退火温度及TiO2结构对羟基磷灰石的沉积诱导作用Inducing effects of annealing temperature and TiO2 structure on deposition of hydroxyapatite
石萍,于千
摘要(Abstract):
采用阳极氧化法在钛金属表面制备TiO2薄膜,将表面改性的钛金属在过饱和钙化溶液中浸泡,在其表面沉积羟基磷灰石,研究了退火处理温度对TiO2薄膜晶型转变的影响以及TiO2的晶型结构对羟基磷灰石的诱导沉积作用。研究表明,300℃退火处理,TiO2薄膜为板钛矿相,500℃退火处理转变为锐钛矿相,高于500℃退火处理,锐钛矿相开始向金红石相转变。其中锐钛矿相的TiO2对羟基磷灰石的沉积具有最好诱导作用,沉积物分布均匀,板钛矿相对羟基磷灰石的诱导作用最差,所形成的沉积层是由片状的羟基磷灰石围成的多孔结构。
关键词(KeyWords): 羟基磷灰石;TiO2晶型;阳极氧化
基金项目(Foundation): 辽宁省自然科学基金资助项目(20052201);; 辽宁省教育厅资助项目(20060400)
作者(Author): 石萍,于千
DOI: 10.13289/j.issn.1009-6264.2010.01.030
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