热处理工艺对S53高强度不锈钢组织与性能的影响Effect of heat treatment process on microstructure and properties of S53 high strength stainless steel
徐明阳,陆金玉,王威,田家龙
摘要(Abstract):
采用光学显微镜(OM)、场发射扫描电镜(FESEM)、X-射线衍射仪(XRD)、洛氏硬度仪、拉伸试验机和冲击试验机等研究了热处理工艺对S53高强度不锈钢组织和力学性能的影响,并采用Thermo-Calc和FactSage等计算软件对实验钢进行了热、动力学计算。结果表明:随固溶温度的升高,实验钢晶粒长大的同时伴随着析出相的回溶,奥氏体相稳定性提升,残留奥氏体含量增加。在1080~1100℃固溶时析出相基本完全回溶,此时组织均匀性较好,实验钢达到了强韧性的良好匹配。实验钢经1100℃固溶处理1 h及双时效处理后的力学性能最佳,其抗拉强度达到2 GPa以上,伸长率接近11%,冲击吸收能量达到20 J以上,同时洛氏硬度达到了56 HRC。在固溶处理的温度范围内,随固溶温度的升高,各元素的扩散系数显著提高,析出相加速回溶;在时效处理的温度范围内,碳的扩散系数显著高于其余合金元素,相较于奥氏体相(FCC),各合金元素在铁素体相(BCC)中的扩散速度较高。
关键词(KeyWords): 超高强度不锈钢;热处理工艺;力学性能;显微组织
基金项目(Foundation): 国家自然科学基金面上项目(52271122);; 慈溪市共性技术攻关项目(2019gy02);; 中央高校基本科研业务专项资金(N2225009)
作者(Author): 徐明阳,陆金玉,王威,田家龙
DOI: 10.13289/j.issn.1009-6264.2022-0545
参考文献(References):
- [1] 杨柯,牛梦超,田家龙,等.新一代飞机起落架用马氏体时效不锈钢的研究[J].金属学报,2018,54(11):1567-1585.YANG Ke,NIU Meng-chao,TIAN Jia-long,et al.Research and development of maraging stainless steel used for new generation landing gear[J].Acta Metallurgica Sinica,2018,54(11):1567-1585.
- [2] 万如.新型高合金二次硬化超高强度钢的发展[J].材料工程,1994(11):1-5.WAN Ru.Development of advanced highly alloy of secondary hardening ultrahigh-strength steels[J].Journal of Materials Engineering,1994(11):1-5.
- [3] 赵博,许广兴,贺飞,等.飞机起落架用超高强度钢应用现状及展望[J].航空材料学报,2017,37(6):1-6.ZHAO Bo,XU Guang-xing,HE Fei,et al.Present status and prospect of ultra high strength steel applied to aircraft landing gear[J].Journal of Aeronautical Materials,2017,37(6):1-6.
- [4] 王晓辉,罗海文.飞机起落架用超高强度不锈钢的研究及应用进展[J].材料工程,2019,47(9):1-12.WANG Xiao-hui,LUO Hai-wen.Research and application progress in ultrahigh strength stainless steel for aircraft landing gear[J].Journal of Materials Engineering,2019,47(9):1-12.
- [5] Jing G Y,Huang W P,Yang H H,et al.Microstructural evolution and mechanical properties of 300M steel produced by low and high power selective laser melting[J].Journal of Materials Science & Technology,2020,48:44-56.
- [6] Liu J,Li J,Cheng X,et al.Microstructures and tensile properties of laser cladded AerMet100 steel coating on 300M steel[J].Journal of Materials Science & Technology,2018,34(4):643-652.
- [7] Zhao M J,Huang L,Li C M,et al.Evaluation of the deformation behaviors and hot workability of a high-strength low-alloy steel[J].Materials Science and Engineering A,2021,810:141031.
- [8] 冉先喆,程昊,王华明,等.激光熔化沉积AerMet100耐蚀超高强度钢的耐蚀性[J].材料热处理学报,2012,33(12):126-131.RAN Xian-zhe,CHENG Hao,WANG Hua-ming,et al.Corrosion properties of laser melting-deposited corrosion-resistant ultrahigh strength steel AerMet100[J].Transactions of Materials and Heat Treatment,2012,33(12):126-131.
- [9] 彭雯雯,曾卫东,闫文巧,等.回火工艺对Aermet100超高强度钢组织与韧性的影响[J].材料热处理学报,2013,34(6):58-61.PENG Wen-wen,ZENG Wei-dong,YAN Wen-qiao,et al.Effect of tempering process on microstructure and toughness of Aermet100 ultrahigh strength steel[J].Transactions of Materials and Heat Treatment,2013,34(6):58-61.
- [10] 彭雯雯,曾卫东,康超,等.热处理工艺对300M超高强度钢组织和性能的影响[J].材料热处理学报,2012,33(3):94-98.PENG Wen-wen,ZENG Wei-dong,KANG Chao,et al.Effect of heat treatment on microstructure and properties of 300M ultrahigh strength steel[J].Transactions of Materials and Heat Treatment,2012,33(3):94-98.
- [11] 胡春东,孟利,董瀚.超高强度钢的研究进展[J].材料热处理学报,2016,37(11):178-183.HU Chun-dong,MENG Li,DONG Han.Research and development of ultra-high strength steels[J].Transactions of Materials and Heat Treatment,2016,37(11):178-183.
- [12] 王彬文,陈先民,苏运来,等.中国航空工业疲劳与结构完整性研究进展与展望[J].航空学报,2021,42(5):6-44.WANG Bin-wen,CHEN Xian-min,SU Yun-lai,et al.Research progress and prospect of fatigue and structural integrity for aeronautical industry in China[J].Acta Aeronautica et Astronautica Sinica,2021,42(5):6-44.
- [13] 杨志勇,刘振宝,梁剑雄,等.马氏体时效不锈钢的发展[J].材料热处理学报,2008,29(4):1-7.YANG Zhi-yong,LIU Zhen-bao,LIANG Jian-xiong,et al.Development of maraging stainless steel[J].Transactions of Materials and Heat Treatment,2008,29(4):1-7.
- [14] 赵振业,李志,刘天琦,等.探索新强韧化机制、开拓超高强度钢新领域[J].中国工程科学,2003(9):39-42.ZHAO Zhen-ye,LI Zhi,LIU Tian-qi,et al.Studying the new strength-toughen mechanisms,developing a new field of ultra-high Steel[J].Engineering Science,2003(9):39-42.
- [15] Du X H,Li W P,Chang H T,et al.Dual heterogeneous structures lead to ultrahigh strength and uniform ductility in a Co-Cr-Ni medium-entropy alloy[J].Nature Communications,2020,11:2390.
- [16] Liu S L,Hu B,Li W,et al.Refined heterogeneous phase unit enhances ductility in quenched ultra-high strength steels[J].Scripta Materialia,2021,194:113636.
- [17] Seede R,Shoukr D,Zhang B,et al.An ultra-high strength martensitic steel fabricated using selective laser melting additive manufacturing:Densification,microstructure,and mechanical properties[J].Acta Materialia,2020,186:199-214.
- [18] Du Y B,Hu X F,Zhang S Q,et al.Precipitation behavior of Cu-NiAl nanoscale particles and their effect on mechanical properties in a high strength low alloy steel[J].Materials Characterization,2022,190:112014.
- [19] Zhang Y P,Zhan D P,Qi X W,et al.Effect of solid-solution temperature on the microstructure and properties of ultra-high-strength FerriumS53 Steel[J].Materials Science and Engineering A,2018,730:41-49.
- [20] 董纪,杨晓斌,刘晨曦,等.超高强度钢热处理组织中碳化物演化行为研究进展[J].钢铁研究学报,2021,33(10):1052-1063.DONG Ji,YANG Xiao-bin,LIU Chen-xi,et al,Research progress of carbide evolution behavior in heat treated structure of ultra-high strength steel[J].Journal of Iron and Steel Research,2021,33(10):1052-1063.
- [21] 郑宝星,邓小虎,董纪.显微组织对25CrMo48V超高强度钢在NaCl溶液中腐蚀行为的影响[J].材料热处理学报,2020,41(4):107-115.ZHENG Bao-xing,DENG Xiao-hu,DONG Ji.Effect of microstructure on corrosion behavior of 25CrMo48V ultra-high strength steel in NaCl solution[J].Transactions of Materials and Heat Treatment,2020,41(4):107-115.
- [22] Zhang X,Miyamoto G,Toji Y.Role of cementite and retained austenite on austenite reversion from martensite and bainite in Fe-2Mn-1.5Si-0.3C alloy[J].Acta Materialia,2021,209(6):116772.
- [23] Zhang Y P,Zhan D P,Qi X W,et al.Effect of tempering temperature on the microstructure and properties of ultrahigh-strength stainless steel[J].Journal of Materials Science & Technology,2019,35(7):1240-1249.
- [24] Misra R,Balasubramanian T V,Rao P R.AES analysis of fracture toughness variation with heat treatment in an 18Ni (250 grade) maraging steel[J].Journal of Materials Science Letters,1987,6(2):125-130.
- [25] 赵振业.超高强度钢中二次硬化现象研究[J].航空材料学报,2002(4):46-55.ZHAO Zhen-ye.Studing status on the secondary hardening phenomenon in ultra-high strength steels[J].Journal of Aeronautical Materials,2002(4):46-55.
- [26] Tahiro H.Challenge for maximum tensile strength steel cord[J].Nippon Steel Technical Report,1999,41(80):6-8.
- [27] Tian J L,Chen K,Li H B,et al.Suppressing grain boundary embrittlement via Mo-driven interphase precipitation mechanism in martensitic stainless steel[J].Materials Science and Engineering A,2022,833:142529.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||