曲立杰,李慕勤,张二林,马臣,李扬德

• 1:哈尔滨工业大学先进焊接与连接国家重点实验室
• 2:佳木斯大学材料科学与工程学院
• 3:东莞宜安科技股份有限公司

摘要(Abstract)：

为改善医用镁合金的耐蚀性能,将超声波引入到微弧氧化过程中,实现对镁合金的超声辅助微弧氧化处理,考察超声波在微弧氧化过程中对镁合金在模拟体液中的耐蚀性能的作用。采用析氢法测定镁合金在两种不同模拟体液中的腐蚀速率,电化学腐蚀方法测定镁合金平衡腐蚀电位、电流密度和线性极化电阻。结果表明,不同表面处理的镁合金的在两种不同的模拟体液中的耐蚀性能大小关系均为:超声-微弧氧化>微弧氧化>未经处理的镁合金。超声波有效的提高了微弧氧化镁合金的耐蚀性能。

关键词(KeyWords)： 超声波;微弧氧化;镁合金;耐蚀性;模拟体液

Abstract:

Keywords:

基金项目(Foundation): 国家自然科学基金(31070859);; 黑龙江省自然科学基金重点项目(ZD201008)

作者(Author): 曲立杰,李慕勤,张二林,马臣,李扬德

DOI: 10.13289/j.issn.1009-6264.2013.03.025

参考文献(References)：

• [1]袁广银,张佳,丁文江.可降解医用镁基生物材料的研究进展[J].中国材料进展,2011,30(2):44-50.YAN Guang-yin,ZHANG Jia,DING Wen-jiang.Research progress of Mg-based alloys as degradable biomedical materials[J].Materials China,2011,30(2):44-50.
• [2]Gu X N,Li N,Zhou W R,et al.Corrosion resistance and surface biocompatibility of a micro-arc oxidation coating on a Mg-Ca alloy[J].ActaBiomaterialia,2011,7:1880-1889.
• [3]Witte F.The history of biodegradable magnesium implants:A review[J].Acta Biomaterialia,2010,6:1680-1692.
• [4]Witte F,Fischer J,Nellesen J,et al.In vivo corrosion and corrosion protection of magnesium alloy LAE442[J].Acta Biomaterialia,2010,6:1792-1799.
• [5]王勇,高家诚,张艳,等.纯镁在模拟体液中的腐蚀机理[J].中国有色金属学报,2007,25(3):66-70.WANG Yong,GAO JIA-cheng,ZHANG Yan,et al.Mechanism of pure magnesium corrosion immersed in simulated body fluid[J].The ChineseJournal of Nonferrous Metals,2007,25(3):66-70.
• [6]Zhang E L,Xu L P,Yang K.Formation by ion plating of Ti-coating on pure Mg for biomedical applications[J].Scripta Materialia,2005,53(5):523-527.
• [7]Song G L.Control of degradation of biocompatible magnesium in a pseudo physiological environment by a ceramic like anodized coating[J].AdvancedMaterials Research,2007,29-30:95-98.
• [8]Zhang X P,Zhao Z P,Wu F M.Corrosion and wear resistance of AZ91D magnesium alloy with and without microarc oxidation coating in Hank’ssolution[J].Journal of Materials Science,2007,42(20):8523-8528.
• [9]王亚明,王福会,雷廷权,等.镁合金表面生物陶瓷涂层在模拟体液中的腐蚀性能[J].热处理技术与装备,2007,12(6):7-9.WANG Ya-ming,WANG Fu-hui,LEI Ting-quan,et al.Microstructure and corrosion behaviors in SBF of microarc oxidation ceramic coating formed onMg alloy[J].Heat Treatment Technology and Equipment,2007,12(6):7-9.
• [10]蒋百灵,夏天,时惠英,等.镁合金微弧氧化陶瓷层的绝缘强度及耐蚀性的研究[J].材料热处理学报,2005,26(2):82-86.JIANG Bai-ling,XIA Tian,SHI Hui-ying,et al.Study of impedance characteristic and corrosion-resistance properties of ceramic coating by micro-arcoxidation on magnesium alloy[J].Trans Mater Heat Treat,2005,26(2):82-86.
• [11]Bai A.Optimization of anti-corrosion ability of micro-arc oxide coating on AZ91D alloy using experimental strategies[J].Surface and CoatingsTechnology,2010,204:1856-1862.
• [12]Song Y,Zhang S X,Li J N,et al.Electrodeposition of Ca-P coatings on biodegradable Mg alloy:in vitro biomineralization behavior[J].ActaBiomaterialia,2010,6:1736-1742.
• [13]Gu X N,Zheng W,Cheng Y,et al.A study on alkaline heat treated Mg-Ca alloy for the control of the biocorrosion rate[J].Acta Biomaterialia.2009,5(7):2790-2799.
• [14]李绮,刘新杰,王泽庆,等.AZ31B镁合金表面氟涂层的生物相容性和抗菌性能[J].材料研究学报,2011,25(2):193-198.LI-Qi,LIU Xin-jie,WANG Ze-qin,et al.Biocompatibility and antibacterial property of a fluoride coating on AZ31B magnesium alloy[J].Journal ofMaterials Research,2011,25(2):193-198.
• [15]刘继光,包殿瑞,毕庆伟,等.超声辅助微弧氧化钛合金表面制备含镧涂层的生物相容性评价[J].中国组织工程研究与临床康复,2010,14(29):5351-5354.LIU Ji-guang,BAO Dian-rui,BI Qing-wei,et al.Ultrasound-assisted micro-arc oxidation to prepare biocoatings containing lanthanum on the surface oftitanium alloy:Biocompatibility evaluation[J].Journal of Clinical Rehabilitative Tissue Engineering Research,2010,14(29):5351-5354.
• [16]胡晓丽.AZ60镁合金钙系磷酸盐膜层成膜与腐蚀机制研究[D].吉林:吉林大学,2010.
• [17]杨柯,谭丽丽,任伊宾,等.AZ31镁合金的生物降解行为研究[J].中国材料进展,2009,28(2):26-30.YANG Ke,TAN Li-li,REN Yi-bin,et al.Study on biodegradation behavior of AZ31 magnesium alloy[J].Materials China,2009,28(2):26-30.
• [18]任伊宾,黄晶晶,杨柯,等.纯镁的生物腐蚀研究[J].金属学报,2005,41(11):1228.REN Yi-bin,HUANG Jing-jing,YANG Ke,et al.Study of bio-corrosion of pure magnesium[J].Acta Metallurgica Sinica,2005,41(11):1228-1232.

文章评论(Comment)：