.Mn 含量对轻质 Fe-10Al-0.8C-10/15Mn 钢组织与力学性能的影响[J].上海金属，2017,39(4):19-24.LI Jun-yang,YAO Liang,JIAO Si-yuan,et al.Effect of Mn content on microstructure and mechanical properties of lightweight Fe-10Al-0.8C-10/15 steel[J].Shanghai Metals,2017,39(4):19-24.
• [15] Kim H,Suh D W,Kim N J.Fe-Al-Mn-C lightweight structural alloys:a review on the microstructures and mechanical properties[J].Science and Technology of Advanced Materials,2013,14(1):014205.
• [16] Gutierrez-Urrutia I.Low density Fe-Mn-Al-C steels:phase structures,mechanisms and properties[J].ISIJ International,2021,61(1):16-25.
• [17] 陈兴品，李文佳，任平，等.C 含量对 Fe-Mn-Al-C 低密度钢组织和性能的影响[J].金属学报，2019,55(8):951-957.CHEN Xing-pin,LI Wen-jia,REN Ping,et al.Effects of C content on microstructure and properties of Fe-Mn-Al-C low-density steels[J].Acta Metallurgica Sinica,2019,55(8):951-957.
• [18] Song C,Wang H,Sun Z,et al.A new hot-rolled lightweight steel with ultra-high strength and good ductility designed by dislocation character and transformation strain[J].Scripta Materialia,2022,212:114583.
• [19] 冯一帆.时效硬化型轻质超高锰钢的强化机理及冲击磨损行为研究[D].北京：北京科技大学，2021.FENG Yi-fan.Strengthening mechanism and impact wear behavior of aging hardening light-weight ultra-high manganese steel[D].Beijing:University of Science and Technology Beijing,2021.
• [20] Chu C M,Huang H,Kao P W,et al.Effect of alloying chemistry on the lattice constant of austenitic Fe-Mn-Al-C alloys[J].Scripta Metallurgica et Materialia,1994,30(4):505-508.
• [21] 彭世广，宋仁伯，谭志东，等.衬板用 Fe-24Mn-7Al-1C 耐磨钢的热处理工艺对组织和性能影响[J].材料热处理学报，2016,37(4):88-94.PENG Shi-guang,SONG Ren-bo,TAN Zhi-dong,et al.Effect of heat treatment process on microstructure and property of Fe-24Mn-7Al-1C wear resistant steel for lining plate[J].Transactions of Materials and Heat Treatment,2016,37(4):88-94.
• [22] Hallstedt B,Khvan A V,Lindahl B B,et al.PrecHiMn-4—A thermodynamic database for high-Mn steels[J].Calphad,2017,56:49-57.
• [23] Yao M J,Welsch E,Ponge D,et al.Strengthening and strain hardening mechanisms in a precipitation-hardened high-Mn lightweight steel[J].Acta Materialia,2017,140:258-273.
• [24] Sohrabizadeh M A,Mazaheri Y,Sheikhi M.The effects of age hardening on tribological behavior of lightweight Fe-Mn-Al-C steel[J].Journal of Materials Engineering and Performance,2021,30:4629-4640.
• [25] Fernandes F A P,Heck S á C,Totten G E,et al.Effect of the strain-hardening on the wear and corrosion behaviour of a Fe-Mn-Al-C alloy[J].International Journal of Microstructure and Materials Properties,2012,7(2/3):143-151.
• [26] Zuazo I,Hallstedt B,Lindahl B,et al.Low-density steels:complex metallurgy for automotive applications[J].JOM,2014,66(9):1747-1758.
• [27] Kalashnikov I,Shalkevich A,Acselrad O,et al.Chemical composition optimization for austenitic steels of the Fe-Mn-Al-C system[J].Journal of Materials Engineering and Performance,2000,9:597-602.
• [28] Gr?ssel O,Frommeyer G,Derder C,et al.Phase transformations and mechanical properties of Fe-Mn-Si-Al TRIP-steels[J].Le Journal de Physique IV,1997,7(C5):383-388.
• [29] Kim C W,Kwon S I,Lee B H,et al.Atomistic study of nano-sized κ-carbide formation and its interaction with dislocations in a cast Si added FeMnAlC lightweight steel[J].Materials Science and Engineering A,2016,673:108-113.
• [30] Wang Z,Lu W,Zhao H,et al.Formation mechanism of κ-carbides and deformation behavior in Si-alloyed FeMnAlC lightweight steels[J].Acta Materialia,2020,198:258-270.
• [31] Sohn S S,Lee S,Lee B J,et al.Microstructural developments and tensile properties of lean Fe-Mn-Al-C lightweight steels[J].JOM,2014,66(9):1857-1867.
• [32] Tang Y,Ji P,Li B,et al.Effect of loading on microstructure and friction and wear behavior of an austenite lightweight steel[J].Tribology International,2023,177:108006.
• [33] Chu C M,Huang H,Kao P W,et al.Effect of alloying chemistry on the lattice constant of austenitic Fe-Mn-Al-C alloys[J].Scripta Metallurgica et Materialia,1994,30(4):505-508.
• [34] 冯浩，刘仁东，乔军，等.Al 含量对高锰轻质钢组织和力学性能的影响[J].金属热处理，2016,41(11):62-66.FENG Hao,LIU Ren-dong,QIAO Jun,et al.Effect of Al content on microstructure and mechanical properties of high-Mn light-weight steels[J].Heat Treatment of Metals,2016,41(11):62-66.
• [35] Zuidema B K,Subramanyam D K,Leslie W C.The effect of aluminum on the work hardening and wear resistance of hadfield manganese steel[J].Metallurgical Transactions A,1987,18:1629-1639.
• [36] Barona-Osorio G M,Teran L A,Rodríguez S A,et al.On the tribocorrosion behavior of Fe-Mn-Al-C alloys in ringer’s solution[J].Metals,2022,12(8):1339.
• [37] 刘越，魏顺华，臧勐超.轻质高锰钢微观组织及耐磨性能研究[J].摩擦学学报，2018,38(3):291-298.LIU Yue,WEI Shun-hua,ZANG Meng-chao.Microstructure and impact wear properties of high manganese steel[J].Tribology,2018,38(3):291-298.
• [38] 林方敏，邢梅，唐立志，等.Fe-Mn-Al-C 系低密度钢及其强韧化机制研究进展[J].材料导报，2023,37(5):162-169.LIN Fang-min,XING Mei,TANG Li-zhi,et al.Research progress of Fe-Mn-Al-C low-density steels and their strengthening mechanisms[J].Materials Reports,2023,37(5):162-169.
• [39] Chen S,Rana R,Haldar A,et al.Current state of Fe-Mn-Al-C low density steels[J].Progress in Materials Science,2017,89:345-391.
• [40] Rodríguez J S,Duran J F,Aguilar Y,et al.Effect of Al content on the low-stress abrasive wear behaviour of Fe-18Mn-xAl-0.7C alloys[J].Tribology International,2023,180:108286.
• [41] Ma T,Li H,Gao J,et al.Effect of Al content and solution treatment on tensile and corrosion resistance of Fe-Mn-Al-C low-density steel[C]//TMS 2020 149th Annual Meeting & Exhibition Supplemental Proceedings.Springer International Publishing,2020.
• [42] Wu Z Q,Ding H,Li H Y,et al.Microstructural evolution and strain hardening behavior during plastic deformation of Fe-12Mn-8Al-0.8C steel[J].Materials Science and Engineering A,2013,584:150-155.
• [43] Zhao C,Song R,Zhang L,et al.Effect of annealing temperature on the microstructure and tensile properties of Fe-10Mn-10Al-0.7C low-density steel[J].Materials & Design,2016,91:348-360.
• [44] Etienne A,Massardier-Jourdan V,Cazottes S,et al.Ferrite effects in Fe-Mn-Al-C triplex steels[J].Metallurgical and Materials Transactions A,2014,45:324-334.
• [45] Tang Y,Li B,Shi H,et al.The role of ferrite on the wear and corrosion behaviors of dual-phase lightweight steel[J].Materials Today Communications,2023,35:106395.
• [46] Li Z,Wang H,Zhao Y,et al.Effect of progressive solid-solution treatment on microstructures,mechanical properties and impact abrasive wear behavior of alloyed high manganese steel[J].Materials Research Express,2022,9(3):036512.
• [47] Dalai R,Das S,Das K.Effect of thermo-mechanical processing on the low impact abrasion and low stress sliding wear resistance of austenitic high manganese steels[J].Wear,2019,420:176-183.
• [48] Eskandari M,Zarei-Hanzaki A,Kamali A R,et al.Strain hardening during hot compression through planar dislocation and twin-like structure in a low-density high-Mn steel[J].Journal of Materials Engineering and Performance,2014,23:3567-3576.
• [49] Frommeyer G,Brüx U.Microstructures and mechanical properties of high-strength Fe-Mn-Al-C light-weight TRIPLEX steels[J].Steel Research International,2006,77(9/10):627-633.
• [50] 邢梅，林方敏，唐立志，等.Al 元素对 Fe-Mn-Al-C系低密度钢的影响特性综述[J].中国冶金，2022,32(2):15-26.XING Mei,LIN Fang-min,TANG Li-zhi,et al.Effect of Al on properties of Fe-Mn-Al-C low density steel[J].China Metallurgy,2022,32(2):15-26.
• [51] Lee H J,Sohn S S,Lee S,et al.Thermodynamic analysis of the effect of C,Mn and Al on microstructural evolution of lightweight steels[J].Scripta Materialia,2013,68(6):339-342.
• [52] 魏顺华.轻质高锰钢微观组织及耐磨性能研究[D].沈阳：东北大学，2017.WEI Shun-hua.Study of microstructure and wear resistance of light high manganese steel[D].Shenyang:Northeastern University,2017.
• [53] Zambrano O A,Valdés J,Rodriguez L A,et al.Elucidating the role of κ-carbides in FeMnAlC alloys on abrasion wear[J].Tribology International,2019,135:421-431.
• [54] Acselrad O,De Souza A R,Kalashnikov I S,et al.A first evaluation of the abrasive wear of an austenitic FeMnAlC steel[J].Wear,2004,257(9/10):999-1005.
• [55] 王凤权，孙挺，王毛球，等.Fe-Mn-Al-C 系奥氏体基低密度钢的研究进展[J].钢铁，2021,56(6):89-102.WANG Feng-quan,SUN Ting,WANG Mao-qiu,et al.Research progress of Fe-Mn-Al-C system austenitic low density steel[J].Iron & Steel,2021,56(6):89-102.
• [56] Gutiérrez-Urrutia I,Raabe D.High strength and ductile low density austenitic FeMnAlC steels:Simplex and alloys strengthened by nanoscale ordered carbides[J].Materials Science and Technology,2014,30(9):1099-1104.
• [57] Lin C L,Chao C G,Juang J Y,et al.Deformation mechanisms in ultrahigh-strength and high-ductility nanostructured FeMnAlC alloy[J].Journal of Alloys and Compounds,2014,586:616-620.
• [58] Chen P,Zhang F,Zhang Q C,et al.Precipitation behavior of κ-carbides and its relationship with mechanical properties of Fe-Mn-Al-C lightweight austenitic steel[J].Journal of Materials Research and Technology,2023,25:3780-3788.
• [59] Ding H,Li H,Misra R D K,et al.Strengthening mechanisms in low density Fe-26Mn-xAl-1C steels[J].Steel Research International,2018,89(9):1700381.
• [60] Peng S,Song R,Sun T,et al.Wear behavior and hardening mechanism of novel lightweight Fe-25.1Mn-6.6Al-1.3C steel under impact abrasion conditions[J].Tribology Letters,2016,64:1-10.
• [61] Feng Y,Song R,Peng S,et al.Microstructures and impact wear behavior of al-alloyed high-Mn austenitic cast steel after aging treatment[J].Journal of Materials Engineering and Performance,2019,28(8):4845-4855.
• [62] Lee J,Park S,Kim H,et al.Simulation of κ-carbide precipitation kinetics in aged low-density Fe-Mn-Al-C steels and its effects on strengthening[J].Metals and Materials International,2018,24:702-710.
• [63] Bai S,Chen Y,Liu X,et al.Research status and development prospect of Fe-Mn-C-Al system low-density steels[J].Journal of Materials Research and Technology,2023,25:1537-1559.
• [64] 丁桦，胡晓.高层错能 Fe-Mn-Al-C 低密度钢的变形机制和组织控制[J].材料与冶金学报，2018,17(4):239-244.DING Hua,HU Xiao.Deformation mechanisms and microstructure control in Fe-Mn-Al-C steels with high stacking fault energies[J].Journal of Materials and Metallurgy,2018,17(4):239-244.
• [65] 刘春泉，彭其春，薛正良，等.Fe-Mn-Al-C 系列低密度高强钢的研究现状[J].材料导报，2019,33(15):2572-2581.LIU Chun-quan,PENG Qi-chun,XUE Zheng-liang,et al.Research situation of Fe-Mn-Al-C system low-density high-strength steel[J].Materials Reports,2019,33(8):2572-2581.
• [66] Kim S H,Kim H,Kim N J.Brittle intermetallic compound makes ultrastrong low-density steel with large ductility[J].Nature,2015,518(7537):77-79.
• [67] Hwang J H,Trang T T T,Lee O,et al.Improvement of strength-ductility balance of B2-strengthened lightweight steel[J].Acta Materialia,2020,191:1-12.
• [68] Ba Q,Song R,Zhou N,et al.Revealing working hardening behavior and substructure evolutions of ultrahigh strength and enhanced wear resistance Fe-25Mn-7Al-1C steel treated by explosion processing[J].Journal of Materials Science,2020,55(3):1256-1268.
• [69] 李欢.FeMnAlC轻质钢耐磨性的改进及耐蚀性[D].秦皇岛：燕山大学，2021.LI Huan.Wear resistance improving and corrosion resistance of FeMnAlc light steel[D].Qinhuangdao:Yanshan University,2021.
• [70] Bartlett L N,Serino S.Nitriding of lightweight high manganese and aluminum steels[J].International Journal of Metalcasting,2016,10(2):190-200.
• [71] Torabi S A,Amini K,Gharavi F.The effect of shot peening and precipitation hardening on the wear behavior of high manganese austenitic steels[J].Metallurgical Research & Technology,2017,114(5):507.
• [72] Yan W,Fang L,Sun K,et al.Effect of surface work hardening on wear behavior of Hadfield steel[J].Materials Science and Engineering A,2007,460:542-549.
• [73] Yan W,Fang L,Zheng Z,et al.Effect of surface nanocrystallization on abrasive wear properties in Hadfield steel[J].Tribology International,2009,42(5):634-641.
• [74] Wang Z,Yang Y,Chen C,et al.Effect of surface impacting parameters on wear resistance of high manganese steel[J].Coatings,2023,13(3):539.

文章评论(Comment)：