热处理后La0.80Mg0.20Ni3.70合金循环容量衰减的机理Cyclic capacity decay mechanism of La0.80Mg0.20Ni3.70 alloy after annealing treatment
董小平,杨丽颖,王青,朱凯宁,王涛,王翠表
摘要(Abstract):
为研究热处理后La-Mg-Ni系合金的循环容量衰减机理,制备铸态及热处理后La0.80Mg0.20Ni3.70合金。结果表明,合金经热处理后,其循环容量衰减速率减小。热处理后合金中各物相间Mg和Ni元素的浓度差降低。随热处理温度升高,合金中各相间电化学腐蚀的混合腐蚀电位绝对值和最大腐蚀电流先减小后增加,950℃热处理后合金明显好于其他合金。合金颗粒粉化、活性元素的氧化以及各相间的电化学腐蚀是合金电极失效的重要原因。
关键词(KeyWords): 热处理;La-Mg-Ni系合金;相成分;容量衰减;机理
基金项目(Foundation): 河北省自然科学基金项目(E2010000301);; 河北大学自然科学研究计划项目(2009-152,2009-153);; 河北省高等学校科学研究计划项目(Z2012168);; 保定市科学计划研究与发展指导计划项目(12ZG018)
作者(Author): 董小平,杨丽颖,王青,朱凯宁,王涛,王翠表
DOI: 10.13289/j.issn.1009-6264.2012.12.002
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