粉末冶金Al3(Zr,Ti)/Al复合材料的组织与性能Microstructure and properties of powder metallurgy Al3(Zr,Ti)/Al composites
徐道兵,龙威,周小平
摘要(Abstract):
为了研究Zr含量变化对Al-Ti-Zr铝基复合材料组织与力学性能的影响,以纯Al粉末作为基体材料,纯Ti粉和纯Zr粉作为增强体材料,采用粉末冶金原位合成法在750℃烧结制备了Al-Ti-Zr复合材料。随后将烧结制备的复合材料加热到400℃进行热压变形处理,测试其组织和性能的变化。结果表明:在Al-Ti-Zr三元体系中,复合材料内部通过置换反应生成Al_3(Zr,Ti)化合物;随着Zr含量的增加,复合材料的组织更加均匀、致密化,其抗拉强度、硬度逐渐增加,抗拉强度最大值为227.66 MPa,硬度最大值为132.83 HV0.025;复合材料的耐腐蚀性能随着Zr含量的增加呈现下降趋势,在Zr含量为5%时,复合材料的耐腐蚀性能最佳,其腐蚀电位为-0.67661 V,腐蚀电流密度为1.0214×10~(-6) A/cm~2。
关键词(KeyWords): 粉末冶金;复合材料;组织性能;耐腐蚀性
基金项目(Foundation):
作者(Author): 徐道兵,龙威,周小平
DOI: 10.13289/j.issn.1009-6264.2019-0481
参考文献(References):
- [1] Li S S,Su Y S,Zhang D,et al.In-situ carbon nanotube-covered silicon carbide particle reinforced aluminum matrix composites fabricated by powder metallurgy[J].Materials Letters,2016,167:118-121.
- [2] Luan B F,Qiu R S,Li C H,et al.Hot deformation and processing maps of Al2O3/Al composites fabricated by flake powder metallurgy[J].Transactions of Nonferrous Metals Society of China,2015,25(4):1056-1063.
- [3] Qin Q D,Huang B W,Li W,et al.Preparation and wear resistance of aluminum composites reinforced with in situ formed TiO/Al2O3[J].Journal of Materials Engineering and Performance,2016,25(5):2029-2036.
- [4] Li S F,Kondoh K,Chen B,et al.Strengthening behavior of in situ-synthesized (TiC-TiB)/Ti composites by powder metallurgy and hot extrusion[J].Materials and Design,2016,95(5):127-132.
- [5] Yang X D,Zou T C,Shi C S,et al.Effect of carbon nanotube (CNT) content on the properties of in-situ synthesis CNT reinforced Al composites[J].Materials Science and Engineering A,2016,660:11-18.
- [6] Li X,Zhang Y X,Shi C S,et al.In-situ synthesis of MgAl2O4 nanowhiskers reinforced 6061 aluminum alloy composites by reaction hot pressing[J].Materials Science and Engineering A,2014,617:235-242.
- [7] Lu Z G,Wu J,Xu L,et al.Preparation and properties of Ti-47Al-2Cr-2Nb-0.15B alloy by powder metallurgy route[J].Materials Science Forum,2015,817:615-620.
- [8] Tao R,Zhao Y T,Kai X Z,et al.Effects of hot rolling deformation on the microstructure and tensile properties of an in situ-generated ZrB2 nanoparticle-reinforced AA6111 composite[J].Materials Science and Engineering A,2018,732:138-147.
- [9] Wang Z G,Li C P,Wang H Y,et al.Aging behavior of nano-SiC/2014Al composite fabricated by powder metallurgy and hot extrusion techniques[J].Journal of Materials Science and Technology,2016,32:1008-1012.
- [10] Wang Z G,Li C P,Wang H Y,et al.Effect of nano-SiC content on mechanical properties of SiC/2014Al composites fabricated by powder metallurgy combined with hot extrusion[J].Powder Metallurgy,2016,59(4):236-241.
- [11] Rezaei A,Reza H,Hosseini M.Evolution of microstructure and mechanical properties of Al-5 wt%Ti composite fabricated by P/M and hot extrusion:Effect of heat treatment[J].Materials Science and Engineering A,2017,689:166-175.
- [12] Li Q,Qiu F,Gao Y Y,et al.Microstructure refinement and strengthening mechanisms of bimodal-sized and dual-phased (TiCn-Al3Tim)/Al hybrid composites assisted ultrasonic vibration[J].Journal of Alloys and Compounds,2019,788:1309-1327.
- [13] Zhang Q,Xiao B L,Wang D,et al.Formation mechanism of in situ Al3Ti in Al matrix during hot pressing and subsequent friction stir processing[J].Materials Chemistry and Physics,2011,130:1109-1117.
- [14] Arakawa Y,Kobashi M,Kanetake N.Foaming behavior of long-scale Al-Ti intermetallic foam by SHS mode combustion reaction[J].Intermetallics,2013,41:22-27.
- [15] Zhang L,Wu B L,Liu Y L,et al.Microstructure and mechanical properties of a hot-extruded Al-based composite reinforced with core-shell-structured Ti/Al3Ti[J].International Journal of Minerals,Metallurgy and Materials,2017,24(12):1431-1437.
- [16] Wang L N,Hou S J,Liang D W.First-principles investigations on the phase stability elastic and thermodynamic properties of Zr-Al alloys[J].International Journal of Modern Physics C,2015,26(12):1-12.
- [17] Saha S,Todorova T Z,Zwanziger J W.Temperature dependent lattice misfit and coherency of Al3X (X=Sc,Zr,Ti and Nb) particles in an Al matrix[J].Acta Materialia,2015,89:109-115.
- [18] Kaveendran B,Wang G S,Huang L J,et al.In situ (Al3Zr+Al2O3np)/2024Al metal matrix composite with novel reinforcement distributions fabricated by reaction hot pressing[J].Journal of Alloys and Compounds,2013,58:16-22.
- [19] Guo Y,Zhang Y Q,Li Z Y,et al.Microstructure and properties of in-situ synthesized ZrC-Al3Zr reinforced composite coating on AZ91D magnesium alloy by laser cladding[J].Surface and Coatings Technology,2018,334:471-478.
- [20] Kotiyani M Z M,Ranjbar K,Dehmolaei R.In-situ fabrication of Al3Zr aluminide reinforced AA3003 alloy composite by friction stir processing[J].Materials Characterization,2017,131:78-90.
- [21] Yang Y G,Zhao Y T,Kai X Z,et al.Superplasticity behavior and deformation mechanism of the in-situ Al3Zr/6063Al composites processed by friction stir processing[J].Journal of Alloys and Compounds,2017,17:225-233.
- [22] Lu K L,Yang F,Xie Z Y,et al.Isothermal section of Al-Ti-Zr ternary system at 1073 K[J].Transactions of Nonferrous Metals Society of China,2016,26:3052-3058.
- [23] Popova E A,Shubin A B,Kotenkov P V,et al.Al-Ti-Zr master alloys:Structure formation[J].Russian Metallurgy (Metally),2012,2012(5):357-361.
- [24] Tang L T,Zhu D G,Sun Z,et al.Microstructure and mechanical properties of Al-Ti-Zr intermetallic compounds prepared by vacuum hot pressing[J].Vacuum,2018,150:166-172.
- [25] Zhang L,Eskin D G,Miroux A G,et al.On the mechanism of the formation of primary intermetallics under ultrasonic melt treatment in an Al-Zr-Ti alloy[J].IOP Conference Series:Materials Science and Engineering,2011,27:1-6.
- [26] 阮建明,黄培云.粉末冶金原理[M].北京:机械工业出版社,2012:326-332.
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