原位合成Ti(CN)/Fe复合涂层及耐磨耐蚀性能In-situ synthesis of Ti(CN)/Fe composite coating and wear and corrosion resistance
赵建国,李建昌,刘扬,郝建军,孙维连,马跃进
摘要(Abstract):
采用反应氮弧熔覆技术在Q235A钢试件表面原位合成了Ti(CN)/Fe金属陶瓷复合涂层。利用扫描电镜、XRD射线衍射仪、显微硬度计、摩擦磨损试验机、电化学工作站分析了涂层形貌、涂层物相、涂层显微硬度及其耐磨耐蚀性能,并与Q235A钢进行了硬度、耐磨耐蚀对比试验。结果表明:涂层主要由Ti(CN)、Fe及少量的TiO2相组成,Ti(CN)呈细小颗粒状,涂层为良好的冶金结合;与Q235A钢相比,硬度提高了约3倍,摩擦系数约为Q235A的2/3,磨损量约为Q235A的1/2;在5%H2SO4溶液中,Ti(CN)涂层的腐蚀速率约为Q235A的1/3,在3.5%NaCl溶液中,Ti(CN)涂层的腐蚀速率约为Q235A钢的1/4。
关键词(KeyWords): 原位合成;反应氮弧熔覆技术;Ti(CN)/Fe涂层;耐蚀性;耐磨性
基金项目(Foundation): 河北省杰出青年科学基金项目(E2011204036);; 河北省科技支撑计划项目(12211025)
作者(Author): 赵建国,李建昌,刘扬,郝建军,孙维连,马跃进
DOI: 10.13289/j.issn.1009-6264.2014.05.035
参考文献(References):
- [1]钟金豹,黄传真.纳米氧化锆增韧氧化铝基陶瓷刀具材料的研究[J].工具技术,2008,42(10):51-53.ZHONG Jin-bao,HUANG Chuan-zhen.Study on ceramic tool material with nano-scale zirconia toughening alumina matrix[J].Tool Engineering,2008,42(10):51-53.
- [2]郝建军,马跃进,黄继华,等.氩弧熔覆Ni60A耐磨层在农机刀具上的应用[J].农业工程学报,2005,21(11):73-76.HAO Jian-jun,MA Yue-jin,HUANG Ji-hua,et al.Application of argon-arc clad Ni60A anti-abrasion coatings for cutter of agricultural machinery[J].Transactions of the Chinese Society of Agricultural Engineering,2005,21(11):73-76.
- [3]郝建军,黄继华,赵建国,等.电火花沉积反应合成TiN增强金属基复合涂层[J].焊接学报,2007,28(10):33-36.HAO Jian-jun,HUANG Ji-hua,ZHAO Jian-guo,et al.Reactive synthesis TiN reinforced matrix composite coating by electric-spark deposition[J].Transactions of the China Welding Institution,2007,28(10):33-36.
- [4]宋思利,邹增大,王新洪,等.多层氩弧熔敷含TiC颗粒增强涂层的微观组织及耐磨性能[J].焊接学报,2007,28(4):33-37.SONG Si-li,ZOU Zeng-da,WANG Xin-hong,et al.Microstructure and wear-resisting property of TiC particle reinforced coatings claded by TIG welding with multiple layer[J].Transactions of the China Welding Institution,2007,28(4):33-37.
- [5]郭立新,刘荣祥,王亚明,等.钛合金表面激光重熔NiCrBSi+TiN涂层的组织研究[J].材料热处理学报,2009,30(2):134-137.GUO Li-xin,LIU Rong-xiang,WANG Ya-ming,et al.Study on microstructure of laser remelted NiCrBSi+TiN coatings on surface of tianium alloy[J].Transactions of Materials and Heat Treatment,2009,30(2):134-137.
- [6]朱琳,何继宁,阎殿然,等.利用反应等离子喷涂制备TiCN涂层的研究[J].材料导报,2006,20(S2):468-470.ZHU Lin,HE Ji-ning,YAN Dian-ran,et al.The Study on TiCN coating prepared by reactive plasma spraying[J].Materials Review,2006,20(S2):468-470.
- [7]吴玉萍.等离子弧熔覆Fe基合金+TiC涂层中的陶瓷相行为与相结构[J].焊接学报,2001,22(6):89-91.WU Yu-ping.The behavior and structure of TiC phase in Fe matrix alloy and TiC ceram cladded by arc plasma[J].Transactions of the China Welding Institution 2001,22(6):89-91.
- [8]郝建军,黄继华,刘洪杰,等.反应电火花沉积TiN/Ti复合涂层机理与性能[J].材料热处理学报,2009,30(3):170-173.HAO Jian-jun,HUANG Ji-hua,LIU Hong-jie,et al.Forming mechanism and property of TiN/Ti composite coatings prepared by reactive electric-spark deposition[J].Transactions of Materials and Heat Treatment,2009,30(3):170-173.
- [9]李建平,高见,曾祥才,等.中温化学气相沉积(MTCVD)工艺技术及超级涂层材料的研究[J].工具技术,2004,38(9):72-75.LI Jian-ping,GAO Jian,ZENG Xiang-cai,et al.Study on medium temperature chemical vapor deposition(MTCVD)technology and super coating material[J].Tool Engineering,2004,38(9):72-75.
- [10]CHAO Sheng,LIU Ning,YUAN Yu-peng,et al.Microstructure and mechanical properties of ultrafine Ti(C,N)-based cermets fabricated from nano/submicro starting powders[J].Ceramics International,2005,31(6):851-862.
- [11]郝建军,黄继华,周志军,等.钛合金表面反应电火花沉积Ti(CN)涂层研究[J].材料热处理学报,2008,29(2):128-130.HAO Jian-jun,HUANG Ji-hua,ZHOU Zhi-jun,et al.Reactive electric-spark deposition Ti(CN)-based ceramets coating on titanium alloy[J].Transactions of Materials and Heat Treatment,2008,29(2):128-130.
- [12]杨玉玲,刘常升,张多,等.激光熔覆-激光气体氮化方法制取TiCN-TiN复合熔覆层[J].东北大学学报:自然科学版,2007,28(9):1289-1292.YANG Yu-ling,LIU Chang-sheng,ZHANG Duo,et al.Preparation of TiCN-TiN compound cladding by LC-LGN technology[J].Journal of Northeastern University:Natural Science,2007,28(9):1289-1292.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||