改型617合金的铸态组织特征及均匀化工艺As-cast microstructure and homogenization process of modified alloy 617
吴贇,聂义宏,赵帅,白亚冠,朱怀沈,姜萍
摘要(Abstract):
利用扫描电镜分析、模拟热处理等方法,研究了700℃超超临界电站汽轮机转子用改型617合金双真空冶炼(VIM+ESR)后的铸态组织特征和均匀化热处理后的微观组织变化。结果表明,铸态组织存在明显的偏析,主要偏析元素为Mo和Ti,偏聚于枝晶间;枝晶间和晶界上分布有块状和连续的碳化物;均匀化热处理后枝晶明显消除,块状碳化物部分溶解,晶界连续碳化物充分溶解;该合金成分均匀化主要受Mo原子扩散控制。提出改型617合金均匀化热处理工艺应为1180~1200℃保温24 h以上。
关键词(KeyWords): 617高温合金;偏析;均匀化;700℃超超临界
基金项目(Foundation):
作者(Author): 吴贇,聂义宏,赵帅,白亚冠,朱怀沈,姜萍
DOI: 10.13289/j.issn.1009-6264.2015.07.025
参考文献(References):
- [1]Viswanathan R,Coleman K,Rao U.Materials for ultra-supercritical coal-fired power plant boilers[J].International Journal of Pressure Vessels and Piping,2006,83(11):778-783.
- [2]Jablonski P D,Hawk J A,Cowen C J,et al.Processing of advanced cast alloys for A-USC steam turbine applications[J].JOM,2012,64(2):271-279.
- [3]Rahman S,Priyadarshan G,Raja K S,et al.Investigation of the secondary phases of Alloy 617 by scanning kelvin probe force microscope[J].Materials Letters,2008,62(15):2263-2266.
- [4]Roster J,Gotting M,Del Genovese D,et al.Wrought Ni-base superalloys for steam turbine applications beyond 700℃[J].Advanced Engineering Materials,2003,5(7):469-483.
- [5]Akbari-Garakani M,Mehdizadeh M.Effect of long-term service exposure on microstructure and mechanical properties of Alloy 617[J].Materials&Design,2011,32(5):2695-2700.
- [6]郭岩,周荣灿,侯淑芳,等.617合金760℃时效组织结构及力学性能分析[J].中国电机工程学报,2010,30(26):86-89.GUO Yan,ZHOU Rong-can,HOU Shu-fang,et al.Analysis of microstructure and mechanical properties of alloy 617 aged at 760℃[J].Proceedings of the CSEE,2010,30(26):86-89.
- [7]Blaes N,Donth B,Diwo A,et al.Advanced forgings for highly efficient fossil power plants[C]//Advances in Materials Technology for Fossil Power Plants:Proceedings from the Sixth International Conference,August 31-September 3,2010,Santa Fe,New Mexico,USA.ASM International,2011:436-449.
- [8]Zhao S,Xie X,Smith G D,et al.Microstructural stability and mechanical properties of a new nickel-based superalloy[J].Materials Science and Engineering A,2003,355(1):96-105.
- [9]Zhao S,Xie X,Smith G D,et al.Research and improvement on structure stability and corrosion resistance of nickel-base superalloy INCONEL alloy740[J].Materials and Design,2006,27(10):1120-1127.
- [10]余永宁.材料科学基础[M].北京:高等教育出版社,2006.
- [11]Flemings M C.Solidification processing[J].Metallurgical Transactions,1974,5(10):2121-2134.
- [12]王珏,董建新,张麦仓,等.700℃以上超超临界电站锅炉过热器管材用典型镍基合金的平衡析出相规律[J].北京科技大学学报,2012,34(7):799-807.WANG Jue,DONG Jian-xin,ZHANG Mai-cang,et al.Equilibrium-phase precipitation behaviors of typical nickel-base alloys for 700℃advanced ultra-supercritical boiler tubes[J].Journal of University of Science and Technology Beijing,2012,34(7):799-807.
- [13]Gariboldi E,Cabibbo M,Spigarelli S,et al.Investigation on precipitation phenomena of Ni-22Cr-12Co-9Mo alloy aged and crept at high temperature[J].International Journal of Pressure Vessels and Piping,2008,85(1):63-71.
- [14]Wu Q,Song H,Swindeman R W,et al.Microstructure of long-term aged IN617 ni-base superalloy[J].Metallurgical and Materials Transactions A,2008,39(11):2569-2585.
- [15]姚志浩,董建新,张麦仓,等.固溶及稳定化工艺对GH738合金碳化物和γ'相析出规律的影响[J].材料热处理学报,2013,34(10):43-49.YAO Zhi-hao,DONG Jian-xin,ZHANG Mai-cang,et al.Influence of solution and stabilization heat treatment on carbide and gamma prime for super alloy GH738[J].Transactions of Materials and Heat Treatment,2013,34(10):43-49.
- [16]于秋颖,董建新,张麦仓,等.GH710高温合金长期时效中的组织演变[J].材料热处理学报,2013,34(3):84-88.YU Qiu-ying,DONG Jian-xin,ZHANG Mai-cang,et al.Microstructure evolution of GH710 superalloy after long time aging[J].Transactions of Materials and Heat Treatment,2013,34(3):84-88.
- [17]王珏,吴赟,董建新,等.700℃超超临界锅炉材料GH4700合金铸态组织及均匀化工艺[J].稀有金属材料与工程,2013,42(9):1908-1914.WANG Jue,WU Yun,DONG Jian-xin,et al.Microstructure and homogenization of as-cast GH4700 alloy for 700℃ultra-supercritical boilers[J].Rare Metal Materials and Engineering,2013,42(9):1908-1914.
- [18]马兹·希拉特.合金扩散和热力学[M].赖和怡,刘国勋,译.北京:冶金工业出版社,1984.
- [19]Liu X,Pan Q,Fan X,et al.Microstructural evolution of Al-Cu-Mg-Ag alloy during homogenization[J].Journal of Alloys and Compounds,2009,484(1):790-794.
- [20]Karunaratne M S A,Cox D C,Carter P,et al.Modelling of the microsegregation in CMSX-4 superalloy and its homogenization during heat treatment[J].Superalloy 2000,2000:263-272.
- [21]Semiatin S L,Kramb R C,Turner R E,et al.Analysis of the homogenization of a nickel-base superalloy[J].Scripta Materialia,2004,51(6):491-495.
- [22]梅声勇,郑磊,蒙肇斌,等.GH105合金铸锭元素偏析和均匀化工艺[J].北京科技大学学报,2009,31(6):714-718.MEI Sheng-yong,ZHENG Lei,MENG Zhao-bin,et al.Microsegregation and homogenization of GH105 superalloy ingots[J].Journal of University of Science and Technology Beijing,2009,31(6):714-718.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||