C422钢气体渗氮及其缺口敏感性Gas nitriding and notch sensitivity of C422 steel
张健,缪春辉,秦小龙,王若民,陈国宏,汤文明
摘要(Abstract):
在氨气气氛下对C422 (22Cr12NiMoWV)钢进行两段式气体渗氮,并研究了渗氮层的显微组织结构以及渗氮后C422钢的室温及高温力学性能,评价渗氮对该钢缺口敏感性的影响。结果表明:C422钢的渗氮层具有三层结构:表层为主要由Fe_3N、Fe_4N和CrN构成的化合物层,中间层为致密的α-Fe(N)扩散层,内层为α-Fe(N)相扩散进入钢基体而形成的过渡层。与未渗氮试样相比,随着渗氮时间延长,有无缺口C422钢渗氮试样的室温、高温拉伸强度和伸长率单调下降,屈服强度先增大后减小。渗氮层的断裂模式为解理断裂的脆性断裂。气体渗氮导致C422钢的室温缺口敏感性增大,但对其高温缺口敏感性影响不大。
关键词(KeyWords): C422钢;两段式气体渗氮;渗氮层;解理断裂;缺口敏感性
基金项目(Foundation): 安徽新力电业科技咨询有限责任公司科研项目(2016咨-CL-02)
作者(Author): 张健,缪春辉,秦小龙,王若民,陈国宏,汤文明
DOI: 10.13289/j.issn.1009-6264.2021-0643
参考文献(References):
- [1]Hradil D,Duchek M,HrbáˇckováT,et al.Gas nitriding with deep cryogenic treatment of high-speed steel[J].Acta Metallurgica Slovaca,2018,24(2):187-193.
- [2]张洲全,涂湛,何可龙,等.汽轮机高压主汽阀阀杆断裂原因分析[J].汽轮机技术,2016,58(1):78-80.ZHANG Zhou-quan,TU Zhan,HE Ke-long,et al.Fracture analysis of high pressure main steam valve stem of steam turbine[J].Turbine Technology,2016,58(1):78-80.
- [3]张涛,田峰,陈浩,等.超临界汽轮机中压调速汽阀2Cr12Ni Mo1W1V钢阀杆断裂原因分析[J].理化检验(物理分册),2015,51(4):278-282.ZHANG Tao,TIAN Feng,CHEN Hao,et al.Fracture analysis of 2Cr12Ni Mo1W1V steel stem of medium pressure governing valve for supercritical steam turbine[J].Physical and Chemical Analysis (Physical Testing),2015,51(4):278-282.
- [4]张健,缪春辉,秦小龙,等.某超临界汽轮机主汽阀杆断裂原因分析[J].装备环境工程,2021,18(6):130-135.ZHANG Jian,MIAO Chun-hui,QIN Xiao-long,et al.Failure analysis on main steam valve stem of an ultra-supercritical turbine[J].Equipment Environmental Engineering,2021,18(6):130-135.
- [5]方梦莎,张津,连勇,等.马氏体不锈钢不同渗氮方法对比试验[J].金属热处理,2021,46(10):221-225.FANG Meng-sha,ZHANG Jin,LIAN Yong,et al.Comparative test on different nitriding methods for martensitic stainless steel[J].Heat Treatment of Metals,2021,46(10):221-225.
- [6]Yang J,Liu Y,Ye Z,et al.Microstructural and tribological characterization of plasma-and gas-nitrided 2Cr13 steel in vacuum[J].Materials&Design,2011,32(2):808-814.
- [7]杨强云,赵辉,杨川,等.两段式气体渗氮对35Cr Mo钢疲劳和腐蚀性能的影响[J].热加工工艺,2015,44(12):207-210.YANG Qiang-yun,ZHAO Hui,YANG Chuan,et al.Effect of two stage gas nitriding process on fatigue and corrosion properties of35Cr Mo steel[J].Hot Working Technology,2015,44(12):207-210.
- [8]李德彬,王宇,刘飞.1Cr11Ni23Ti3Mo B材料气体渗氮工艺研究[J].航空精密制造技术,2021,57(1):48-50.LI De-bin,WANG Yu,LIU Fei.Research on 1Cr11Ni23Ti3Mo B material gas-nitridation technology[J].Aviation Precision Manufacturing Technology,2021,57(1):48-50.
- [9]Hussain P,Mahmoud H,Basha S N,et al.Correlation between microstructure and micro-hardness of 316L nitrided austenitic stainless steel[J].IOP Conference Series:Materials Science and Engineering,2020,863(1):12-25.
- [10]Kim Y M,Son S W,Lee W B.Thermodynamic and kinetic analysis of formation of compound layer during gas nitriding of AISI1018carbon steel[J].Metals and Materials International,2018,24(1):180-186.
- [11]Nam N D,Xuan N A,Van B N,et al.Control gas nitriding process:A review[J].Journal of Mechanical Engineering Research and Developments,2019,42(1):17-25.
- [12]王津,洪悦,陈兴岩,等.氮化势对低碳钢气体渗氮化合物层组织结构和性能的影响[J].材料热处理学报,2016,37(8):168-176.WANG Jin,HONG Yue,CHEN Xing-yan,et al.Effect of nitriding potential on microstructure and properties of compound layer for low-carbon steel under gas nitriding[J].Transactions of Materials and Heat Treatment,2016,37(8):168-176.
- [13]Emilia W K,Jerzy M,Barbara K.Kinetic aspects of low-pressure nitriding process[J].Vacuum,2018,155(9):292-299.
- [14]Widi K A,Wardana W,Suprapto W O,et al.White layer control on AISI 316L using temperature and gas nitriding diffusion stage process[J].International Review of Mechanical Engineering,2017,11(8):613-618.
- [15]Yang M,Sisson R D.Alloy effects on the gas nitriding process[J].Journal of Materials Engineering and Performance,2014,23(12):4181-4186.
- [16]Tschiptschin A P.Predicting microstructure development during high temperature nitriding of martensitic stainless steels using thermodynamic modeling[J].Materials Research,2002,5(3):257-262.
- [17]Widi K A,Wardana I,Suprapto W,et al.The role of diffusion media in nitriding process on surface layers characteristics of AISI4140 with and without hard chrome coatings[J].Tribology in Industry,2016,38(3):308-317.
- [18]Kundalkar D,Mavalankar M,Tewari A.Effect of gas nitriding on the thermal fatigue behavior of martensitic chromium hot-work tool steel[J].Materials Science and Engineering A,2016,651(1):391-398.
- [19]Karadas R,Celik O,Cimenoglu H.Low temperature nitriding of a martensitic stainless steel[J].Defect and Diffusion Forum,2011,312-315(4):994-999.
- [20]胡胜天,刘永,王建坤,等.1Cr12Ni3Mo VN钢渗氮层的组织与性能[J].金属热处理,2019,44(6):6-10.HU Sheng-tian,LIU Yong,WANG Jian-kun,et al.Microstructure and properties of nitrided layer for 1Cr12Ni3Mo VN steel[J].Heat Treatment of Metals,2019,44(6):6-10.
- [21]Watkins K.Fundamentals of gas nitriding[J].Aluminium International Today,2017,30(2):38-39.
- [22]Farghali A,Aizawa T.Phase transformation induced by high nitrogen content solid solution in the martensitic stainless steels[J].Materials Transactions,2017,58(4):697-700.
- [23]Shankar V,Valsan M,Rao K B S,et al.Effects of temperature and strain rate on tensile properties and activation energy for dynamic strain aging in alloy 625[J].Metallurgical and Materials Transactions A,2004,35(10):3129-3139.
- [24]鲁家瑞,朱鹏程,沈寅忠.11Cr3W3Co钢在不同温度下拉伸时的锯齿流变行为[J].机械工程材料,2017,41(3):13-18.LU Jia-rui,ZHU Peng-cheng,SHEN Yin-zhong.Serranted flow behavior of 11Cr3W3Co steel during tension at different temperatures[J].Materials for Mechanical Engineering,2017,41(3):13-18.
- [25]符师桦.合金中锯齿形屈服现象的实验和理论研究[D].合肥:中国科学技术大学,2013.FU Shi-hua.Experimental and theoretical investigations on serrated yielding phenomenon in alloys[D].Hefei:University of Science and Technology of China,2013.
- [26]孟丽君,庞淦文,邢辉,等.AL6XN超级奥氏体钢高温拉伸时的动态应变时效[J].材料热处理学报,2010,31(4):50-54.MENG Li-jun,PANG Gan-wen,XING Hui,et al.Dynamic strain aging effect during high-temperature tensile test of AL6XN super austenite steel[J].Transactions of Materials and Heat Treatment,2010,31(4):50-54.
- [27]王若民,段谟刚,张健,等.电站锅炉用HR3C钢管表面裂纹临界尺寸[J].材料热处理学报,2021,42(3):125-134.WANG Ruo-min,DUAN Mo-gang,ZHANG Jian,et al.Critical surface crack size of HR3C steel tube for power station boiler[J].Transactions of Materials and Heat Treatment,2021,42(3):125-134.
- [28]王若民,段谟刚,张健,等.服役态HR3C耐热钢管的缺口敏感性[J].材料热处理学报,2020,41(10):66-72.WANG Ruo-min,DUAN Mo-gang,ZHANG Jian,et al.Notch sensitivity of in-service HR3C heat resistant steel tube[J].Transactions of Materials and Heat Treatment,2020,41(10):66-72.
- [29]陈大明,康沫狂.飞机起落架用钢贝氏体组织的屈强比问题[J].航空学报,1993,14(8):377-382.CHEN Da-ming,KANG Mo-kuang.On yield to ultimate tensile strength ratio of bainitic microstructure in a steel for aircraft landing gear[J].Acta Aeronautica et Astronautica Sinica,1993,14(8):377-382.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||