过时效工艺对高强钢表面选择性氧化行为的影响Effect of over-aging process on selective oxidation behavior of high strength steel surface
蒋光锐,王海全,滕华湘
摘要(Abstract):
利用热浸镀工艺模拟器研究过时效工艺温度和气氛露点温度对C-M-Si高强钢选择性氧化的影响。使用场发射扫描电镜和能谱仪分析样品表面显微形貌以及成分,使用辉光放电光谱仪表征样品浅表层的元素深度分布,采用X射线光电子能谱仪确定样品表面的氧化物种类。结果表明:采用较高的过时效温度(350℃)和较高的气氛露点温度(-10℃),可以抑制Mn和Si在高强钢表面的选择性氧化,此时样品表面的化合物为无定型SiO_x、无定型MnO_x以及纯态Mn;随着气氛露点温度和过时效温度的降低,Mn和Si在样品表面的富集量明显增加,样品表面出现大量富含Mn和Si的颗粒状氧化物;气氛露点温度对样品表面合金元素富集峰值的影响比过时效工艺温度的影响更显著。
关键词(KeyWords): 高强钢;选择性氧化;过时效处理;露点
基金项目(Foundation): 国家重点研发计划(2017YFB0304305)
作者(Author): 蒋光锐,王海全,滕华湘
DOI: 10.13289/j.issn.1009-6264.2018-0135
参考文献(References):
- [1]康永林.汽车轻量化先进高强钢与节能减排[J].钢铁,2008,43(6):1-7.KANG Yong-lin.Light weight vehicle,advanced high strength steel and energy-saving and emission reduction[J].Iron and Steel,2008,43(6):1-7.
- [2]Li Y,Lin Z,Jiang A,et al.Use of high strength steel sheet for lightweight and crashworthy car body[J].Materials and Design,2003,24(3):177-182.
- [3]Senuma T.Physical metallurgy of modern high strength steel sheets[J].ISIJ International,2001,41(6):520-532.
- [4]Matlock D K,Speer J G,Moor E D,et al.Recent developments in advanced high strength sheet steels for automotive applications:An overview[J].Engineering Science and Technology An International Journal,2012,15(1):1-12.
- [5]Zhong N,Wwang X D,Wang L,et al.Enhancement of the mechanical properties of a Nb-microalloyed advanced high-strength steel treated by quenching-partitioning-tempering process[J].Materials Science and Engineering A,2009,506(1/2):111-116.
- [6]Ma Y X,Guo B,Zheng L,et al.Microstructure and mechanical properties in ultra-high strength steel with tensile strength1000 MPa[J].Advanced Materials Research,2012,567:79-87.
- [7]Wang X,Huang B,Rrong Y,et al.Mechanical and transformation behaviors of a C-Mn-Si-Al-Cr TRIP steel under stress[J].Journal of Materials Science and Technology,2006,22(5):625-628.
- [8]Liu H,Li F,Shi W,et al.Challenges in hot-dip galvanizing of high strength dual phase steel:Surface selective oxidation and mechanical property degradation[J].Surface and Coatings Technology,2012,206(16):3428-3436.
- [9]蒋光锐,王海全,刘李斌.退火工艺对C-Mn-Si高强钢表面选择性氧化行为的影响[J].材料热处理学报,2017,38(12):96-100.JIANG Guang-rui,WANG Hai-quan,LIU Li-bin.Effect of annealing technology on surface selective oxidation behavior of high strength steels with different silicion content[J].Transactions of Materials and Heat Treatment,2017,38(12):96-100.
- [10]Suzuki Y,Yamashita T,Sugimoto Y,et al.Thermodynamic analysis of selective oxidation behavior of Si and Mn-added steel during recrystallization annealing[J].ISIJ International,2009,96(1):11-20.
- [11]Liu L,Jiang G,Wang H,et al.Effect of dew point during heating on selective oxidation of TRIP steels[J].Metallurgical Research and Technology,2017,114(6):609.
- [12]蒋光锐,陈凌峰,王海全,等.过时效段露点对双相钢表面色差的影响[J].钢铁,2017,52(8):87-91.JIANG Guang-rui,CHEN Ling-feng,WANG Hai-quan,et al.Influence of over-aging dew point on surface color difference of dual phase steel[J].Iron and Steel,2017,52(8):87-91.
- [13]Jiang G,Teng H,Wang H,et al.Selective oxidation in press hardening steel during annealing with different dew points[C]//Galvatech 2013,Metallurgical Industry Press,Beijing,2013:139-142.
- [14]蒋光锐,王海全,刘李斌.加热工艺对含磷高强钢氧化行为的影响[J].钢铁,2017,52(10):78-82.JIANG Guang-rui,WANG Hai-quan,LIU Li-bin.Heating process on oxidation behavior of P-bearing high strength steel[J].Iron and Steel,2017,52(10):78-82.
- [15]Parezanovic I,Spiegel M.Influence of dew point on the selective oxidation during annealing of cold rolled DP and Ti-IF steels[J].Journal of Corrosion Science and Engineering,2003,6(2):74-79.
- [16]Kim M S,Kwak J H,Kim J S,et al.Galvanizability of advanced high-strength steels 1180TRIP and 1180CP[J].Metallurgical and Materials Transactions A,2009,40(8):1903-1910.
- [17]Bellhouse E M,Mc Dermid J R.Selective oxidation and reactive wetting during hot-dip galvanizing of a 1.0 pct Al-0.5 pct Si TRIPassisted steel[J].Metallurgical and Materials Transactions A,2012,43(7):2426-2441.
- [18]Bellhouse E M,Mc Dermid J R.Selective oxidation and reactive wetting of 1.0 Pct Si-0.5 Pct Al and 1.5 Pct Si TRIP-assisted steels[J].Metallurgical and Materials Transactions A,2010,41(6):1539-1553.
- [19]Kim Y,Shin K S,Jeon S H,et al.The influence of the dew point on the wettability of twinning-induced-plasticity steels by liquid Zn-0.23-wt%Al[J].Corrosion Science,2014,85(4):364-371.
- [20]Kim Y,Lee J,Shin K S,et al.Effect of dew point on the formation of surface oxides of twinning-induced plasticity steel[J].Materials Characterization,2014,89(3):138-145.
- [21]Pourmajidian M,Mc Dermid J R.Selective oxidation of a 0.1C-6Mn-2Si third generation advanced high-strength steel during dewpoint controlled annealing[J].Metallurgical and Materials Transactions A,2018,49(5):1795-1808.
- [22]Maki J,Mahieu J,Cooman B C D,et al.Galvanisability of silicon free CMn Al TRIP steels[J].Metal Science Journal,2003,19(1):125-131.
- [23]Matsumoto R,Nishizawa Y,Kataoka N,et al.Automatic background estimation and quantitative analysis for XPS spectrum by active shirley method[J].Journal of Surface Analysis,2016,22(3):155-167
- [24]Naumkin A V,Kraut V A,Gaarenstroom S W,et al.NIST Xray photoelectron spectroscopy database,NIST Standard Reference Database 20,vers.4.1.Web Vers[DB/OL].http://srdata.nist.gov/xps/Default.aspx(2012-9-15),doi:10.18434/T4T88K.
- [25]Rumble J R,Bickham D M,Powell C J.The NIST X-ray photoelectron spectroscopy database[J].Surface and Interface Analysis,2010,19(1/12):241-246.
- [26]Gesmundo F,Viani F,Niu Y,et al.The transition from the formation of mixed scales to the selective oxidation of the most-reactive component in the corrosion of single and two-phase binary alloys[J].Oxidation of Metals,1993,40(3/4):373-393.
- [27]Grabke H J,Leroy V,Viefhaus H.Segregation on the surface of steels in heat treatment and oxidatio[J].ISIJ International,1995,35(2):95-113.
- [28]Rapp R A.The transition from internal to external oxidation and the formation of interruption bands in silver-indium alloys[J].Acta Metallurgica,1961,9(8):730-741.
- [29]Liu H,He Y,Lin L.Application of thermodynamics and Wagner model on two problems in continuous hot-dip galvanizing[J].Applied Surface Science,2009,256(5):1399-1403.
- [30]Lee S K,Kim J S,Choi J W,et al.Effects of dew point on selective oxidation of TRIP steels containing Si,Mn,and B[J].Metals and Materials International,2011,17(2):251-257.
- [31]Ollivier L A,Giorgi M L,Balloy D,et al.Nucleation and growth of selective oxide particles on ferritic steel[J].Corrosion Science,2010,52:2498-2504.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||