稀土对Fe基合金激光熔覆层组织性能的影响Effect of rare earth element on microstructure and properties of laser clad Fe-based alloy coatings
李养良,潘东,王洪涛,甘春飞,郭鑫,盛永奇,李文欣
摘要(Abstract):
采用CO2激光器在45钢基体表面熔覆稀土氧化物La2O3的Fe基涂层;借助于扫描电镜(SEM)、X射线衍射仪(XRD)、能谱仪(EDS)、显微硬度计、ML-100型磨粒磨损试验机对涂层组织结构、物相、组成成分、硬度及耐磨性能进行了分析。结果表明,添加稀土能够减少甚至消除Fe基合金涂层中存在的孔洞,细化晶粒,提高致密性;涂层的硬度和磨损形貌表明,添加稀土能够小幅度地提高涂层的硬度,但能够使涂层表面的硬度值比较均匀一致,从而引起磨损表面的相对光滑。Fe基合金涂层的磨损机理为轻微的磨粒磨损,45钢的磨损机理为磨粒磨损与粘着磨损。
关键词(KeyWords): 激光熔覆;稀土氧化物;铁基合金;显微硬度;耐磨性能
基金项目(Foundation): 江西省自然科学基金项目(2010GQC0117);; 国家自然科学基金项目(51001056);; 2010年九江学院大学生自主创新实验项目(10XSCXXSY53)
作者(Author): 李养良,潘东,王洪涛,甘春飞,郭鑫,盛永奇,李文欣
DOI: 10.13289/j.issn.1009-6264.2013.03.028
参考文献(References):
- [1]许萍,梅敦,张秀云.45钢激光熔覆的组织与性能[J].内蒙古工业大学学报,2001,20(4):295-299.XU Ping,MEI Dun,ZHANG Xiu-yun.Structure and properties of laser cladding on 45 steel[J].Journal of Inner Mongolia Polytechnic University,2001,20(4):295-299.
- [2]张永忠,金具涛,涂义,等.纯铜表面激光熔覆铜合金涂层的组织及耐磨性[J].金属热处理,2009,34(4):28-32.ZHANG Yong-zhong,JIN Ju-tao,TU Yi,et al.Microstructure and wear resistance of laser clad copper alloy coating on pure copper[J].Heat Treatmentof Metals,2009,34(4):28-32.
- [3]崔泽琴,王文先,曹国光,等.碳钢表面激光熔覆铁基B4C陶瓷涂层的组织与性能[J].材料热处理学报,2011,32(3):134-138.CUI Ze-qin,WANG Wen-xian,CAO Guo-guang,et al.Microstructure and properties of Fe-based alloy and B4 C ceramics compositecoating on lowcarbon steel by laser cladding[J].Transactions of Materials and Heat Treatment,2011,32(3):134-138.
- [4]张静,刘继常,张福全,等.球墨铸铁表面激光熔覆Fe-Cr-Si-B涂层[J].材料热处理学报,2010,31(5):133-137.ZHANG Jing,LIU Ji-chang,ZHANG Fu-quan,et al.Fe-Cr-Si-B coating by laser cladding on nodular cast iron[J].Transactions of Materials and HeatTreatment,2010,31(5):133-137.
- [5]沈龙光,张庆茂,宋杰.铁基合金激光熔覆层高温润滑磨损性能[J].强激光与粒子束,2009,21(11):1628-1632.SHEN Long-guang,ZHANG Qing-mao,SONG Jie.Wear behavior under high temperature and lubrication condition of Fe-based alloy coating formed bylaser cladding[J].High Power Laser and Particle Beams,2009,21(11):1628-1632.
- [6]程义远,王勇,赫庆坤,等.LaF3对激光原位合成TiC组织与性能影响[J].焊接学报,2010,31(10):85-88,92.CHENG Yi-yuan,WANG Yong,HE Qing-kun,et al.Influences of LaF3 on microstructure and performance of laser cladding layer in-situ fabricated[J].Transactions of the China Welding Institution,2010,31(10):85-88,92.
- [7]赵高敏,王昆林,李传刚.La2O3对激光熔覆Fe基合金熔覆层显微组织的影响[J].金属热处理,2004,29(4):9-13.ZHAO Gao-min,WANG Kun-lin,LI Chuan-gang.Effect of La2 O3 on microstructure of laser cladding ferrite-based alloy coating[J].Heat Treatment ofMetals,2004,29(4):9-13.
- [8]李养良,潘东,甘春飞,等.QT-500球墨铸铁表面激光熔覆镍基合金的组织与性能[J].金属热处理,2012,37(2):102-106.LI Yang-liang,PAN Dong,GAN Chun-fei,et al.Microstructure and properties of surface laser clad Ni-base alloy layer on QT-500 ductile cast iron[J].Heat Treatment of Metals,2012,37(2):102-106.
- [9]闫华.铜合金表面激光复合耐磨层及界面特性研究[D].武汉:华中科技大学,2010:34-40.
- [10]叶宏,薛志芬,范彦宏,等.激光熔覆NiCrSiB合金的组织与性能研究[J].激光杂志,2009,30(1):61-62.YE Hong,XUE Zhi-fen,FAN Yan-hong,et al.Structure and properties of NiCrSiB alloy laser cladding[J].Laser Journal,2009,30(1):61-62.
- [11]彭玉娟.稀土对激光熔覆镍基合金涂层的影响[D].阜新:辽宁工程技术大学,2005:39-45.
- [12]匡建新,汪新衡,刘安民.稀土对激光熔覆金属陶瓷复合层的影响[J].润滑与密封,2007,32(6):87-89,131.KUANG Jian-xin,WANG Xin-heng,LIU An-min,et al.Effects of CeO2 on Ni-based metal-ceramic compound coatings by laser cladding[J].Lubrication Engineering,2007,32(6):87-89,131.
- [13]王义厢,李宝增,宫耀华,等.45钢表面激光熔覆铁基合金涂层显微组织与性能[J].热加工工艺,2008,37(21):131-133.WANG Yi-xiang,LI Bao-zeng,GONG Yao-hua,et al.Microstructure and performance of iron-based alloy laser cladding on 45 steel surface[J].HotWorking Techonlogy,2008,37(21):131-133.
- [14]李安敏.稀土在激光熔覆TiCp/Ni基复合涂层中的作用[D].武汉:武汉科技大学,2005:24-29.
- [15]马兴伟,金洙吉,高玉周.稀土La2O3对激光熔覆铁铝基合金及TiC增强复合材料涂层组织及摩擦磨损性能的影响[J].中国激光,2010,31(1):271-276.MA Xing-wei,JIN Zhu-ji,GAO Yu-zhou.Effect of rare earth La2 O3 on microstructure and tribological property of laser cladding FeAl based alloys andTiC reinforced composites coatings[J].Chinese Journal of Laser,2010,31(1):271-276.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||