固溶处理对Mg-1Zn-0.3Zr-2Gd-0.3Sr合金组织和腐蚀性能的影响Effect of solid solution treatment on microstructure and corrosion properties of Mg-1Zn-0.3Zr-2Gd-0.3Sr alloy
郑丽鸽,贺俊光,文九巴,徐大召
摘要(Abstract):
采用扫描电镜(SEM)以及光学显微镜(OM)观察了Mg-1Zn-0.3Zr-2Gd-0.3Sr合金的微观组织。用X射线衍射仪(XRD)分析了合金的偏析相,并用浸泡测试和电化学试验研究了合金的腐蚀性能。结果表明:铸态合金的偏析相最多,平均腐蚀速率为1.102 mm/a;随着固溶温度的升高,合金的偏析相逐渐减少,组织逐渐变得较为均匀,平均腐蚀速率基本逐渐降低;经510℃固溶处理的合金的平均腐蚀速率最小为0.63 mm/a,比铸态合金的平均腐蚀速率降低了42.8%。
关键词(KeyWords): 固溶温度;微观组织;腐蚀性能;平均腐蚀速率
基金项目(Foundation): 河南省自然科学基金项目(162300410213);; 河南省教育厅科技攻关项目(14A430001)
作者(Author): 郑丽鸽,贺俊光,文九巴,徐大召
DOI: 10.13289/j.issn.1009-6264.2018-0410
参考文献(References):
- [1] 张帆,毕广利,李元东,等.固溶处理对Mg-Dy-Zn 合金显微组织和腐蚀性能的影响[J].材料热处理学报,2015,36(4):85-92.ZHANG Fan,BI Guang-li,LI Yuan-dong,et al.Effect of solution treatment on microstructure and corrosion properties of Mg-Dy-Zn alloy[J].Transactions of Materials and Heat Treatment,2015,36(4):85-92.
- [2] Virtanen S.Biodegradable Mg and Mg alloys:Corrosion and biocompatibility[J].Materials Science and Engineering B,2011,176(20):1600-1608.
- [3] Liu M,Song G L.Impurity control and corrosion resistance of magnesium-aluminum alloy[J].Corrosion Science,2013,77(1):143-150.
- [4] 马晓刚,刘德宝,刘林波,等.生物可降解Mg-3Zn-0.8Zr-xMn合金的组织与性能[J].材料热处理学报,2015,36(2):27-31.MA Xiao-gang,LIU De-bao,LIU Lin-bo,et al.Microstructure and properties of Mg-3Zn-0.8Zr-xMn alloy[J].Transactions of Materials and Heat Treatment,2015,36(2):27-31.
- [5] Wang H,Estrin Y,Zúberová Z.Bio-corrosion of a magnesium alloy with different processing histories[J].Materials Letters,2008,62(16):2476-2479.
- [6] Cheng D D,Wen J B,He J G,et al.Effects of solution treatment on biocorrosion properties of Mg-Nd-Zn-Zr magnesium alloy[J].Transactions of Materials and Heat Treatment,2015,36(1):36-41.
- [7] Seyedraoufi Z S,Mirdamadi S.Effects of pulse electrodeposition parameters and alkali treatment on the properties of nano hydroxyapatite coating on porous Mg-Zn scaffold for bone tissue engineering application[J].Materials Chemistry and Physics,2014,148(3):519-527.
- [8] Gao Y L,Ma G C,Zhang H B,et al.Corrosion resistance and biocompatibility of AZ91HP alloy melted layer treated by laser[J].Transactions of Materials and Heat Treatment,2015,36(1):147-152.
- [9] Liu X B,Shan D Y,Song Y W,et al.Effects of heat treatment on corrosion behaviors of Mg-3Zn magnesium alloy[J].Transactions of Nonferrous Metals Society of China,2010,20(7):1345-1350.
- [10] 刘亚,文九巴,单玉郎,等.Mg-0.5Zn-0.4Zr-5Gd生物镁合金组织及耐蚀性[J].材料热处理学报,2017,38(2):38-42.LIU Ya,WEN Jiu-ba,SHAN Yu-lang,et al.Microstructure and corrosion resistance of Mg-0.5Zn-0.4Zr-5Gd biomedical magnesium alloy[J].Transactions of Materials and Heat Treatment,2017,38(2):38-42.
- [11] 孙毅,张文鑫,许春香,等.固溶处理对Mg-Zn-Y-Zr-Ca生物镁合金组织及腐蚀性能的影响[J].材料热处理学报,2017,38(9):24-29.SUN Yi,ZHANG Wen-xin,XU Chun-xiang,et al.Effects of solution treatment on microstructure and corrosion properties of Mg-3.0Zn-0.6Y-0.5Zr-0.3Ca biological magnesium alloy[J].Transactions of Materials and Heat Treatment,2017,38(9):24-29.
- [12] 殷俏,章晓波,王章忠,等.固溶温度对Mg-2Nd-2Gd-0.3Sr-0.2Zn-0.4Zr镁合金腐蚀性能的影响[J].材料热处理学报,2016,37(1):133-137.YIN Qiao,ZHANG Xiao-bo,WANG Zhang-zhong,et al.Effects of solution temperature on corrosion properties of Mg-2Nd-2Gd-0.3Sr-0.2Zn-0.4Zr magnesium alloy[J].Transactions of Materials and Heat Treatment,2016,37(1):133-137.
- [13] 贺俊光,郑丽鸽,文九巴,等.Sr含量对Mg-1Zn-0.3Zr-2Gd-xSr生物镁合金组织和性能的影响[J].材料热处理学报,2018,39(6):35-41.HE Jun-guang,ZHENG Li-Ge,WEN Jiu-ba,et al.Effects of Sr on microstructure and properties of as-cast Mg-1Zn-0.3Zr-2Gd-xSr magnesium alloy[J].Transactions of Materials and Heat Treatment,2018,39(6):35-41.
- [14] Zeng R C,Sun L,Zheng Y F,et al.Corrosion and characterisation of dual phase Mg-Li-Ca alloy in Hank’s solution:The influence of microstructural features[J].Corrosion Science,2014,79(79):69-82.
- [15] 纪晓昀,韩振华,郭皓,等.晶粒度对Mg-5Ca-2.5Nd合金力学及腐蚀性能的影响[J].热加工工艺,2017(6):104-106.JI Xiao-yun,HAN Zhen-hua,GUO Hao,et al.Influence of grain size on mechanical and corrosion properties of Mg-5Ca-2.5Nd alloy[J].Hot Working Technology,2017(6):104-106.
- [16] 王自启.热处理对AZ31镁合金轧制板材组织和性能的影响[D].太原:太原理工大学,2011.WANG Zi-qi.Effects of heat treatment of the microstructure and properties of rolled AZ31 magnesium alloy sheets[D].Taiyuan:Taiyuan University of Technology,2011.
- [17] Zhang X,Yuan G,Mao L,et al.Effects of extrusion and heat treatment on the mechanical properties and biocorrosion behaviors of a Mg-Nd-Zn-Zr alloy[J].Journal of the Mechanical Behavior of Biomedical Materials,2012,7(1):77-86.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||