时效时间对Mg-2.0Zn-1.0Y-0.5Zr合金组织与性能的影响Effect of aging time on microstructure and properties of Mg-2.0Zn-1.0Y-0.5Zr alloy
冯武云,贺俊光,田培梧,文九巴,龚圆,郑向阳
摘要(Abstract):
首先对Mg-2.0Zn-1.0Y-0.5Zr合金进行490℃固溶处理8 h,随后对其进行200℃时效2~12 h的处理,采用X射线衍射仪(XRD)、扫描电镜(SEM)、拉伸实验、浸泡测试和电化学测试等研究了合金经不同热处理后的组织和性能。结果表明:与固溶态合金相比,时效处理后,合金中的析出相呈细小颗粒状在基体上均匀分布,随时效时间的延长第二相数量逐渐增多;时效后的合金强度均高于固溶态合金,但耐蚀性有所下降。经综合考虑,200℃时效4 h后合金的性能最佳,其极限抗拉强度、屈服强度、伸长率和腐蚀速率分别为(224.6±7.3) MPa、(135.2±4.3) MPa、(19.1±1.2)%和(0.463±0.015) mm/y。
关键词(KeyWords): 生物镁合金;时效时间;第二相;性能
基金项目(Foundation): 河南省高等学校重点科研项目(20A430010)
作者(Author): 冯武云,贺俊光,田培梧,文九巴,龚圆,郑向阳
DOI: 10.13289/j.issn.1009-6264.2022-0452
参考文献(References):
- [1] 李俊伟,都承斐,尉迟晨曦,等.可降解植入物在骨折固定中的应用[J].中国组织工程研究,2018,22(34):5526-5533.LI Jun-wei,DU Cheng-fei,YUCHI Chen-xi,et al.Application of degradable implants in fracture fixation[J].Chonese Journal of Tissue Engineering Research,2018,22(34):5526-5533.
- [2] Zheng Y F,Gu X N,Witte F.Biodegradable metals[J].Materials Science and Engineering R,2014,77(2):1-34.
- [3] 王湛,杨军,李建军.新型骨科植入物镁合金材料抗菌性能的体外实验研究[J].中国医科大学学报,2014,43(12):1142-1144.WANG Zhan,YANG Jun,LI Jian-jun.In vitro experimental study on the antibacterial properties of new orthopedic implant material-magnesium alloy[J].Journal of China University,2014,43(12):1142-1144.
- [4] Riaz U,Shabib I,Haider W.The current trends of Mg alloys in biomedical applications-A review[J].Journal of Biomedical Materials Research Part B:Applied Biomaterials,2019,107:1970-1996.
- [5] Atrens A,Liu M,Abidin N I Z.Corrosion mechanism applicable to biodegradable magnesium implants[J].Materials Science and Engineering B,2011,176:1609-1636.
- [6] 袁广银,牛佳林.可降解医用镁合金在骨修复应用中的研究进展[J].金属学报,2017,53(10):1168-1180.YUAN Guang-yin,NIU Jia-lin.Research progress of biodegradable magnesium alloys for orthopedic application[J].Acta Metallurgica Sinica,2017,53(10):1168-1180.
- [7] 余琨,雷路,陈良建,等.新型镁合金在生理体液环境下腐蚀行为评价[J].金属功能材料,2011,18(2):32-36.YU Kun,LEI Lu,CHEN Liang-jian,et al.Corrosion behavior of magnesium alloy in the biological environment[J].Metallic Functional Materials,2011,18(2):32-36.
- [8] Bordbar-Khiabani A,Yarmand B,Mozafari M.Emerging magnesium-based biomaterials for orthopedic implantation[J].Emerging Materials Research,2019,8:305-319.
- [9] Costantino M D,Schuster A,Helmholz H,et al.Inflammatory response to magnesium-based biodegradable implant materials[J].Acta Biomaterialia,2020,101:598-608.
- [10] Ding W J.Opportunities and challenges for the biodegradable magnesium alloys as next-generation biomaterials[J].Regenerative Biomaterials,2016,3(2):79-86.
- [11] 赵亚忠,彭建,宋成猛,等.高塑性镁合金的研究现状[J].材料导报,2008,22(10):66-69.ZHAO Ya-zhong,PENG Jian,SONG Cheng-meng,et al.Research situation of high plasticity magnesium alloy[J].Materials Review,2008,22(10):66-69.
- [12] 刘正,张奎,曾小勤.镁基轻质合金理论基础及其应用[M].北京:机械工业出版社,2002.
- [13] 姜磊.Mg-Zn-Zr/Sr合金组织与性能研究[D].沈阳:沈阳工业大学,2020.JIANG Lei.Research on microstructures and properties of Mg-Zn-Zr/Sr alloy[D].Shenyang:Shenyang University of Technology,2020.
- [14] 卢立伟,康伟,黎小辉,等.时效处理对Mg-Zn-Gd-Er稀土镁合金的组织和力学性能的影响[J].稀有金属,2022,46(9):1153-1162.LU Li-wei,KANG Wei,LI Xiao-hui,et al.Microstructure and mechanical properties of Mg-Zn-Gd-Er rare earth magnesium alloy via aging treatment[J].Chinese Journal of Rare Metals,2022,46(9):1153-1162.
- [15] Cao L,Liu W C,Li Z Q,et al.Effect of heat treatment on microstructures and mechanical properties of sand-cast Mg-10Gd-3Y-0.5Zr magnesium alloy[J].Transactions of Nonferrous Metals Society of China,2014,24(3):611-618.
- [16] 单玉郎.Mg-Zn-Zr-Gd生物镁合金组织与性能研究[D].洛阳:河南科技大学,2016.SHAN Yu-lang.Study on the microstructure and properties of Mg-Zn-Zr-Gd biological alloys[D].Luoyang:Henan University of Science and Technology,2016.
- [17] 程丹丹.Mg-Nd-Zn-Zr-Y生物材料的制备及性能研究[D].洛阳:河南科技大学,2015.CHENG Dan-dan.Preparation and properties research of M-Nd-Zn-Zr-Y biological material[D].Luoyang:Henan University of Science and Technology,2015.
- [18] 徐大召.Mg-Zn-Y-Zr系生物镁合金组织与性能的研究[D].洛阳:河南科技大学,2020.XU Da-zhao.Study of microstructure and properties on the Mg-Zn-Y-Zr biological magnesium alloy[D].Luoyang:Henan University of Science and Technology,2020.
- [19] 田培梧,贺俊光,文九巴,等.固溶时间对Mg-2Zn-1Y-0.5Zr合金组织与腐蚀性能的影响[J].材料热处理学报,2021,42(9):50-57.TIAN Pei-wu,HE Jun-guang,WEN Jiu-ba,et al.Effect of solution time on microstructure and corrosion properties of Mg-2Zn-1Y-0.5Zr alloy[J].Transactions of Materials and Heat Treatment,2021,42(9):50-57.
- [20] Cho J H,Chen H M,Choi S H,et al.Aging effect on texture evolution during warm rolling of ZK60 alloys fabricated by twin-roll casting[J].Metallurgical and Materials Transactions A,2010,41:2575-2583.
- [21] Xu D K,Han E H.Effect of quasicrystalline phase on improving the corrosion resistance of a duplex structured Mg-Li alloy[J].Scripta Materialia,2014,71(9):21-24.
- [22] 李松瑞,周善初.金属热处理[M].长沙:中南大学出版社,2003.
- [23] 姚怀,刘亚,杜三明,等.时效处理对Mg-2.0Zn-0.5Zr-3.0Gd生物降解镁合金组织、力学性能及耐腐蚀性能的影响[J].中国有色金属学报,2020,30(3):518-529.YAO Huai,LIU Ya,DU San-ming,et al.Effect of aging treatment on microstructure,mechanical properties and corrosion resistance of biodegranical Mg-2.0Zn-0.5Zr-3.0Gd magnesium alloy[J].The Chinese Journal of Nonferrous Metals,2020,30(3):518-529.
- [24] 侯彩凤.固溶时效工艺对Mg-7Y-1Nd合金组织和耐蚀性能的影响[D].济南:山东大学,2017.HOU Cai-feng.Effect of solid and aging process on the microstructure and corrosion resistance of Mg-7Y-1Nd alloy[D].Jinan:Shandong University,2017.
- [25] 章晓波,殷俏,马青龙,等.时效处理对挤压态Mg-Gd-Nd-Sr-Zn-Zr合金力学与腐蚀性能的影响[J].中国有色金属学报,2016,26(3):526-534.ZHANG Xiao-bo,YIN Qiao,MA Qing-long,et al.Effect of a treatment on mechanical and corrosion properties of as-extruded Mg-Gd-Nd-Sr-Zn-Zr alloy[J].The Chinese Journal of Nonferrous Metals,2016,26(3):526-534.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||