Ce含量对Mg-2Zn-0.4Zr-xCe生物镁合金组织及耐蚀性的影响Effects of Ce on microstructure and properties of Mg-2Zn-0.4Zr-xCe biomedical magnesium alloys
雷少帆,文九巴,姚怀,贺俊光,刘亚
摘要(Abstract):
研究了不同Ce含量对Mg-2Zn-0.4Zr-x Ce生物镁合金组织及耐蚀性的影响。通过拉伸试验、电化学测试、SEM分析等手段对合金的力学性能、耐蚀性及显微组织进行了研究。结果表明:当Ce含量在低于1 mass%的范围内,随着Ce含量的增加,第二相沿着晶界析出并且逐渐增多,晶粒细化,力学性能和耐蚀性逐渐提高;Ce含量为0.6 mass%时,合金的力学性能与耐蚀性较佳,抗拉强度约为140.13 MPa,伸长率约为9.47%,腐蚀速率约为0.776 mg·cm~(-2)·d~(-1);当Ce含量大于0.6 mass%时,腐蚀速率有增大的趋势,力学性能变化不明显。
关键词(KeyWords): 生物镁合金;稀土Ce;耐蚀性
基金项目(Foundation): 河南省“新型有色金属材料”高校科技创新团队支持计划(2012IRTSTHN008);; 河南省教育厅重点项目(15A430024)
作者(Author): 雷少帆,文九巴,姚怀,贺俊光,刘亚
DOI: 10.13289/j.issn.1009-6264.2016.10.018
参考文献(References):
- [1]Witte F.The history of biodegradable magnesium implants:a review[J].Acta Biomaterialia,2015,23:S28-S40.
- [2]Jitka Pelcova,Bohumil Smola,Ivana Stulikova.Influence of processing technology on phase transformations in a rare-earth-containing Mg-Zn-Zr alloy[J].Materials Science and Engineering A,2007,462:334-338.
- [3]高亚丽,熊党生.医用镁合金等离子喷涂羟基磷灰石涂层研究材料[J].材料热处理学报,2011,32(1):109-113.GAO Ya-li,XIONG Dang-sheng.Study on plasma sprayed hydroxyapatite coating on magnesium alloy[J].Transactions of Materials and Heat Treatment,2011,32(1):109-113.
- [4]姜海英,艾红军.生物可降解镁合金植入材料的医用特征[J].中国组织工程研究与临床康复,2011,34(15):6411-6415.JIANG Hai-ying,AI Hong-jun.Medical characteristics of degradable magnesium alloy as medical implant materials[J].Journal of Clinical Rehabilitative Tissue Engineering Research,2011,34(15):6411-6415.
- [5]Seitz J M,Eifler R,Stahl J.Characterization of Mg Nd2 alloy for potential applications in bioresorbable implantable devices[J].Acta Biomaterialia2012,8:3852-3864.
- [6]宋光玲.镁合金腐蚀与防护[M].北京:化学工业出版社,2006.
- [7]Staiger M P,Pietak J.Huadmai,et al.Magnesium and its alloys as orthopedic biomaterials:a review[J].Biomaterials,2006,27:1728-1734.
- [8]W F Ng,Chiu K Y,Cheng F T.Effect of p H on the vitro corrosion rate of magnesium degradable implant material[J].Materials Science and Engineering C,2010,30(6):898-903.
- [9]王昌,崔亚军,刘汉源,等.可生物降解医用镁合金的合金化研究进展[J].材料导报,2015,29(6):55-60.WANG Chang,CUI Ya-jun,LIU Han-yuan,et al.Research progress on the alloying of biodegradable magnesium alloys[J].Materials Review,2015,29(6):55-60.
- [10]Daeho Hong,Partha Saha,Da-Tren Chou,et al.In vitro degradation and cytotoxicity response of Mg-4%Zn-0.5%Zr(ZK40)alloy as a potential biodegradable material[J].Acta Biomaterials,2013,9:8534-8547.
- [11]张清,李全安,文九巴,等.稀土在镁合金腐蚀防护中的应用[J].腐蚀科学与防护技术,2007,2(19):119-121.ZHANG Qing,LI Quan-an,WEN Jiu-ba,et al.Application of rare earth in corrosion prevention of magnesium alloy[J].Corrosion Science and Protection Technology,2007,2(19):119-121.
- [12]巫瑞智,张景怀,尹冬松,等.先进镁合金制备与加工技术[M].北京:科学出版社,2012.
- [13]YANG Mingbo,GUO Tingzhang,QIN Caiyuan,et al.Microstructure,tensile and creep properties of as-cast Mg-3.8Zn-2.2Ca-x Ce(x=0,0.5,1 and 2wt.%)magnesium alloys[J].Journal of Rare Earths,2012,2:181-188.
- [14]Mingli HUANG,Hongxiao LI,Hua DING.Intermetallics and phase relations of Mg-Zn-Ce alloys at 400℃[J].Transactions of Nonferrous Metals Society of China,2012,3(22):539-545.
- [15]卢立伟.镁合金挤压变形的组织性能与工艺研究[D].重庆:重庆大学,2012.
- [16]刘莹,王炳德,王忠堂.挤压变形对镁合金组织与力学性能的影响[J].材料热处理学报,2011,32(5):51-54.LIU Ying,WANG Bing-de,WANG Zhong-tang.Influence of extrusion deformation on microstructure and mechanical properties of magnesium alloy[J].Transactions of Materials and Heat Treatment,2011,32(5):51-54.
- [17]ZHANG Xiao-bo,YUAN Guang-yin,MAO Lin,et al.Effects of extrusion and heat treatment on the mechanical properties and biocorrosion behaviors of a Mg-Nd-Zn-Zr alloy[J].Journal of the Mechanical Behavior of Biomedical Materials,2012,3(7):77-86.
- [18]Ascencio M,Pekguleryuz M.An investigation of the corrosion mechanisms of WE43 Mg alloy in a modified simulated body fluid solution:The influence of immersion times[J].Corrosion Science,2014,87:489-503.
- [19]LI Tao,HE Yong,ZHENG Hai-long.Microstructure,mechanical property and in vitro biocorrosion behavior of single-phase biodegradable Mg-1.5Zn-0.6Zr alloy[J].Journal of Magnesium and Alloys,2014,2:181-189.
- [20]ZHANG Fan,MA Aibin,SONG Dan.Improving in-vitro biocorrosion resistance of Mg-Zn-Mn-Ca alloy in Hank’s solution through addition of cerium[J].Journal of Rare Earths,2015,33(1):93-103.
- [21]Lu Y,Bradshaw A R,Chiu Y L.The role of precipitates in the bio-corrosion performance of Mg-3Zn in simulated body fluid[J].Journal of Alloys and Compounds,2014,614:345-352.
- [22]章晓波,王章忠,袁广银.二次挤压对Mg-Nd-Zn-Zr生物镁合金组织与性能的影响[J].材料热处理学报,2013,34(2):103-107.ZHANG Xiao-bo,WANG Zhang-zhong,YUAN Guang-yin.Effects of double extrusion on microstructure and properties of Mg-Nd-Zn-Zr bio-magnesium alloy[J].Transactions of Materials and Heat Treatment,2013,34(2):103-107.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||