2507双相不锈钢在电解海水防污环境中的腐蚀钝化行为Corrosion and passivation behavior of 2507 duplex stainless steel in electrolytic seawater antifouling environment
冯淼,彭靖博,张钰柱,余翠兰,寇晓培,田于财
摘要(Abstract):
通过开路电位、动电位极化曲线、恒电位极化曲线、Mott-Schottky曲线和腐蚀形貌观察等研究了2507双相不锈钢在电解海水防污环境中的腐蚀行为和钝化行为。结果表明:2507双相不锈钢在电解海水防污环境中的腐蚀形式是点蚀;随着NaClO质量浓度的增大,NaClO水解导致溶液pH值升高,阻碍溶解氧的阴极去极化过程,减缓阳极氧化溶解速率,开路电位和自腐蚀电位增加,腐蚀倾向性降低;而NaClO阻碍钝化膜生成过程,钝化区间减小,载流子密度增大,钝化膜屏蔽性能下降,阻抗半径减小,腐蚀电流密度增大,点蚀孔数量增多,孔径深度增大,耐腐蚀性能下降。
关键词(KeyWords): 2507双相不锈钢;NaClO;腐蚀行为;钝化行为;钝化膜
基金项目(Foundation): 重庆市教委科学技术研究项目青年项目(KJQN202002402)
作者(Author): 冯淼,彭靖博,张钰柱,余翠兰,寇晓培,田于财
DOI: 10.13289/j.issn.1009-6264.2022-0496
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