Mg-4Zn-1Mn镁合金均匀化热处理及导热率Homogenizing heat treatment and thermal conductivity of Mg-4Zn-1Mn magnesium alloy
袁家伟,李婷,李兴刚,李永军,张奎,郝永辉,罗广求,罗萍
摘要(Abstract):
采用光学显微镜、X射线衍射、布氏硬度测试、扫描电镜、能谱分析等方法,研究新型Mg-4Zn-1Mn(ZM41)镁合金在铸态和不同热处理状态下的显微组织、成分、硬度变化规律。用激光闪射法测定其不同状态的热扩散系数,计算得到导热率值。以空位扩散机制为基础,研究均匀化扩散动力学过程,建立此合金的均匀化扩散方程。结果表明:铸态组织枝晶偏析严重,晶界上有许多粗大的Mg7Zn3非平衡结晶相,Mn以单质形式存在于合金中。经370℃×12 h均匀化热处理后,大部分的Mg7Zn3相已溶入基体。根据实验结果和均匀化动力学计算,确定最佳均匀化处理工艺为370℃×12 h。该合金室温导热率值为125.5 W/(m.K),比常见的镁合金如AZ系、AM系、AS系等的导热性能高出1倍左右。
关键词(KeyWords): Mg-4Zn-1Mn镁合金;导热率;均匀化热处理;扩散动力学
基金项目(Foundation): 国家“十二五”支撑计划课题(2011DAE22B01)
作者(Author): 袁家伟,李婷,李兴刚,李永军,张奎,郝永辉,罗广求,罗萍
DOI: 10.13289/j.issn.1009-6264.2012.04.009
参考文献(References):
- [1]刘正,张奎,曾小勤.镁基轻质合金理论基础及应用[M].北京:机械工业出版社,2002.
- [2]张丁非,方霖,段红玲,等.ZM61镁合金的热变形行为[J].材料热处理学报,2011,32(4):25-29.ZHANG Ding-fei,FANG Lin,DUAN Hong-ling,et al.Constitutive equation of thermal compression deformation for ZM61magnesium alloy[J].Transactions of Materials and Heat Treatment,2011,32(4):25-29.
- [3]尹东松,张二林,曾松岩.Mg-3Zn-Mn合金均匀化处理工艺研究[J].铸造技术,2008,29(12):1647-1650.YIN Dong-song,ZHANG Er-lin,ZENG Song-yan.Research of homogenization treatment process on as-cast Mg-3Zn-Mn alloy[J].Foundry Technology-Die Casting,2008,29(12):1647-1650.
- [4]Yamasaki M,Kawamura Y.Thermal diffusivity and thermal conductivity of Mg-Zn-rare earth element alloys with long-period stacking ordered phase[J].Scripta Materialia,2009,60:264-267.
- [5]Rudajevova A,Stane.M,Luka P.Determination of thermal diffusivity and thermal conductivity of Mg-Al alloys[J].Materials Science and Engineering A,2003,341:152-157.
- [6]Chen C J,Wang Q D,Yin D D.Thermal properties of Mg-11Y-5Gd-2Zn-0.5Zr(wt.%)alloy[J].Journal of Alloys and Compounds,2009,487:560-563.
- [7]Rudajevova A,Lukac P.Comparison of the thermal properties of AM20and AS21magnesium alloys[J].Materials Science and Engineering A,2005,397:16-21.
- [8]李红英,刘洋,康巍,等.均匀化退火对ZA27合金组织与性能的影响[J].材料热处理学报,2010,31(12):107-111.LI Hong-ying,LIU Yang,KANG Wei,et al.Effect of homogenizing annealing on microstructure and mechanical properties of ZA27alloy[J].Transactions of Materials and Heat Treatment,2010,31(12):107-111.
- [9]刘晓涛,崔建忠.铝合金均匀化扩散动力学研究[J].材料导报,2004,18(6):102-104.LIU Xiao-tao,CUI Jian-zhong.Study on the diffusion kinetics of aluminum alloy cast during homogenizing treatment[J].Materials Review,2004,18(6):102-104.
- [10]李永军,张奎,李兴刚,等.Mg-Y-Nd-Zr合金均匀化处理工艺及微观组织的研究[J].稀有金属,2008,32(6):679-683.LI Yong-jun,ZHANG Kui,LI Xing-gang,et al.Homogenizing and microstructure of Mg-Y-Nd-Zr Alloy[J].Chinese Journal of Rare Metals,2008,32(6):679-683.
- [11]马鸣龙,张奎,李兴刚,等.GWN751K镁合金均匀化热处理[J].中国有色金属学报,2010,20(1):1-9.MA Ming-Long,ZHANG Kui,LI Xing-gang,et al.Homogenization heat treatment of GWN751K magnesium alloy[J].The Chinese Journal of Nonferrous Metals,2010,20(1):1-9.
- [12]Shewman P G.Diffusion in Solids[M].Mcgraw hill,NewYork,1963.
- [13]潘金生,仝健民,田民波.材料科学与基础[M].北京:清华大学出版社,1998.
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