黄丽琴,刘光明,张民强,黄健航,汪元奎

• 1:南昌航空大学材料科学与工程学院
• 2:东方锅炉股份有限公司材料研究所

摘要(Abstract)：

将Super304H、HR3C钢试样置于700℃下不同SO_2浓度(0.5%,1.5%)模拟气氛中,间隔一定时间取出样品称重,获得腐蚀动力学曲线。采用XRD、SEM和EDS等测试技术对腐蚀产物成分、结构和形貌进行分析。结果表明:在高硫环境中HR3C钢比Super304H钢更耐蚀。Super304H钢的腐蚀产物主要由疏松的富铁氧化物,部分Cr、Ni的氧化物以及尖晶石类化合物和少量的硫化物组成;HR3C钢的腐蚀产物主要为Cr_2O_3和铁的氧化物以及少量硫化物。随着SO_2浓度升高,腐蚀层增厚,腐蚀产物中局部出现S富集,加速了合金腐蚀。

关键词(KeyWords)： 奥氏体钢;Super304H钢;HR3C钢;高温腐蚀

Abstract:

Keywords:

基金项目(Foundation): 国家自然科学基金(51161022);; 江西省教育厅科技计划项目(DB201301133,201301050)

作者(Author): 黄丽琴,刘光明,张民强,黄健航,汪元奎

DOI: 10.13289/j.issn.1009-6264.2017-0186

参考文献(References)：

• [1]张晓鲁.关于加快发展我国先进超超临界燃煤发电技术的战略思考[J].中国工程科学,2013(4):91-95.ZHANG Xiao-lu.Some consideration about future development strategy of advanced ultra supercritical coal-fired power generation technology[J].Chinese Engineering Science,2013(4):91-95.
• [2]贺永冰,王卫军,李长鸣,等.超临界直流锅炉水冷壁管高温硫腐蚀的成因及防治[J].电力建设,2010,31(10):61-66.HE Yong-bing,WANG Wei-jun,LI Chang-ming,et al.Causes and prevention of high temperatures sulfur corrosion of water wan tubes of supercritical concurrent boiler[J].Electric Power Construction,2010,31(10):61-66.
• [3]徐炯,周一工.700℃高效超超临界技术的发展[J].中外能源,2012,6(4):13-17.XU Jiong,ZHOU Yi-gong.The development of 700℃USC technology[J].Sino-global Energy,2012,6(4):13-17.
• [4]林富生,王治政,王宝忠,等.中国电站用耐热钢及合金的研制、应用与发展[J].动力工程学报,2010,30(4):235-244.LIN Fu-sheng,WANG Zhi-zheng,WANG Bao-zhong,et al.Research,Appllication and development of domestic heat-resistant steels and alloys for power plants[J].Journal of Chinese Society of Power Engineering,2010,30(4):235-244.
• [5]成丁南,张知翔,边宝,等.5种电站锅炉过热器用材料高温腐蚀试验研究[J].动力工程学报,2012,32(11):891-897.CHENG Ding-nan,ZHANG Zhi-xiang,BIAN Bao,et al.Five kinds of power station boiler superheated high tempreature corrosion test for material research[J].Journal of power engineering,2012,32(11):891-897.
• [6]潘家栋,王家庆,陈国宏,等.Super304H耐热钢的热稳定性[J].中国科技论文,2012,7(2):95-100.PAN Jia-dong,WANG Jia-qing,CHEN Guo-hong,et al.Thermal stability of super304H heat resistant steel[J].China Science Paper,2012,7(2):95-100.
• [7]贾成洁.Super304H奥氏体不锈钢高温时效后组织结构的变化[D].大连理工大学,2010.JIA Cheng-jie.Changes of microstructure of super304H austenitic stainless steel after high temperature aging[D];Dalian University of Technology,2010.
• [8]Aung N N,Liu X B.Effect of temperature on coal ash hot corrosion resistance of Inconel 740 superalloy[J].Corrosion Science,2014,82:227-238.
• [9]李江,周荣灿,唐丽英,等.HR3C钢在模拟燃用高硫煤锅炉环境中的高温烟气腐蚀行为[J].热力发电,2016,45(1):70-75.LI Jiang,ZHOU Rongcan,TANG Liying,et al.Fireside corrosion behavior of HR3C steel in simulated coal-fired boiler atmospheres with high sulfur concentration[J].Thermal Power Genertion,2016,45(1):70-75.
• [10]庞胜娇.三种合金耐硫酸盐/氯盐腐蚀行为研究[D].大连:大连理工大学,2014:29.PANG Sheng-jiao.Study on corrosion behavior resistancet os ulfates/Chloride salts of three kinds of alloy[D].Dalian:Dalian University of Technology,2014:29.
• [11]李铁藩.金属高温氧化和热腐蚀[M].化学工业出版社,2003.LI Tie-fan.High Temperature Corrosion and Hot Chemistry of Metals[M].Beijing:Chemical Industry Press,2003.
• [12]左禹.钢铁材料的高温硫化腐蚀[J].石油化工腐蚀与防护,1988,3(3):21-31.ZOU Yu.High temperature vulcanization corrosion of steel materials[J].Corrosion&Protection in Petrochemical In dustry,1988,3():21-31.
• [13]张扬伟.310不锈钢高温气体腐蚀行为及其防护涂层研究[D].大连:大连理工大学,2001.ZHANG Yang-wei.High-temperature corrosion behavior of 310SS and it’s protection[D].Dalian:Dalian University of Technology,2001.
• [14]李萍,秦鹏,庞胜娇,等.Super304H在模拟烟气环境下的腐蚀行为[J].材料热处理学报,2015,36(10):210-217.LI Ping,QIN Peng,PANG Sheng-jiao,et al.Study on corrosion behavior of super304H steel in simulated furnace atmosphere[J].Transactions of Materials and Heat Treatment,2015,36(10):210-217.
• [15]Gillot B,Radid M.Corrosion in SO2of chromium and manganese at high temperature[J].Oxidation of metals,1990,33(3/4):279-299.
• [16]Stein-Brzozowska G,Norling R,Viklund P,et al.Fireside corrosion during oxyfuel combustion considering various SO2Contents[J].Energy Procedia,2014,51:135-147.
• [17]Jha B B,Mishra B K,Ojha S N.Acoustic emission during isothermal oxidation of 2.25Cr-1Mo steel[C].Proceedings of the Defect and Diffusion Forum,2009:93-104.
• [18]徐海卫,周旬,魏连启,等.混合气氛下SO2对低碳钢高温氧化行为的影响[J].材料热处理学报,2012,33(11):98-104.XU Hai-wei,ZHOU Xun,WEI Lian-qi,et al.Effect of SO2content on high temperature oxidation behavior of a low carbon steel in mixed gas environments[J].Transactions of Materials and Heat Treatment,2012,33(11):98-104.

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