Sn添加对Cu-3Ni-0.75Si-0.1Mg合金高温抗软化性能的影响及其机理Effect of Sn addition on high temperature softening resistance of Cu-3Ni-0.75Si-0.1Mg alloy and its mechanism
揭晓,钟强强,李钊,陈金水,肖翔鹏
摘要(Abstract):
采用中频感应熔炼炉制备了4种不同Sn含量的Cu-3Ni-0.75Si-0.1Mg-xSn合金,研究了Sn添加对Cu-3Ni-0.75Si-0.1Mg合金高温抗软化性能的影响及其作用机理。结果表明,Sn元素的添加可提高合金的峰值硬度,且随着Sn含量的增加,其提升效果更显著;0.6%Sn元素的添加可提高Cu-3Ni-0.75Si-0.1Mg合金的抗软化温度,这与Sn元素的添加阻碍合金回复和再结晶行为有关;Cu-3Ni-0.75Si-0.1Mg-xSn合金在不同温度区间的退火软化机理不同,低温退火时(450~500℃),退火软化与回复相关;中温退火时(500~600℃),退火软化主要受回复和再结晶影响;当退火温度过高时(>600℃),退火软化主要受第二相粒子的粗化影响。
关键词(KeyWords): Sn添加;Cu-3Ni-0.75Si-0.1Mg合金;高温抗软化;软化机理
基金项目(Foundation): 国家自然科学基金(51561008)
作者(Author): 揭晓,钟强强,李钊,陈金水,肖翔鹏
DOI: 10.13289/j.issn.1009-6264.2020-0517
参考文献(References):
- [1] Suzuki S,Shibutani N,Mimura K,et al.Improvement in strength and electrical conductivity of Cu-Ni-Si alloys by aging and cold rolling[J].Journal of Alloys and Compounds,2006,417(1/2):116-120.
- [2] Monzen R,Watanabe C.Microstructure and mechanical properties of Cu-Ni-Si alloys[J].Materials Science and Engineering A,2008,483-484:117-119.
- [3] Izawa K,Ozawa A,Kita K,et al.Influence of Co on strength and microstructure of Cu-Ni-Co-Si alloy[J].Journal of the Society of Materials Science Japan,2014,63(5):401-408.
- [4] 罗斐.铜合金引线框架材料的现状与发展浅析[J].装备制造技术,2017(5):269-270.LUO Fei.The status and development of lend frame material of copper alloy[J].Equipment Manufacturing Technology,2017(5):269-270.
- [5] 涂思京,阎晓东,谢水生.引线框架用铜合金C194的组织性能研究[J].稀有金属,2004,28(1):199-201.TU Si-jing,YAN Xiao-dong,XIE Shui-sheng.Structure and performance of C194 copper alloy used for lead frame[J].Rare Metals,2004,28(1):199-201.
- [6] Zhang Y,Tian B H,Liu P.High temperature deformation behavior and microstructure preparation of Cu-Ni-Si-P alloy[J].Materials Science Forum,2011,704-705:135-140.
- [7] Fujii T,Kamio H,Sugisawa Y,et al.Cyclic softening of Cu-Ni-Si alloy single crystals under low-cycle fatigue[J].Materials Science Forum,2010,654-656:1287-1290.
- [8] Delbove M,Vogt B,Bouquerel,et al.Low cycle fatigue behaviour of a precipitation hardened Cu-Ni-Si alloy[J].International Journal of Fatigue,2016,92:313-320.
- [9] Su J H,Jia S G,Ren F Z,et al.Effect of cold rolling deformation on aging precipitation of Cu-Cr-Sn-Zn alloy[J].Advanced Materials Research,2009,79-82:1507-1510.
- [10] Abib K,Azzeddine H,Tirsatine K,et al.Thermal stability of Cu-Cr-Zr alloy processed by equal-channel angular pressing[J].Materials Characterization,2016,118:527-534.
- [11] Liao W N,Liu X F,Yang Y H,et al.Relationship and mechanism between double cold rolling-aging process,microstructure and properties of Cu-Ni-Si alloy prepared by two-phase zone continuous casting[J].Materials Science and Engineering A,2020,797:140148.
- [12] Hwangsun K,Jee Hyuk A,Seung Zeon H,et al.Microstructural characterization of cold-drawn Cu-Ni-Si alloy having high strength and high conductivity[J].Journal of Alloys and Compounds,2020,832:155059.
- [13] 张斌,景洁,解亚楠.C70250带材的制备及其性能研究[J].有色金属加工,2016,45(5):41-45.ZHANG Bin,JING Jie,XIE Ya-nan.Preparation and properties of C70250 strip[J].Nonferrous Metals Processing,2016,45(5):41-45.
- [14] Long Y,Liu P,Liu Y,et al.Simulation of recrystallization grain growth during re-aging process in the Cu-Ni-Si alloy based on phase field model[J].Materials Letters,2008,62(17/18):3039-3042.
- [15] Wang D,Xia C,Kang B,et al.Aging precipitation and recrystallization of Cu-Ni-Si alloy[J].Materials Science and Technology,2008,16(2):220-225.
- [16] Zhang Y,Liu P,Tian B H,et al.Modeling of dynamic recrystallization in Cu-Ni-Si-Ag alloy[J].Special Casting and Nonferrous Alloys,2010,30(9):787-745.
- [17] 柳瑞清,谢伟滨,黄国杰,等.Co元素对Cu-3.0Ni-0.75Si合金软化温度的影响[J].稀有金属,2016,40(3):109-114.LIU Rui-qing,XIE Wei-bin,HUANG Guo-jie,et al.Softening temperature of Cu-3.0Ni-0.75Si alloy with different Co additions[J].Rare Metals,2016,40(3):109-114.
- [18] Wang J F,Jia S G,Chen S H,et al.Effect of aging precipitation on properties of Cu-Ni-Si-Mg alloy[J].Advanced Materials Research,2011,1167:1315-1320.
- [19] 上官浩龙,陈小丽,王占军.Cu-Ni-Si-Mg合金的时效特性[J].金属热处理,2013,38(1):50-53.SHANGGUAN Hao-long,CHEN Xiao-li,WANG Zhan-jun.Aging behavior of Cu-Ni-Si-Mg alloy[J].Heat Treatment of Metals,2013,38(1):50-53.
- [20] 李学浩,卞金强.CuNi2SiCrAl 耐热铜合金的工艺及性能研究[J].热加工工艺,2015,44(22):212-214.LI Xue-hao,BIAN Jin-qiang.Research on process and performance of CuNi2SiCrAl heat resisting copper Alloy[J].Hot Working Technology,2015,44(22):212-214.
- [21] 汪黎,孙扬善,付小琴.Cu-Ni-Si基引线框架合金的组织和性能[J].东南大学学报(自然科学版),2005,35(5):729-732.WANG Li,SUN Yang-shan,FU Xiao-qin.Microstructure and properties of Cu-Ni-Si based alloys for lead frame[J].Journal of Southeast University(Natural Science Edition),2005,35(5):729-732.
- [22] 林高用,张胜华.Cu-Ni-Si-Cr-Fe合金时效强化特性的研究[J].金属热处理,2001(4):28-30.LIN Gao-yong,ZHANG Sheng-hua.Study on age hardening characteristic of Cu-Ni-Si-Cr-Fe alloy[J].Heat Treatment of Metals,2001(4):28-30.
- [23] 黎三华,李周,雷前.高强度Cu-Ni-(Al)-Si合金的组织和性能[J].稀有金属材料与工程,2015,44(6):1427-1431.LI San-hua,LI Zhou,LEI Qian.Microstructure and properties of superhigh strength Cu-Ni-(Al)-Si alloy[J].Rare Metal Materials and Engineering,2015,44(6):1427-1431.
- [24] 叶艳君.Si、Sn元素对Cu-Ni-Sn-Si合金组织及性能的影响研究[D].江西:江西理工大学,2017.YE Yan-jun.Effects of Si and Sn elements on microstructure and properties of Cu-Ni-Sn-Si alloy[D].Jiangxi:Jiangxi University of Science and Technology,2017.
- [25] 高维林.Cu-Ni-Si系铜合金板材及其制造方法:日本,10004846.7[P].2011-03-02.GAO Wei-lin.Cu-Ni-Si copper alloy plate and its manufacturing method:Japan,10004846.7[P].2011-03-02.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||