5 mass%TiB2/Al-4.5Cu-xSc-yZr复合材料的微观组织和力学性能Microstructure and mechanical properties of 5 mass%TiB2/Al-4.5Cu-xSc-yZr composites
祝捷,王培卿,薛彦庆,陈易山,张晗,郝启堂,李新雷
摘要(Abstract):
颗粒增强铝基复合材料的室温韧性和高温强度是制约其应用的主要瓶颈,寻求时效析出相的高温稳定和促进增强颗粒的均匀分布是同步解决该问题的潜在途径之一。采用对掺熔盐反应法原位制备了5 mass%TiB_2/Al-4.5Cu-xSc-yZr复合材料,研究了微量添加Sc、Zr元素对TiB_2/Al-4.5Cu复合材料微观组织和力学性能的影响。结果表明:Sc和Zr元素的联合添加既能促进TiB_2的均匀分布又能明显抑制铸造缺陷,多级热处理工艺进一步促进了θ′-Al_2Cu和Al_3(Sc, Zr)相的稳定析出,所制备的5 mass%TiB_2/Al-4.5Cu-0.2Sc-0.2Zr复合材料的室温抗拉强度达到了385.1 MPa,断裂伸长率为8.6%,300℃下,抗拉强度达到了167.6 MPa,断裂伸长率为9.3%。
关键词(KeyWords): TiB_2/Al-Cu复合材料;对掺熔盐反应法;微观组织;力学性能
基金项目(Foundation): 陕西省重点研发计划(2021ZDLGY14-07);; 咸阳市秦创原科技创新专项(L2022-QCYZX-GY-017)
作者(Author): 祝捷,王培卿,薛彦庆,陈易山,张晗,郝启堂,李新雷
DOI: 10.13289/j.issn.1009-6264.2022-0398
参考文献(References):
- [1] Mair P,Kaserer L,Braun J,et al.Microstructure and mechanical properties of a TiB2-modified Al-Cu alloy processed by laser powder-bed fusion[J].Materials Science and Engineering A,2021,799:140209.
- [2] 郝世明,毛建伟,谢敬佩.原位内生颗粒增强TiB2/7055铝基复合材料的组织[J].材料热处理学报,2015,36(5):29-34.HAO Shi-ming,MAO Jian-wei,XIE Jing-pei.Microstructure of in-situ TiB2 particle reinforced 7055 aluminum alloy matrix composites[J].Transactions of Materials and Heat Treatment,2015,36(5):29-34.
- [3] 张翼,颜庆华,寇宝弘,等.TiB2p 颗粒含量及热处理对自生 TiB2p/7075 基构型复合材料组织和力学性能的影响[J].材料热处理学报,2022,43(7):19-27.ZHANG Yi,YAN Qing-hua,KOU Bao-hong,et al.Effects of TiB2p particle content and heat treatment on microstructure and mechanical properties of in-situ TiB2p/7075-based architecture composites[J].Transactions of Materials and Heat Treatment,2022,43(7):19-27.
- [4] 王国路,陈刚,赵玉涛,等.稀土对TiB2/7055复合材料组织及性能的影响[J].材料热处理学报,2011,32(7):1-5.WANG Guo-lu,CHEN Gang,ZHAO Yu-tao,et al.Effects of rare earth element on microstructure and mechanical properties of TiB2/7055 composites[J].Transactions of Materials and Heat Treatment,2011,32(7):1-5.
- [5] 雷晓维,宋雁飞,张觐韬,等.Al-4%Cu合金组织的纳米复合化调控与性能研究[J].材料热处理学报,2022,43(2):10-16.LEI Xiao-wei,SONG Yan-fei,ZHANG Jin-tao,et al.Regulation of microstructure and properties of Al-4%Cu alloy by adding nanoparticles[J].Transactions of Materials and Heat Treatment,2022,43(2):10-16.
- [6] 丁海民,王同贺,张子寒,等.Al-5Ti-1B 中间合金在铝熔体中的沉淀行为[J].材料热处理学报,2022,43(5):31-39.DING Hai-min,WANG Tong-he,ZHANG Zi-han,et al.Sedimentation behavior of Al-5Ti-1B master alloy in aluminum melt[J].Transactions of Materials and Heat Treatment,2022,43(5):31-39.
- [7] Xue Y Q,Hao Q T,Li B,et al.Improving the strength-ductility trade-off of TiB2/Al-4.5%Cu composites via Mg-Ag microalloying and multi-step heat treatment[J].Materials Research Express,2021,8(5):056519.
- [8] Dong B X,Li Q,Wang Z F,et al.Enhancing strength-ductility synergy and mechanisms of Al-based composites by size-tunable in-situ TiB2 particles with specific spatial distribution[J].Composites Part B Engineering,2021,217:108912.
- [9] Xie X L,Chen C Y,Chen Z,et al.Achieving simultaneously improved tensile strength and ductility of a nano-TiB2/AlSi10Mg composite produced by cold spray additive manufacturing[J].Composites Part B Engineering,2020,202:108404.
- [10] Wang H,Zhang H M,Cui Z S,et al.Investigation on the high-temperature ductility and fracture mechanisms of an in-situ particle reinforced Al matrix composite 7075Al/TiB2[J].Materials Science and Engineering A,2019,764:138263.
- [11] Wang T,Chen Z,Zheng Y,et al.Development of TiB2 reinforced aluminum foundry alloy based in situ composites-Part II:Enhancing the practical aluminum foundry alloys using the improved Al-5wt%TiB2 master composite upon dilution[J].Materials Science and Engineering A,2014,605:22-32.
- [12] Chen Z,Wang T,Zheng Y,et al.Development of TiB2 reinforced aluminum foundry alloy based in situ composites-Part I:An improved halide salt route to fabricate Al-5wt%TiB2 master composite[J].Materials Science and Engineering A,2014,605:301-309.
- [13] Gao Q,Wu S,Lv S,et al.Preparation of in-situ 5 vol% TiB2 particulate reinforced Al-4.5Cu alloy matrix composites assisted by improved mechanical stirring process[J].Materials & Design,2016,94:79-86.
- [14] Liu K,Li Y,Duan M G,et al.Fatigue life prediction of in-situ TiB2/2024 aluminum matrix composite[J].International Journal of Fatigue,2021,145:106128.
- [15] Geng J W,Li Y G,Xiao H Y,et al.Study fatigue crack initiation in TiB2/Al-Cu-Mg composite by in-situ SEM and X-ray microtomography[J].International Journal of Fatigue,2021,142:105976.
- [16] Ma Y,Addad A,Ji G,et al.Atomic-scale investigation of the interface precipitation in a TiB2 nanoparticles reinforced Al-Zn-Mg-Cu matrix composite[J].Acta Materialia,2020,185:287-299.
- [17] Liu Y,Han Q.Interaction between nucleant particles and a solid-liquid interface in Al-4.5Cu alloy[J].Acta Materialia,2021,213:116956.
- [18] Li J H,Hage F S,Ramasse Q M,et al.The nucleation sequence of α-Al on TiB2 particles in Al-Cu alloys[J].Acta Materialia,2021,206:116652.
- [19] Wang Q,Li Y Y,Chen Z,et al.Understanding alloying behaviors of Sc,Ni and Zn additions on Al/TiB2 interfaces based on interfacial characteristics and solute properties[J].Surfaces and Interfaces,2021,26:101427.
- [20] Lohar A K,Mondal B N,Panigrahi S C.Effect of Mg on the microstructure and mechanical properties of Al0.3Sc0.15Zr-TiB2 composite[J].Journal of Materials Engineering and Performance,2011,20(9):1575-1582.
- [21] Yang S,Zhang R,Liu H,et al.Effect of La on microstructure and corrosion behavior of 10%TiB2(p)/Al-5%Cu composites[J].Journal of Materials Research and Technology,2020,9(4):7047-7058.
- [22] Zhang X B,Zhu P,Zeng L,et al.Effect of adding Ce on the hot-tearing susceptibility of the 5TiB2/Al-5Cu composite[J].Materials Characterization,2020,168:110552.
- [23] Zhang X B,Sun J,Wang M L,et al.Improvement of yttrium on the hot tearing susceptibility of 6TiB2/Al-5Cu composite[J].Journal of Rare Earths,2015,33(12):1335-1340.
- [24] Xue Y Q,Li B,Wang X L,et al.Effect of Mg on the microstructure evolution and mechanical properties of 5%TiB2/Al-4.5%Cu composites[J].Materials Today Communications,2021,28:102625.
- [25] Zhang X,Hu J Y,Dong B X,et al.Effect of Cu and Zn elements on morphology of ceramic particles and interfacial bonding in TiB2/Al composites[J].Ceramics International,2022,48(18):25894-25904.
- [26] Zhang T T,Feng K,Li Z G,et al.Effects of rare earth elements on the microstructure and wear properties of TiB2 reinforced aluminum matrix composite coatings:Experiments and first principles calculations[J].Applied Surface Science,2020,530:147051.
- [27] Wang Q,Li Y Y,Chen S Y,et al.Interface alloying design to improve the dispersion of TiB2 nanoparticles in Al composites:A first-principles study[J].Journal of Physical Chemistry C,2021,125(10):5937-5946.
- [28] Dorin T,Babaniaris S,Jiang L,et al.Stability and stoichiometry of L12 Al3(Sc,Zr) dispersoids in Al-(Si)-Sc-Zr alloys[J].Acta Materialia,2021,216:117117.
- [29] Gao Y H,Cao L F,Kuang J,et al.Assembling dual precipitates to improve high-temperature resistance of multi-microalloyed Al-Cu alloys[J].Journal of Alloys and Compounds,2020,822:153629.
- [30] Dorin T,Ramajayam M,Lamb J,et al.Effect of Sc and Zr additions on the microstructure/strength of Al-Cu binary alloys[J].Materials Science and Engineering A,2017,707:58-64.
- [31] Vo N Q,Dunand D C,Seidman D N.Improving aging and creep resistance in a dilute Al-Sc alloy by microalloying with Si,Zr and Er[J].Acta Materialia,2014,63:73-85.
- [32] Wang Y,Zhang S,Wu R Z,et al.Coarsening kinetics and strengthening mechanisms of core-shell nanoscale precipitates in Al-Li-Yb-Er-Sc-Zr alloy[J].Journal of Materials Science & Technology,2021,61:197-203.
- [33] Gao Y H,Cao L F,Yang C,et al.Co-stabilization of θ′-Al2Cu and Al3Sc precipitates in Sc-microalloyed Al-Cu alloy with enhanced creep resistance[J].Materials Today Nano,2019,6:100035.
- [34] Jiang L,Rouxel B,Langan T,et al.Coupled segregation mechanisms of Sc,Zr and Mn at θ′ interfaces enhances the strength and thermal stability of Al-Cu alloys[J].Acta Materialia,2021,206:116634.
- [35] Senkov O N,Shagiev M R,Senkova S V,et al.Precipitation of Al3(Sc,Zr) particles in an Al-Zn-Mg-Cu-Sc-Zr alloy during conventional solution heat treatment and its effect on tensile properties[J].Acta Materialia,2008,56(15):3723-3738.
- [36] Robson J D.A new model for prediction of dispersoid precipitation in aluminium alloys containing zirconium and scandium[J].Acta Materialia,2004,52(6):1409-1421.
- [37] Fuller C B,Seidman D N,Dunand D C.Mechanical properties of Al(Sc,Zr) alloys at ambient and elevated temperatures[J].Acta Materialia,2003,51(16):4803-4814.
- [38] Hu S,Baskes M,Stan M,et al.Atomistic calculations of interfacial energies,nucleus shape and size of θ′ precipitates in Al-Cu alloys[J].Acta Materialia,2006,54(18):4699-4707.
- [39] Rakhmonov J U,Bahl S,Shyam A,et al.Cavitation-resistant intergranular precipitates enhance creep performance of θ′-strengthened Al-Cu based alloys[J].Acta Materialia,2022,228:117788.
- [40] Saha S,Todorova T Z,Zwanziger J W.Temperature dependent lattice misfit and coherency of Al3X (X=Sc,Zr,Ti and Nb) particles in an Al matrix[J].Acta Materialia,2015,89:109-115.
- [41] Guo Q,Li J F,Hou L L,et al.TEM characterization of dislocations in TiB2 particles after hypervelocity impact[J].Micron,2014,67:96-99.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||