陈长风,郑树启,姜瑞景,陈立强

• 1:中国石油大学(北京)机电学院

摘要(Abstract)：

利用高温高压哈氏合金反应釜对P110SS油套管钢在不同H2S和CO2环境下的腐蚀行为进行了实验。研究了H2S和CO2分压对P110SS油套管钢腐蚀规律的影响,利用SEM、EDS、XRD等方法分析了腐蚀试样的微观形貌与结构特征,发现P110SS在较低温度条件下,H2S浓度非常低时,腐蚀特征与单纯CO2腐蚀规律相似,腐蚀速率比较高。在相同的H2S分压条件下,随CO2浓度增加,腐蚀速率依次增加。通过应力腐蚀开裂试验表明,P110SS在高温205℃条件下应力腐蚀开裂敏感较小。

关键词(KeyWords)： H2S和CO2环境;P110SS钢;腐蚀规律;应力腐蚀开裂

Abstract:

Keywords:

基金项目(Foundation): 国家自然科学基金(50871122、50771104);; 教育部科学技术研究重点项目(106035)

作者(Author): 陈长风,郑树启,姜瑞景,陈立强

参考文献(References)：

• [1]杨怀玉,陈家坚.酸性H2S溶液中碳钢的腐蚀行为及硫化物膜的生长[J].中国腐蚀与防护学报,2000,20(1):126.YANG Huai-yu,CHEN Jia-jian.Corrosion behavior of carbon steel and growth of sulfide film on it in acidic solutions containing H2S[J].Journal of ChineseSociety for Corrosion and Protection,2000,20(1):126.
• [2]张玉芳.H2S分压对SM 80SS油管钢腐蚀行为的影响[C].西部油田腐蚀与防护论坛.长春:吉林科学技术出版社,2006:145~148.
• [3]白真权,李鹤林,刘道新,等.模拟油田H2S/CO2环境中的N80钢的腐蚀及影响因素研究[J].材料保护,2003,36(4):32.BAI Zhen-quan,LI He-lin,LIU Dao-xin,et al.Corrosion factors of N80 steel in simulated H2S/CO2environment[J].Materials Protection,2003,36(4):32.
• [4]Singer M,Brown B,Camacho A,et al.Combined effect of CO2,H2S and acetic acidon bottom of the line corrosion[J].NACE Corrosion Paper,2007:07661.
• [5]Jiabin H,Yang Y,Bruce B,et al.Electrochemical investigation oflocalized CO2corrosion on mild steel[J].NACE Corrosion Paper,2007:07323.
• [6]Serna S,Fragiel A.Effect of different microstructures and strengths on the cracking resistance of microalloyed pipeline steels in sour environments[J].NACECorrosion Paper,2006:06654.
• [7]Richard L,Martin,Patrick D Logan.Corrosion properties and inhibition of common austenitic stainless steels in sweet and sour oilfield fluids[J].NACECorrosion Paper,2006:06367.
• [8]Yin Z F,Zhao W Z,Bai Z Q,et al.Corrosion behavior of SM 80SS tube steel in stimulant solution containing H2S and CO2[J].Electrochimica Acta,2008,53:3690-3700.
• [9]NACE MR0175-2003.Metals for sulfide stress cracking and stress corrosion cracking resistance in sour oilfield environments[S].2003.
• [10]罗媛媛,袁宗明,刘志成.硫化氢腐蚀数据库的建立[J].炼油与化工,2007,18(2):1.LUO Yuan-yuan,YUAN Zong-ming,LIU Zhi-cheng.Establishment of hydrogen sulfide corrosion database[J].Refining and Chemical Industry,2007,18(2):1.

文章评论(Comment)：