Ni-Mo-Y-Gr复合材料的制备及其在宽温域条件下的摩擦学性能Preparation and tribological properties in wide temperature range of Ni-Mo-Y-Gr composites
陆龙,杨贵荣,苏霄鹏,张文辉,王静波
摘要(Abstract):
采用放电等离子烧结技术制备了Ni-Mo-Y-Gr(石墨烯)自润滑复合材料,通过光学显微镜、扫描电镜、X射线衍射、拉曼及高温摩擦实验机对复合材料的微观组织、成分、力学性能及摩擦磨损性能进行了研究。结果表明:Ni-Mo-Y-Gr复合材料的组织均匀致密,随着石墨烯含量的增加,复合材料的密度、硬度及屈服强度呈下降趋势,实际密度大于计算理论密度,即复合材料制备过程中发生了冶金熔合与固溶;Ni-Mo-Y-Gr复合材料在室温至600℃范围内具有较低的摩擦系数及磨损率,表明其具有较好的摩擦学性能;在室温、200和400℃时石墨烯起到了良好的润滑作用,在600℃时的主要润滑相为石墨烯、NiO、MoO_2、MoO_3和NiMoO_4;在800℃时形成NiMoO_4及镍钼的氧化物,难以形成完整、有效的润滑层,从而使复合材料的摩擦学性能有所下降。
关键词(KeyWords): Ni-Mo-Gr复合材料;粉末冶金;微观结构;摩擦学性能
基金项目(Foundation): 兰州市科技计划项目(2019-1-17);; 国家级“大学生创新创业训练计划”项目(202111562007)
作者(Author): 陆龙,杨贵荣,苏霄鹏,张文辉,王静波
DOI: 10.13289/j.issn.1009-6264.2023-0325
参考文献(References):
- [1] Feng X L,Wang H F,Liu X C,et al.Effect of Al content on wear and corrosion resistance of Ni-based alloy coatings by laser cladding[J].Surface and Coatings Technology,2021,412:126976.
- [2] Xu K,Jiang H,Yan J B,et al.Tensile properties and deformation mechanisms of a solution treated Ni-Fe-based alloy at high temperatures[J].Materials Science and Engineering A,2023,881:145418.
- [3] Frelek-Kozak M,Mulewska K,Wilczopolska M,et al.The effects of high-temperature ion-irradiation on early-stage grain boundaries serrations formation in Ni-based alloys[J].Materials Characterization,2023,203:113060.
- [4] Vega J M,Ganborena L,Gonzalez G Y,et al.Exploring the effect of the pH on the corrosion of multilayer nickel-chromium coatings[J].Corrosion Science,2023,210:110819.
- [5] Shen Z,Zeng X Q,Wang Y,et al.Fretting wear-induced sudden loss of corrosion resistance in a corrosion-resistant Ni-based alloy[J].Materials Characterization,2023,201:112955.
- [6] 杨素兰.宽温域内具有高强度和连续自润滑性能的镍基材料的研究[D].兰州:兰州理工大学,2017.YANG Su-lan.The research on Ni-based materials with high strength and continuous self-lubricating performance in wide temperature range[D].Lanzhou:Lanzhou University of Technology,2017.
- [7] Liu E Y,Wang W Z,Gao Y M,et al.Tribological properties of adaptive Ni-based composites with addition of lubricious Ag2MoO4 at elevated temperatures[J].Tribology Letters,2012,47(1):21-30.
- [8] 李珍,张亚丽,周健松,等.Ni-Mo基高温自润滑复合材料摩擦学性能的研究[J].摩擦学学报,2018,38(2):161-169.LI Zhen,ZHANG Ya-li,ZHOU Jian-song,et al.Tribological properties of Ni-based high temperature self-lubricating composite[J].Tribology,2018,38(2):161-169.
- [9] 刘秀晨,安成强,崔作兴,等.金属腐蚀学[M].北京:国防工业出版社,2002.LIU Xiu-chen,AN Cheng-qiang,CUI Zuo-xing,et al.Corrosion Science of Metal[M].Beijing:National Defense Industry Press,2002.
- [10] Christopher D.The effects of substrate material and thermal processing atmosphere on the strength of PS304:A high temperature solid lubricant coating[J].Tribology Transactions,2003,46(3):361-368.
- [11] 阚存一,刘近朱,张国威,等.一种镍-铬-硫合金的研制及其摩擦学特性[J].摩擦学学报,1994(3):193-204.KAN Cun-yi,LIU Jin-zhu,ZHANG Guo-wei,et al.Preparation and tribological performance of a Ni-Cr-S alloy[J].Triblogy,1994(3):193-204.
- [12] 熊党生,葛世荣,李丽娅,等.Ni-Cr-Mo-Al-Ti-B-MoS2系合金高温摩擦学特性的研究[J].摩擦学学报,1999(4):316-321.XIONG Dang-sheng,GE Shi-rong,LI Li-ya,et al.Study on the high temperature tribological properties of Ni-Cr based alloys containing MoS2[J].Tribology,1999(4):316-321.
- [13] 刘如铁,李溪滨,熊拥军,等.二硫化钼添加方式对Ni-Cr基高温自润滑材料性能的影响[J].材料工程,2005(7):7-10.LIU Ru-tie,LI Xi-bin,XIONG Yong-jun,et al.Effects of different ways of adding MoS2 on the performance of Ni-Cr base high-temperature self-lubricating alloys[J].Journal of Materials Engineering,2005(7):7-10.
- [14] Li J L,Xiong D S.Tribological behavior of graphite-containing nickel-based composite as function of temperature,load and counterface[J].Wear,2009,266(1/2):360-367.
- [15] Shi X L,Song S Y,Zhai W Z,et al.Tribological behavior of Ni3Al matrix self-lubricating composites containing WS2,Ag and hBN tested from room temperature to 800 ℃[J].Materials and Design,2014,55:75-84.
- [16] 朱定一,关翔锋,陈丽娟,等.新型Ni3Al/石墨高温固体自润滑材料的制备及其性能[J].中国有色金属学,2004,14(4):528-533.ZHU Ding-yi,GUAN Xiang-feng,CHEN Li-juan,et al.Preparation and properties of high-temperature self-lubricating Ni3Al/graphite alloy[J].Chinese Journal of Nonferrous Metals,2004,14(4):528-533.
- [17] Niu M Y,Bi Q L,Yang J,et al.Tribological performance of a Ni3Al matrix self-lubricating composite coating tested from 25 to 1000 ℃[J].Surface and Coatings Technology,2012,206(19/20):3938-3943.
- [18] Zhu S Y,Li F,Ma J Q,et al.Tribological properties of Ni3Al matrix composites with addition of silver and barium salt[J].Tribology International,2015,84:118-123.
- [19] Zhai W Z,Shi X L,Yang K,et al.Tribological behaviors of Ni3Al intermetallics with MoO3 multilayer ribbon crystal prepared by spark plasma sintering[J].Acta Metallurgical Sinica,2017,30(6):576-584.
- [20] Berman D,Erdemir A,Sumant A V.Reduced wear and friction enabled by graphene nanoplates layers on sliding steel surfaces in dry nitrogen[J].Carbon,2013,59:167-175.
- [21] Llorent J,Roman M B,Miranzo P,et al.Tribological performance under dry sliding conditions of graphene/silicon carbide composition[J].Journal of the European Ceramic Society,2016,36(3):429-435.
- [22] Zhai W Z,Shi X L,Wang M,et al.Grain refinement:A mechanism for graphene nanoplatelets to reduce friction and wear of Ni3Al matrix self-lubricating composites[J].Wear,2014,310(1/2):33-40.
- [23] Zhai W Z,Shi X L,Yao J,et al.Investigation of mechanical and tribological behaviors of multilayer graphene reinforced Ni3Al matrix composites[J].Composites Part B:Engineering,2015,70:149-155.
- [24] 李文文,杨丽颖,王守仁,等.石墨烯增强TiAl自润滑复合材料的力学性能研究[J].机械强度,2019,41(5):1085-1089.LI Wen-wen,YANG Li-ying,WANG Shou-ren,et al.Research on mechanical of graphene reinforced TiAl self-lubricating composite materials[J].Journal of Mechanical Strength,2019,41(5):1085-1089.
- [25] 冯彦寒,方建华,吴江,等.石墨烯掺杂的陶瓷和金属自润滑材料研究进展[J].摩擦学学报,2019,39(4):511-521.FENG Yan-hang,FANG Jian-hua,WU Jiang,et al.Research progress of graphene doped ceramic and metal self-lubricating materials[J].Tribology,2019,39(4):511-521.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||