原位合成CNTs强化铜基复合材料的组织与性能Microstructure and properties of in-situ synthesis CNTs reinforced Cu-matrix composites
周洪雷,刘平,陈小红,李伟,毕莉明,刘新宽
摘要(Abstract):
选用雾化制粉制备的CuCr复合粉末为原料,利用固溶时效时在CuCr颗粒表面析出的纳米Cr粒子作为催化剂,采用水辅助化学气相沉淀法和放电等离子烧结原位合成CNTs/CuCr复合材料。用扫描电镜、透射电镜、中温退火等测试手段对其抗拉强度、摩擦磨损性能、耐蚀性、显微硬度和抗软化温度进行表征。结果表明:CNTs/CuCr复合材料的抗拉强度较纯铜提高了16%,达到320 MPa;CNTs/CuCr复合材料具有良好的耐腐蚀性能和热稳定性,抗软化温度达到660℃;与钢球的摩擦系数较纯铜降低了49%,仅为0.294,磨损量较纯铜降低了55.3%。
关键词(KeyWords): CuCr合金粉末;固溶时效;摩擦系数;原位合成
基金项目(Foundation): 国家重点研究开发项目(2017YFB0306405)
作者(Author): 周洪雷,刘平,陈小红,李伟,毕莉明,刘新宽
DOI: 10.13289/j.issn.1009-6264.2018-0133
参考文献(References):
- [1]Firkowska I,Boden A,Vogt A M,et al.Effect of carbon nanotube surface modification on thermal properties of copper-CNT composite[J].J Mater Chem,2011,21(43):17541-17546.
- [2]Sheikh M U,Tanvir M,Christoph W,et al.Effect of size and shape of metal particles to improve hardness and electrical properties of carbon nanotube reinforced copper and copper alloy composite[J].Compos Sci Technol,2010,70(16):2253-2257.
- [3]Xu W,Hu R,Li J,et al.Effect of electrical current on tribological property of Cu matrix composite reinforced by carbon nanotubes[J].Trans Nonferrous Metals Soc China,2011,21(10):2237-2241.
- [4]Guiderdoni C,Pavlenko E,Turq V,et al.The preparation of carbon nanotube(CNT)/copper composite and the effect of the number of CNT walls on their hardness,friction and wear properties[J].Carbon,2009,58:185-197.
- [5]Yu M F,Files B S,Arepalli S,et al.Tensile loading of ropes of single wall carbon nanotubes and their mechanical properties[J].Physical Review Letters,2000,84(24):5552-5555.
- [6]Wong E W,Sheehan P E.Nanobeam mechanics:Elasticity,strength,and toughness of nanorods and nanotubes[J].Science,1997,277(5334):1971-1975.
- [7]Treacy M M J,Ebbesen T W.Exceptionally high Young’s modulus observed for individual carbon nanotubes[J].Nature,1996,381(6584):678-680.
- [8]Yang D J,Zhang Q,Chen G,et al.Thermal conductivity of multiwalled carbon nanotubes[J].Physical Review B,2002,66:165440-165445.
- [9]Gong S,Zhu Z H.On the mechanism of piezoresistivity of carbon nanotube polymer composite[J].Polymer,2014,55(16):4136-4149.
- [10]Gonga F,Buib K,Papavassiliouc D V,et al.Thermal transport phenomena and limitations in heterogeneous polymer composite containing carbon nanotubes and inorganic nanoparticles[J].Carbon,2014,78:305-316.
- [11]Daoush W M,Lim B K,Mo C B,et al.Electrical and mechanical properties of carbon nanotube reinforced copper nanocomposite fabricated by electroless deposition process[J].Materials Science and Engineering A,2009,513-514:247-253.
- [12]Dong S R,Tu J P,Zhang X B.An investigation of the sliding wears behavior of Cu-matrix composite reinforced by carbon nanotubes[J].Materials Science and Engineering A,2001,313(1/2):83-87.
- [13]Zhan G D,Kuntz J D,Wan J,et al.Single-wall carbon nanotubes as attractive toughening agents in alumina-based nanocomposite[J].Nature Materials,2003,2(1):38-42.
- [14]Zhou H,Liu P,Chen X,et al.Using precipitated Cr on the surface of Cu-Cr alloy powders as catalyst synthesizing CNTs/Cu composite powders by water-assisted CVD[J].Materials Research Express,2018,5(2):025603-025609.
- [15]He B C,Zhao N Q,Shi C S,et al.An approach to obtaining homogeneously dispersed carbon nanotubes in Al powders for preparing reinforced Al-matrix composite[J].Advanced Materials,2007,19:1128-1132.
- [16]Ghorbani A,Sheibani S,Ataie A.Microstructure and mechanical properties of consolidated Cu-Cr-CNT nanocomposite prepared via powder metallurgy[J].Journal of Alloys and Compounds,2018,732:818-827.
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