高氮奥氏体钢粉末的合成及其致密化工艺Synthesis and densification process of high nitrogen austenitic steel powders
崔大伟,魏文庆,刘炳强,曲选辉
摘要(Abstract):
采用机械合金化和高压气雾化两种工艺分别合成了近球形粉末,随后通过粉末注射成形技术制备了0Cr17Mn11Mo3N高氮奥氏体钢材料。用X射线衍射、扫描电镜、拉伸试验等手段研究了粉末和块状材料的结构及性能。结果表明:两种粉末球形度好,颗粒细小,装载量和烧结活性较高,都能够较好满足后续粉末注射成形工艺要求。机械合金化粉末最佳致密化条件是采用真空脱氧+氮气烧结方式,在0.1 MPa氮气压力下于1260℃烧结120 min,烧结体相对密度97.90%,氮含量1.02 mass%,经过1150℃×90 min固溶处理后屈服强度、抗拉强度、伸长率、断面收缩率、维氏硬度分别高达627 MPa、965 MPa、11.3%、16.7%、312HV;高压气雾化粉末最佳致密化条件为0.1 MPa氮气压力下1300℃烧结120 min,烧结体相对密度98.33%,氮含量0.78mass%,经固溶处理后屈服强度、抗拉强度、伸长率、断面收缩率、维氏硬度也分别达到580 MPa、885 MPa、26.0%、29.1%、222HV。由于氮在奥氏体中的强化作用,0Cr17Mn11Mo3N高氮奥氏体钢的强度、硬度等远高于传统注射成形316L奥氏体不锈钢。
关键词(KeyWords): 高氮奥氏体钢;机械合金化;气雾化;粉末;致密化
基金项目(Foundation): 国家自然科学基金项目(51004077);; 山东省优秀中青年科学家科研奖励基金(BS2010CL046)
作者(Author): 崔大伟,魏文庆,刘炳强,曲选辉
DOI: 10.13289/j.issn.1009-6264.2013.12.008
参考文献(References):
- [1]Katada Y,Sagara M,Kobayashi Y,et al.Fabrication of high strength high nitrogen stainless steel with excellent corrosion resistance and its mechanical properties[J].Materials and Manufacturing Processes,2004,19(1):19-30.
- [2]王威,陈淑梅,严伟,等.氮对冷变形高氮奥氏体不锈钢微观结构的作用[J].材料热处理学报,2010,31(7):59-65.WANG Wei,CHEN Shu-mei,YAN Wei,et al.Effects of nitrogen on microstructure of cold deformed high nitrogen austenitic stainless steels[J].Transactions of Materials and Heat Treatment,2010,31(7):59-65.
- [3]Li H B,Jiang Z H,Zhang Z R.Effect of grain size on mechanical properties of nickel-free high nitrogen austenitic stainless steel[J].Journal of Iron and Steel Research,International,2009,16(1):58-61.
- [4]Baba H,Kodama T,Katada Y.Role of nitrogen on the corrosion behavior of austenitic stainless steels[J].Corrosion Science,2002,44:2393-2407.
- [5]Sumita M,Hanawab T,Teoh S H.Development of nitrogen-containing nickel-free austenitic stainless steels for metallic biomaterials-review[J].Materials Science and Engineering C,2004,24(6-8):753-760.
- [6]Reclaru L,Ziegenhagen R,Eschler P Y,et al.Comparative corrosion study of“Ni-free”austenitic stainless steels in view of medical applications[J].Acta Biomaterialia,2006,2(4):433-444.
- [7]Simmons J W.Overview:High-nitrogen alloying of stainless steels[J].Materials Science and Engineering A,1996,207(2):159-169.
- [8]钟海林,况春江,匡星.粉末冶金高氮不锈钢的研究与发展现状[J].粉末冶金工业,2007,17(3):44-47.ZHONG Hai-lin,KUANG Chun-jiang,KUANG Xing.Research and development of high nitrogen stainless steels by powder metallurgy[J].Powder Metallurgy Industry,2007,17(3):44-47.
- [9]Uggowitzer P J,Bhre W F,Wohlfromm H,et al.Nickel-free high nitrogen austenitic stainless steels produced by metal injection moulding[J].Materials Science Forum,1999,318:663-672.
- [10]Aoyama Y,Komada M,Kuroda Y,et al.Mechanical properties of Ni-free high-nitrogen austenitic stainless steel made by metal injection molding with nitrogen absorption method[J].Journal of the Japan Society of Powder and Powder Metallurgy,2009,56(3):103-107.
- [11]Cisneros M M,Lopez H F,Mancha H,et al.Processing of nanostructured high nitrogen stainless steel by mechanical alloying[J].Metallurgical and Materials Transaction A,2005,36(5):1309-1316.
- [12]Amini R,Hadianfard M J,Salahinejad E,et al.Microstructural phase evalution of high-nitrogen Fe-Cr-Mn alloy powders synthesized by the mechanical alloying process[J].Journal of Materials Science,2009,44(1):136-148.
- [13]Tsuchiyama T,Uchida H,Kataoka K,et al.Fabrication of fine-grained high nitrogen austenitic steels through mechanical alloying treatment[J].ISIJ International,2002,42(12):1438-1443.
- [14]李笃信,黄伯云.金属注射成形技术研究进展[J].粉末冶金材料科学与工程,2002,7(1):24-29.LI Du-xin,HUANG Bo-yun.The status in metal injection molding[J].Materials Science and Engineering of Powder Metallurgy,2002,7(1):24-29.
- [15]Xu Z W,Jia C C,Kuang C J,et al.Fabrication and sintering behavior of high-nitrogen nickel-free stainless steels by metal injection molding[J].International Journal of Minerals Metallurgy and Materials,2010,17(4):423-428.
- [16]Uggowitzer P J,Speidel M O,Wohlfromm H,et al.P.A.N.A.C.E.A.provides the answer to Ni allergy[J].Metal Powder Report,1998,53(9):48-52.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||