42CrMo钢离子氮碳氧多元共渗及动力学分析Plasma oxynitrocarburising of 42CrMo steel and kinetics analysis
缪斌,刘晗,范琪,胡静
摘要(Abstract):
以42CrMo钢为材料,通过在离子氮碳共渗过程中添加空气进行离子氮碳氧多元共渗。采用扫描电镜、光学显微镜、X射线衍射仪和显微硬度计对渗层形貌、渗层厚度、渗层物相和截面硬度进行分析。研究结果表明,在传统离子氮碳共渗过程中添加适量的空气具有显著的催渗效果,且以空气流量为0.3 L/min的效果最佳,截面硬度也得到大幅度提高。离子氮碳氧多元共渗中氮原子的扩散激活能从传统离子氮碳共渗的56.12 k J/mol降低到25.27 k J/mol。同时,对离子氮碳氧多元共渗的机理进行了分析。
关键词(KeyWords): 空气;42CrMo钢;离子氮碳氧多元共渗;动力学
基金项目(Foundation): 江苏省科技成果转化项目(BA2013078);; 江苏省研究生创新基金(SCZ100431322)
作者(Author): 缪斌,刘晗,范琪,胡静
DOI: 10.13289/j.issn.1009-6264.2016.08.031
参考文献(References):
- [1]李杨,徐久军,王亮.42Cr Mo钢表面纳米化对离子渗氮的影响[J].中国表面工程,2010,23(3):60-63.LI Yang,XU Jiu-jun,WANG Liang.Plasma nitriding of 42Cr Mo steel with a nanostructured surface layer induced by surface mechanical attrition treatment[J].China Surface Engineering,2010,23(3):60-63.
- [2]武计强,李虎,李景才,等.42Cr Mo钢的空气离子后氧化[J].材料热处理学报,2015,36(3):78-82.WU Ji-qiang,LI Hu,LI Jing-cai,et al.Post-oxidation treatments of plasma nitrided 42Cr Mo steel[J].Transactions of Materials and Heat Treatment,2015,36(3):78-82.
- [3]乔玉林,胡春华,赵玉强,等.连续加载条件下纳米Al2O3/Fe S固体润滑复合涂层的摩擦学性能[J].摩擦学学报,2010,30(6):561-566.QIAO Yu-lin,HU Chun-hua,ZHAO Yu-qiang,et al.Ttribological properties of nano-Al2O3/Fe S solid lubricant composite coatings under a continuous loading at elevated temperature[J].Tribology,2010,30(6):561-566.
- [4]Ichimura H,Ishii Y,Rodrigo A.Hardness analysis of duplex coating[J].Surface and Coatings Technology,2003,169/170:735-738.
- [5]Liu H,Li J C,Chai Y T,et al.A novel plasma oxynitriding by using plain air for AISI 1045 steel[J].Vacuum,2015,121:18-21.
- [6]Zhou H,Chen F,Yao B,et al.Research on the properties of inside surface of subsurface pump barrel by N-C-O multi-elements penetrating[J].Surface and Coatings Technology,2007,201:5165-5167.
- [7]Liu L F,Zhou S Q,Ren Q.Plasma oxynitrocarburizing of 40Cr steel in an atmosphere of gasoline and air[J].Applied Surface Science,2007,253:6744-6748.
- [8]杜树芳,巢云飞,杜恒山.汽车模具的离子渗氮[J].金属热处理,2006,31(11):81-85.DU Shu-fang,CHAO Yun-fei,DU Heng-shan.Plasma nitriding of auto dies[J].Heat Treatment of Metals,2006,31(11):81-85.
- [9]Chen F S,Wang K L.The kinetics and mechanism of multi-component diffusion on AISI 1045 steel[J].Surface and Coatings Technology,1999,115:239-248.
- [10]Sen S,Sen U,Bindal C.An approach to kinetic study of borided steels[J].Surface and Coatings Technology,2005,191:274-285.
- [11]Neil Birks,Gerald H Meier,Frederick S Pettit.金属高温氧化导论[M].辛丽,王文译.北京:高等教育出版社,2010.
- [12]刘晗,庄晔,孙斐,等.空气流量对45钢离子氮氧共渗的影响[J].真空科学与技术学报,2015,35(12):1427-1430.LIU Han,ZHUANG Ye,SUN Fei,et al.Effect of air flow-rate on plasma oxynitridation of 45-steel surfaces[J].Chinese Journal of Vacuum Science and Technology,2015,35(12):1427-1430.
- [13]李景才,孙斐,王树凯,等.离子渗氮前预氧化催渗作用及机理[J].材料热处理学报,2014,35(7):182-186.LI Jing-cai,SUN Fei,WANG Shu-kai,et al.Catalysis effect and mechanism of pre-oxidation on direct current plasma nitriding[J].Transactions of Materials and Heat Treatment,2014,35(7):182-186.
- [14]LI J C,YANG X M,WANG S K,et al.A rapid D.C.plasma nitriding technology catalyzed by pre-oxidation for AISI4140 steel[J].Materials Letters,2014,116:199-202.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||