吐丝温度对82B线棒材氧化层结构与机械剥离性能的影响Influence of spinning temperature on microstructure and mechanical descaling property of oxide layer of 82B wire rod
王军阳,万善宏,易戈文,姜军,成前前,陕钰,王文珍
摘要(Abstract):
为改善82B线棒材表面氧化铁皮的机械除鳞性能,研究了吐丝温度对氧化皮结构与机械剥离性能的影响。结果表明:82B钢线棒材表面氧化皮具有双层状结构,外层为Fe_3O_4,内层为FeO+Fe_3O_4,未检测到明显的Fe_2O_3层。当吐丝温度从880℃升高至930℃时,氧化皮的平均厚度从约14.46μm增加至16.39μm;[FeO+Fe_3O_4]/[Fe_3O_4]层厚比从2.69降至1.98。氧化层-基体界面微空隙层中含有大量Fe_3O_4粒子,微空隙层的数量与尺寸增加。随着吐丝温度的升高,氧化皮剥离形态由大块状转变为小块状与碎屑状,机械剥离表面残留大量以Fe_3O_4为主要组分的氧化铁皮,氧化铁皮临界剥离载荷与粘结强度增加。这表明提高吐丝温度将降低82B钢线棒材表面氧化铁皮的机械剥离性能。
关键词(KeyWords): 82B线棒材;氧化;吐丝温度;氧化铁皮;相结构;机械剥离
基金项目(Foundation): 国家自然科学基金面上项目(52072380,51675508)
作者(Author): 王军阳,万善宏,易戈文,姜军,成前前,陕钰,王文珍
DOI: 10.13289/j.issn.1009-6264.2022-0331
参考文献(References):
- [1] Wei F C,Zhang T,Xu L,et al.Study of phase transformation behavior of SWRH82B high-carbon steel and its abnormal core structure[J].Materials Research Express,2019,6(10):106507.
- [2] Wei H,Chen Y L,Su L,et al.Effect of cooling rate and isothermal temperature on the phase transformation and microstructure evolution in SWRH82B high-carbon steel[J].Materials Research Express,2018,5(8):086506.
- [3] Yu X L,Jiang Z Y,Zhao J W,et al.Crystallographic texture based analysis of Fe3O4/α-Fe2O3 scale formed on a hot-rolled microalloyed steel[J].ISIJ International,2015,55(1):278-284.
- [4] Krzyzanowski M,Beynon J H,Farrugia D C J.Oxide Scale Behavior in High Temperature Metal Processing[M].Germany:Wiley-VCH Verlag GmbH & Co.KGaA,2010.
- [5] Tominaga J,Wakimoto K Y,Mori T,et al.Manufacture of wire rods with good descaling property[J].Transactions of the Iron and Steel Institute of Japan,1982,22(8):646-656.
- [6] Gillstr?m P,Jarl M.Mechanical descaling of wire rod using reverse bending and brushing[J].Journal of Materials Processing Technology,2005,172(3):332-340.
- [7] Parusov V V,Sav’Yuk A N,Sychkov A B,et al.Study of the possibilities for maximizing scale removal from wire rod before drawing[J].Metallurgist,2004,48(5/6):292-297.
- [8] Hu X J,Zhang B M,Chen S H,et al.Oxide scale growth on high carbon steel at high temperatures[J].Journal of Iron and Steel Research(International),2013,20(1):47-52.
- [9] Chattopadhyay A,Kumar P,Roy D.Study on formation of “easy to remove oxide scale” during mechanical descaling of high carbon wire rods[J].Surface & Coatings Technology,2009,203(19):2912-2915.
- [10] Confente M,Geneve D,Resiak B.Effects of mechanical descaling on the surface of low carbon wire rod for drawing or cold heading[J].Wire Journal International,1995,28(2):238-242.
- [11] Wanda M,Henk B,Marco R,et al.Experimental study on primary scale formation and descalability on steels containing Ni and Ni+Si[J].ISIJ International,2013,53(5):866-873.
- [12] Takeda M,Kushida H,Onishi T,et al.Influence of oxidation temperature and Cr content on the adhesion and microstructure of scale on low Cr steels[J].Oxidation of Metals,2010,73(1/2):1-13.
- [13] 彭玉.72A高碳钢盘条氧化铁皮组织结构及机械剥离性控制研究[D].武汉:武汉科技大学,2018.PENG Yu.Research on microstructure and controlling of mechanical peeling properties of iron oxide scale of 72A cord steel wire rod[D].Wuhan:Wuhan University of Science and Technology,2018.
- [14] 郭大勇,高航,任玉辉,等.轧制和吐丝温度对高碳钢盘条氧化铁皮机械除鳞性能影响研究[J].钢铁研究学报,2013,25(12):23-27.GUO Da-yong,GAO Hang,REN Yu-hui,et al.Effect of rolling and laying temperatures on mechanical descalability of high carbon steel wire rod[J].Journal of Iron and Steel Research,2013,25(12):23-27.
- [15] 付松岳,任勇,程晓茹,等.高碳钢盘条三次氧化铁皮机械剥离性能[J].钢铁,2016,51(3):73-77.FU Song-yue,REN Yong,CHENG Xiao-ru,et al.Descaling property of third oxide scale of high carbon steel wire[J].Iron and Steel,2016,51(3):73-77.
- [16] 张玉海.SWRH82A盘条氧化铁皮结构研究与应用[J].金属制品,2022,48(1):28-31.ZHANG Yu-hai.Research and application of oxide scale structure of SWRH82A wire rod[J].Metal Products,2022,48(1):28-31.
- [17] 沈奎,张宇,于学森,等.高碳钢盘条表面氧化铁皮剥离性能研究[J].钢铁研究学报,2021,33(11):1198-1203.SHEN Kui,ZHANG Yu,YU Xue-sen,et al.Research on peeling properties of oxide scale of high carbon steel wire rod[J].Journal of Iron and Steel Research,2021,33(11):1198-1203.
- [18] Genève D,Rouxel D,Pigeat P,et al.Descaling ability of low-alloy steel wires depending on composition and rolling process[J].Corrosion Science,2009,52(4):1155-1166.
- [19] Pieraggi B,Rapp R A,Hirth J P.Role of interface structure and interfacial defects in oxide scale growth[J].Oxidation of Metals,1995,44(1/2):63-79.
- [20] Malik A U,Whittle D P.Oxidation of Fe-C alloys in the temperature range 600-850 ℃[J].Oxidation of Metals,1981,16(5/6):339-353.
- [21] Kofstad P.On the formation of porosity and microchannels in growing scales[J].Oxidation of Metals,1985,24(5/6):265-276.
- [22] Hsu H S.The formation of multilayer scales on pure metals[J].Oxidation of Metals,1986,26(5/6):315-332.
- [23] Young D J.High Temperature Oxidation and Corrosion of Metals[M].Netherlands:Elsevier Science,2016.
- [24] Chen R Y,Yuen W.A study of the scale structure of hot-rolled steel strip by simulated coiling and cooling[J].Oxidation of Metals,2000,53(5/6):539-560.
- [25] Yu X L,Jiang Z Y,Zhao J W,et al.Effect of a grain-refined microalloyed steel substrate on the formation mechanism of a tight oxide scale[J].Corrosion Science,2014,85:115-125.
- [26] Peng X,Yan J,Zhou Y,et al.Effect of grain refinement on the resistance of 304 stainless steel to breakaway oxidation in wet air[J].Acta Materialia,2005,53(19):5079-5088.
- [27] Herchl R,Khoi N N,Homma T,et al.Short-circuit diffusion in the growth of nickel oxide scales on nickel crystal faces[J].Oxidation of Metals,1972,4(1):35-49.
- [28] Gleeson B,Hadavi S M M,Young D J.Isothermal transformation behavior of thermally-grown wüstite[J].Materials at High Temperatures,2000,17(2):311-318.
- [29] Ilschner B,Mlitzke E.Ausscheidungskinetik in wüstit (Fe1-xO)[J].Acta Metallurgica,1965,13(7):855-867.
- [30] Saito Y,Watanabe H,Yamada T,et al.Interfacial strength evaluation of oxide films on carbon steel by using the laser shock adhesion test[J].Journal of Materials Engineering and Performance,2019,28(8):4762-4773.
- [31] Ambhorn S C,Klubvihok N.Quantification of adherence of thermal oxide scale on low carbon steel using tensile test[J].Oxidation of Metals,2016,85(1/2):103-125.
- [32] Novikov V I.Grain Growth and Control of Microstructure and Texture in Polycrystalline Materials[M].Spain:Taylor & Francis Group,1997.
- [33] 张校诚.Q235带钢表面氧化铁皮破裂机理及实验研究[D].太原:太原科技大学,2016.ZHANG Xiao-cheng.The theoretical and experimental study of Q235 steel strip surface oxide scales fracture[D].Taiyuan:Taiyuan University of Science and Technology,2016.
- [34] Valentin B,Entela D,Pierre F,et al.Characterization of oxide scales formed on ferritic stainless steel 441 at 1100 ℃ under water vapor[J].Oxidation of Metals,2014,82(5/6):347-357.
- [35] Faria L,Silva V S,Oliveira M.Raman microspectroscopy of some iron oxides and oxyhydroxides[J].Journal of Raman Spectroscopy,1997,28(11):873-878.
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