Zn-Ni-Ti热浸镀层组织及其耐蚀性Microstructure and corrosion resistance of hot-dipped Zn-Ni-Ti coatings
吴长军,范赛林,苏旭平,袁冲,王建华,涂浩
摘要(Abstract):
将Q235钢在450℃的Zn-Ni-Ti合金中热浸镀0.5~5 min,研究了锌池中添加0.03%~0.06%Ni和0.02%~0.04%Ti对含硅结构钢热浸镀锌层组织的影响。并通过电化学方法测试了Zn-Ni-Ti合金及其镀层在10%Na Cl溶液中的耐蚀性。研究发现,锌池中同时添加0.03%~0.05%Ni和0.02%~0.03%Ti可有效抑制Q235钢热浸镀锌时的硅反应性,合金层厚度明显减薄,其生长主要受扩散控制。而且不会形成大量的三元化合物渣滓。实验证实,添加微量Ni和Ti后,提高了锌合金及其镀层的耐蚀性。但当添加0.05%Ni+0.04%Ti时,镀层表面质量下降,还会形成较多的溶解了约1.0%Ni的Zn-Fe-Ti三元化合物。
关键词(KeyWords): 热浸镀锌;硅反应性;合金元素;耐蚀性
基金项目(Foundation): 国家自然科学基金(51271040,51201023);; 江苏高校优势学科建设工程资助项目;; 溧阳市科技计划项目(ly2012PT01)
作者(Author): 吴长军,范赛林,苏旭平,袁冲,王建华,涂浩
DOI: 10.13289/j.issn.1009-6264.2015.09.027
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