热处理工艺对Mg-Gd-Sm(-Zn)-Zr合金微观组织和力学性能的影响Influence of heat treatment process on microstructure and mechanical properties of Mg-Gd-Sm(-Zn)-Zr alloy
王聪,李全安,陈晓亚,张娜娜,史浩鹏
摘要(Abstract):
采用光学显微镜、X射线衍射仪、扫描电镜以及电子拉伸试验机等研究了不同热处理工艺及Zn元素对Mg-10Gd-3Sm(-1Zn)-0.5Zr(mass%)合金微观组织和力学性能的影响。结果表明:Zn元素的加入可以有效细化晶粒,促进第二相的析出,并生成一种新相(Mg, Zn)_3(Sm, Gd)_1;Mg-10Gd-3Sm(-1Zn)-0.5Zr合金的最佳热处理工艺为515℃×6 h固溶及225℃×10 h时效处理;对其进行室温和高温拉伸,发现随着温度的升高,时效态Mg-10Gd-3Sm(-1Zn)-0.5Zr合金的抗拉强度表现出先增大后减小的趋势;Zn的加入使合金的抗拉强度和伸长率明显高于基体合金,表现出优异的力学性能;两种合金在室温和高温下的断裂机制均属于脆性断裂,不含Zn的基体合金脆性特征更为明显,塑性较差,而含Zn的合金断口形貌中撕裂棱和解理刻面数目较多,塑性较高。
关键词(KeyWords): Mg-10Gd-3Sm-1Zn-0.5Zr合金;固溶处理;时效处理;显微组织;力学性能
基金项目(Foundation): 国家自然科学基金(52371108,52201119);; 龙门实验室前沿探索课题(LMQYTSKT014);; 河南省科技研发计划联合基金(242103810056)
作者(Author): 王聪,李全安,陈晓亚,张娜娜,史浩鹏
DOI: 10.13289/j.issn.1009-6264.2024-0515
参考文献(References):
- [1] Kojima Y.Project of platform science and technology for advanced magnesium alloys[J].Materials Transactions,2001,42(7):1154-1159.
- [2] 郑泽宇,李全安,陈晓亚,等.Ce微合金化在镁合金中的研究现状与展望[J].材料热处理学报,2024,45(6):1-15.ZHENG Ze-yu,LI Quan-an,CHEN Xiao-ya,et al.Research status and prospects of Ce microalloying in magnesium alloys[J].Transactions of Materials and Heat Treatment,2024,45(6):1-15.
- [3] Davis A E,Kennedy J R,Lunt D,et al.Preageing of magnesium alloys[J].Materials Science and Engineering A,2021,809:141002.
- [4] 李中山,王梅,胡耀波,等.挤压温度对Mg-Sm-Zr合金组织与力学性能的影响[J].材料热处理学报,2023,44(7):48-56.LI Zhong-shan,WANG Mei,HU Yao-bo,et al.Effect of extrusion temperature on microstructure and mechanical properties of Mg-Sm-Zr alloy[J].Transactions of Materials and Heat Treatment,2023,44(7):48-56.
- [5] 刘亚,文九巴,李欢,等.Y含量对 Mg-Zn-Gd-Y-Zr 生物镁合金组织及性能的影响[J].材料热处理学报,2021,42(10):49-55.LIU Ya,WEN Jiu-ba,LI Huan,et al.Effect of Y content on microstructure and properties of Mg-Zn-Gd-Y-Zr biological magnesium alloy[J].Transactions of Materials and Heat Treatment,2021,42(10):49-55.
- [6] Bayat-Tork N,Mahmudi R,Hoseini-Athar M M,et al.Hot deformation constitutive analysis and processing maps of extruded Mg-Gd binary alloys[J].Journal of Materials Research and Technology,2020,9(6):15346-15359.
- [7] Zhang J,Liu S,Wu R,et al.Recent developments in high-strength Mg-RE-based alloys:Focusing on Mg-Gd and Mg-Y systems[J].Journal of Magnesium and Alloys,2018,6(3):277-291.
- [8] 孙瑞雪,陈君,陈晓亚,等.热处理对Mg-12Gd-1Zn-0.5Zr合金显微组织和力学性能的影响[J].材料热处理学报,2022,43(2):17-24.SUN Rui-xue,CHEN Jun,CHEN Xiao-ya,et al.Effect of heat treatment on microstructure and mechanical properties of Mg-12Gd-1Zn-0.5Zr alloy[J].Transactions of Materials and Heat Treatment,2022,43(2):17-24.
- [9] 顾侃,肖旅,曾小勤,等.航空航天用高强度Mg-RE系合金的研究进展[J].上海航天(中英文),2022,39(6):84-95.GU Kan,XIAO Lü,ZENG Xiao-qin,et al.Recent development of high strength Mg-RE alloys for aerospace application[J].Aerospace Shanghai (Chanese and English),2022,39(6):84-95.
- [10] Zhou H,Xu W,Jian W,et al.A new metastable precipitate phase in Mg-Gd-Y-Zr alloy[J].Philosophical Magazine,2014,94(21):2403-2409.
- [11] 王金阳.Gd对ZMT813合金组织及性能的影响[D].重庆:重庆大学,2021.WANG Jin-yang.The effect of Gd on the microstructure and properties of ZMT813 alloy[D].Chongqing:Chongqing University,2021.
- [12] Wang C,Li H,Guo E,et al.The effect of Gd on the microstructure evolution and mechanical properties of Mg-4Zn-0.6Ca alloy[J].Materials Science and Engineering A,2023,868:144756.
- [13] 庞浩,李全安,陈晓亚.含钐镁合金的研究现状与应用[J].中国稀土学报,2022,40(4):561-576.PANG Hao,LI Quan-an,CHEN Xiao-ya,et al.Research status and application of samarium-containing magnesium alloys[J].Journal of the Chinese Society of Rare Earths,2022,40(4):561-576.
- [14] Pang H,Bao J,Li Q,et al.Effect of Sm on microstructures and mechanical properties of Mg-Gd(-Sm)-Zr alloys by hot extrusion and aging treatment[J].Journal of Materials Research and Technology,2022,19:3877-3893.
- [15] Hu Y,Yu N,Zhao L,et al.Effect of Sm on the microstructure and properties of Mg-9Al alloy[J].International Journal of Cast Metals Research,2017,30(6):317-321.
- [16] Zhao J,Xu J,Liu Y,et al.Role of Zn addition on the microstructure and tensile property in Mg-Mn-Nd alloys[J].Journal of Materials Research and Technology,2023,27:7964-7969.
- [17] Nie J F,Gao X,Zhu S M.Enhanced age hardening response and creep resistance of Mg-Gd alloys containing Zn[J].Scripta Materialia,2005,53(9):1049-1053.
- [18] 李卓琳,李全安,陈晓亚,等.Mg-Gd-Sn-Zr合金热处理工艺优化[J].中国稀土学报,2024,11(9):1-13.LI Zhuo-lin,LI Quan-an,CHEN Xiao-ya,et al.Heat treatment process optimization of Mg-Gd-Sn-Zr alloy[J].Journal of the Chinese Society of Rare Earths,2024,11(9):1-13.
- [19] Guan K,Ma R,Zhang J,et al.Modifying microstructures and tensile properties of Mg-Sm based alloy via extrusion ratio[J].Journal of Magnesium and Alloys,2021,9(3):1098-1109.
- [20] Liu Y,Song Y,Li N,et al.Mechanical properties and microstructure evolution of Mg-Gd alloy during aging treatment[J].Metals,2021,12(1):39-44.
- [21] Liu Z,Zhou J,Yang L,et al.Study on microstructure and properties of Mg-Al-Si-Ca alloy by heat treatment[J].Journal of Alloys and Compounds,2023,947:169431.
- [22] Ma T,Zhao S,Guo E,et al.Microstructure evolution and strengthening mechanism analysis of novel Mg-RE-Ag alloy during heat treatment[J].Journal of Materials Research and Technology,2022,21:692-703.
- [23] 张帅,李全安,朱宏喜,等.热处理对 Mg-11Gd-3Y-0.8Ca-0.5Zr合金显微组织及性能的影响[J].材料热处理学报,2020,41(1):19-26.ZHANG Shuai,LI Quan-an,ZHU Hong-xi,et al.Effect of heat treatment on microstructure and properties of Mg-11Gd-3Y-0.8Ca-0.5Zr alloy[J].Transactions of Materials and Heat Treatment,2020,41(1):19-26.
- [24] 付三玲.Mg-Gd(-Y-Sm-Zr)耐热镁合金组织和性能研究[D].西安:西安理工大学,2016.FU San-ling.Study on the microstructure and mechanical properties of Mg-Gd(-Y-Sm-Zr) heat resistant magnesium alloys[D].Xi’an:Xi’an University of Technology,2016.
- [25] 朱利敏,李全安,周耀,等.Sm对Mg-10Gd-0.5Zr合金组织及力学性能的影响[J].稀有金属材料与工程,2019,48(1):171-176.ZHU Li-min,LI Quan-an,ZHOU Yao,et al.Effect of Sm on microstructures and mechanical properties of Mg-10Gd-0.5Zr alloy[J].Rare Metal Materials and Engineering,2019,48(1):171-176.
- [26] Tang C,Liu W,Chen Y,et al.Effects of thermal treatment on microstructure and mechanical properties of a Mg-Gd-based alloy plate[J].Materials Science and Engineering A,2016,659:63-75.
- [27] Orlova T S,Latynina T A,Murashkin M Y,et al.Effects of Mg on strengthening mechanisms in ultrafine-grained Al-Mg-Zr alloy[J].Journal of Alloys and Compounds,2021,859:157775.
- [28] Frost H J,Ashby M F.Deformation-mechanism maps:the plasticity and creep of metals and ceramics[J].Pergamon Press,Oxford,1982.
- [29] Zha M,Wang S Q,Wang T,et al.Developing high-strength and ductile Mg-Gd-Y-Zn-Zr alloy sheet via bimodal grain structure coupling with heterogeneously-distributed precipitates[J].Materials Research Letters,2023,11(9):772-780.
- [30] Zhang N,Li Q,Chen X,et al.Effect of different extrusion parameters on the microstructure and mechanical properties of Mg-4Sm-3Gd-2Yb-0.5 Zr alloy[J].Journal of Magnesium and Alloys,2024.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||