含纳米Al2O3/Fe3O4的FeS固体润滑复合层的摩擦学性能Tribological performances of FeS solid lubrication duplex layer under liquid paraffin oil with n-Al2O3/ n-Fe3O4 lubricant
胡春华,杨春燕,刘庆存,孙志杰,马世宁,乔玉林
摘要(Abstract):
采用离子氮碳共渗与离子渗硫复合处理技术在45钢表面制备FeS固体润滑复合层,复合层中硫化物表层厚度约为10μm,其硫化物颗粒与孔隙均在微纳米量级且分布均匀。复合层相组成主要为FeS、FeS2和Fe3N。在含0.1%n-Al2O3+0.08%n-Fe3O4液体石蜡润滑下,复合层与纳米Al2O3/Fe3O4复合添加剂产生协同作用,磨损表面形成了由硫化物、硫酸盐、氮化物等组成的化学反应膜,使FeS固体润滑复合层表面摩擦因数最低,始终保持在0.07左右,体积磨损量最小,比未渗表面降低了92%,比渗硫表面和氮碳共渗表面分别降低了85%和44%。
关键词(KeyWords): FeS固体润滑复合层;纳米Al2O3/Fe3O4;化学反应膜;减摩耐磨
基金项目(Foundation): 国家自然科学基金资助项目(50775221)
作者(Author): 胡春华,杨春燕,刘庆存,孙志杰,马世宁,乔玉林
DOI: 10.13289/j.issn.1009-6264.2011.12.024
参考文献(References):
- [1]冯雪君,杨志伊.MnZnFe2O4磁性纳米添加剂抗磨减磨及自修复效应研究[J].中国矿业大学学报,2007,36(5):653-657.FENG Xue-jun,YANG Zhi-yi.Tribological properties and self-healing action of nano magnetic particles MnZnFe2 O4[J].Journal of China Universityof Mining&Technology,2007,36(5):653-657.
- [2]董凌,陈国需,方建华,等.硅镁型复合纳米添加剂的摩擦学及自修复性能研究[J].润滑与密封,2008,33(1):54-58.DONG Ling,CHEN Guo-xu,FANG Jian-hua,et al.Study on tribological properties and self-healing action of combined nanoparticle Si-Mg[J].Lubrication Engineering,2008,33(1):54-58.
- [3]刘新,王晓波,张立,等.三种含金属类纳米添加剂摩擦学性能比较[J].润滑油,2008,23(1):42-45.LIU Xin,WANG Xiao-bo,ZHANG Li,et al.The investigation ofthe tribological behavior of three metal nanoparticles as additives[J].Lubricating Oil,2008,23(1):42-45.
- [4]李久盛,张立,王会东.润滑油纳米添加剂研究现状及趋势[J].润滑油,2008,23(1):5-9.LI Jiu-sheng,ZHANG Li,WANG Hui-dong.Research status and development trend of nanoparticles as lubricating oil additives[J].Lubricating Oil,2008,23(1):5-9.
- [5]叶斌,陶德华.化学修饰的纳米钛酸钙的摩擦学特性研究[J].润滑与密封,2008,33(3):30-31.YE Bin,TAO De-hua.Study on tribological characteristic of chemically modified CaTiO3 nano-particles on synthetic easters[J].LubricationEngineering,2008,33(3):30-31.
- [6]李海涛,刘万辉,鲍爱莲.环保型润滑油纳米添加剂的摩擦学行为[J].中国材料科技与设备,2008,(3):47-48.LI Hai-tao,LIU Wan-hui,BAO Ai-lian.The tribological properties of environmentally friendly lubricants containing anti-wear nano additives[J].China Material Science and Technology and Equipment,2008,(3):47-48.
- [7]崔荣星,李美玉,王海飞.离子渗氮对2Cr13不锈钢磨损及冲蚀行为的影响[J].热处理,2009,24(3):55-57.CUI Rong-xing,LI Mei-yu,WANG Hai-fei.Wear and erosion-corrosion behaviors of ion-nitrided 2Cr13 stainless steel[J].Heat Treatment,2009,24(3):55-57.
- [8]刘静,钱林茂,董汉山,等.碳化、氮化与碳氮化对316LVM不锈钢微动腐蚀磨损性能的影响[J].摩擦学学报,2009,29(5):399-404.LIU Jing,QIAN Lin-mao,DONG Han-shan,et al.Effect of surface treatment on the fretting wear behavior of medical grade austenitic stainless steels[J].Tribology,2009,29(5):399-404.
- [9]胡春华,马世宁,乔玉林,等.45钢表面离子渗硫层组成与减摩过程的研究[J].材料热处理学报,2009,30(4):134-137.HU Chun-hua,MA Shi-ning,QIAO Yu-lin,et al.Study on friction reduction process and composition of ion sulphurized layer on 45 steel[J].Transactions of Materials and Heat Treatment,2009,30(4):134-137.
- [10]Zhang N,Zhuang D M,Liu J J.Tribological behaviors of steel surfaces treated with ion sulphurization duplex processes[J].Surface and CoatingsTechnology,2009,203(20-21):3173-3177.
- [11]Li X F,Wang Y,Meng L.Microstructure and optical absorption of FeS2 films formed by sulfurizing precursive iron of various crystallite scales[J].Materials Research Bulletin,2009,44(2):462-467.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||