热作模具钢低温回火短程碳扩散行为Short range diffusion behaviors of carbon atoms of hot work die steel during low-temperature tempering
张进峰,吴晓春,闵娜,金明江
摘要(Abstract):
通过电阻法对淬火态SDCM1热作模具钢从室温~200℃回火过程进行动态表征,采用三维原子探针(3DAP)显微组织分析技术分析淬火态和回火态试样各元素原子的三维空间分布及在选区空间的浓度变化,结合淬火态试样在室温~200℃加热过程中硬度变化分析低温回火过程中碳原子扩散行为。结果表明:淬火态试样低温回火后碳元素在局部区域出现明显的偏聚,合金元素Mn、Mo、Cr等几乎分布均匀;室温至70℃回火时电阻随温度的升高而增加主要是声子散射电子引起的;70℃至125℃回火时电阻偏离原有线性上升趋势,增幅变缓,随后呈现下降趋势,为该温度区间碳原子短程扩散偏聚散射电子作用减弱所致;120℃附近出现与电阻峰特征吻合的硬度峰值,归因为碳原子向位错扩散偏聚钉扎位错。
关键词(KeyWords): 热作模具钢;碳扩散;硬度;电阻法;三维原子探针
基金项目(Foundation): 省部共建高品质特殊钢冶金与制备国家重点实验室自主课题(SKLASS2022-Z12);; 苏州市职业大学科研项目(KY20230422)
作者(Author): 张进峰,吴晓春,闵娜,金明江
DOI: 10.13289/j.issn.1009-6264.2025-0165
参考文献(References):
- [1] 毛宏,吴红庆,涂宇杰,等.热处理工艺对3种不同Cr系冷作模具钢热处理变形的影响[J].材料热处理学报,2024,45(8):154-163.MAO Hong,WU Hong-qing,TU Yu-jie,et al.Effect of heat treatment process on heat treatment deformation of three different Cr series cold working die steels[J].Transactions of Materials and Heat Treatment,2024,45(8):154-163.
- [2] 黄苏起,李玲,吴晓春.新型热作模具钢4Cr3Mn1Mo2V的抗铝熔损性能[J].材料热处理学报,2021,42(8):91-98.HUANG Su-qi,LI Ling,WU Xiao-chun.Erosion resistance of new hot working die steel 4Cr3Mn1Mo2V in molten aluminum[J].Transactions of Materials and Heat Treatment,2021,42(8):91-98.
- [3] 左鹏鹏,何雪松,吴晓春,等.三维原子探针表征淬回火Cr-Mo-V-Ni中合金钢的元素分布[J].材料导报,2017,31(22):85-89.ZUO Peng-peng,HE Xue-song,WU Xiao-chun,et al.Elements distributions in quenched and tempered Cr-Mo-V-Ni medium-alloy steel characterized by three dimension atom probe[J].Materials Review,2017,31(22):85-89.
- [4] Jin X,Zeng F,Sun R,et al.The influential factors of baking time in internal friction and bake-hardening properties on low carbon steel[J].Journal of Physics Conference Series,2021,1948(1):012208.
- [5] 张进峰.中低碳钢碳扩散行为的电阻和内耗方法研究[D].上海:上海大学,2021.ZHANG Jin-feng.Study on carbon diffusion behaviors of medium and low carbon steels by resistance and internal friction methods[D].Shanghai:Shanghai Unversity,2021.
- [6] Luo Z C,Huang M X.The role of interstitial carbon atoms on the strain-hardening rate of twinning-induced plasticity steels[J].Scripta Materialia,2020,178:264-268.
- [7] Wilde J,Cerezo A,Smith G D W.Three-dimensional atomic-scale mapping of a cottrell atmosphere around a dislocation in iron[J].Scripta Materialia,2000,43(1):39-48.
- [8] 谢尘,吴晓春,闵娜,等.3DAP研究高碳高合金钢深冷处理过程的C偏聚行为[J].金属学报,2015,51(3):325-332.XIE Chen,WU Xiao-chun,MIN Na,et al.Carbon segregation behavior of high-carbon high alloy steel during deep cryogenic treatment using 3DAP[J].Acta Metallurgica Sinica,2015,51(3):325-332.
- [9] Lu X W,Jin M J,Jin X J.Origin of low temperature shoulder internal friction peak of Snoek-K?ster peak[J].Solid State Communications,2014,195:31-34.
- [10] Sherman A M,Eldis G T,Cohen M.The aging and tempering of iron-nickel-carbon martensites[J].Metallurgical Transactions A,1983,14:995-1005.
- [11] Furst S J,Crews J H,Seelecke S.Stress,strain,and resistance behavior of two opposing shape memory alloyactuator wires for resistance based self-sensing applications[J].Journal of Intelligent Material Systems and Structures,2013,24(16):1951-1968.
- [12] 张进峰,吴晓春,闵娜.SDCM1新型热作模具钢回火过程中碳扩散行为的电阻表征[J].材料热处理学报,2021,42(5):88-95.ZHANG Jin-feng,WU Xiao-chun,MIN Na.Characterization of carbon diffusion behaviors of SDCM1 new hot working die steel during tempering by in-situ resistance method[J].Transactions of Materials and Heat Treatment,2021,42(5):88-95.
- [13] Vieira I,Klemm-Toole J,Buchner E,et al.A dilatometric study of tempering complemented by m?ssbauer spectroscopy and other characterization techniques[J].Scientific Reports,2017,7(1):1-14.
- [14] Speich G R.Tempering of low-carbon martensite[J].Transactions of AIME,1969,245(12) 2553-2564.
- [15] 葛庭燧,容保粹,王业宁.钢中碳氮的扩散、脱溶和沉淀[J].物理学报,1955,11(1):91-106.GE Ting-sui,RONG Bao-cui,WANG Ye-ning.Diffusion and precipitation of carbon and nitrogen from solid solution in iron and steel[J].Acta Physica Sinca,1955,11(1):91-106.
- [16] Campbell F C.Elements of Metallurgy and Engineering Alloys[M].Ohio:ASM International,2008:177-200.
- [17] Vieira I,Klemm-Toole J,Buchner E,et al.A dilatometric study of tempering complemented by m?ssbauer spectroscopy and other characterization techniques[J].Scientific Reports,2017,7(1):1-14.
- [18] Speich G R,Leslie W C.Tempering of steel[J].Metallurgical Transactions,1972,3(5):1043-1054.
- [19] Cohen M.Symposium on the tempering of steel[J].Metallurgical Transaction A,1983(14):991-993.
- [20] 张进峰,周正存.钢回火碳扩散行为的表征方法[J].科学技术与工程,2022,22(18):7735-7745.ZHANG Jin-feng,ZHOU Zheng-cun.Review of characterization methods of carbon atom occupation and diffusion behavior in steel[J].Science Technology and Engineering,2022,22(18):7735-7745.
- [21] Christian J.Thoery of Transformation in Metals and Alloys[M].Oxford:Pergamon Press,1997:433-489.
- [22] Harper S.Precipitation of carbon and nitrogen in cold-worked alpha-iron[J].Physical Review,1951,83(4):709-712.
- [23] Zhou Q C,Wu X C,et al.Effect of Si addition on kinetics of martensitic hot-work die steel during tempering[J].Metals and Materials Internationala,2011,17(4):547-552.
- [24] Gènin J M R.The clustering and coarsening of carbon multiplets during the aging of martensite from m?ssbauer spectroscopy:theprecipitation stage of epsilon carbide[J].Metallurgical Transactions A,1987,18:1371-1388.
- [25] Chen P C,Winchell P G.Martensite lattice changes during tempering[J].Metallurgical Transactions A,1980,11:1333-1339.
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