纳米化3J33钢低温渗氮生成相性能第一性原理表征First-principles characterization on mechanical properties of phases produced during lower temperature nitriding for nanocrystallized 3J33 steel
闫牧夫,刘瑞良,吴业琼,杨茂
摘要(Abstract):
采用固溶处理、热轧、冷拔变形和电加热的复合技术实现了3J33马氏体时效钢纳米化,平均晶粒尺寸约为70nm。对纳米化的马氏体时效钢分别在390℃和360℃进行8h脉冲等离子体渗氮,利用XRD、显微硬度计和纳米硬度计对渗氮层生成相和性能进行了测试,并且基于第一性原理对渗氮相的性能进行了表征。结果表明,两个温度下渗层中生成的氮化相分别为γ′-Fe4N和FeN0.076,二者均具有较高的硬度和良好的塑性。计算结果表明,γ′-Fe4N和FeN0.076相中N与Fe原子的成键作用较强,且两相都具有延性。
关键词(KeyWords): 3J33钢;纳米化;低温离子体渗氮;FeN0.076;第一性原理表征
基金项目(Foundation): 国家自然科学基金(50871035);; 教育部博士点基金(20060213017)
作者(Author): 闫牧夫,刘瑞良,吴业琼,杨茂
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