热处理对Mg-10Y-1Zn-0.5Zr镁合金微观组织和力学性能的影响Effect of heat treatment on microstructure and mechanical properties of Mg-10Y-1Zn-0.5Zr alloy
刘明明,李全安,陈晓亚,陈君,陈培军,谭劲峰,李向宇
摘要(Abstract):
采用光学显微镜、扫描电镜、X射线衍射仪和电子拉伸试验机等研究了不同热处理对Mg-10Y-1Zn-0.5Zr合金的微观组织和力学性能的影响。结果表明:铸态Mg-10Y-1Zn-0.5Zr合金组织主要由α-Mg基体、Mg_3Y_2Zn_3(W)相以及Mg_(10)YZn(18R-LPSO)相构成;固溶处理后,LPSO相从18R型转变为14H型LPSO(Mg_(12)YZn),固溶态合金组织主要由α-Mg基体和Mg_(12)YZn(14H-LPSO)相组成;时效处理后,合金组织主要由α-Mg基体、Mg_3Y_2Zn_3(W)相和Mg_(12)YZn(14H-LPSO)相组成。Mg-10Y-1Zn-0.5Zr合金的最佳热处理工艺为500℃固溶12 h+225℃时效80 h;此时合金的极限抗拉强度和屈服强度由铸态的185.83 MPa和116.25 MPa增加到269.53 MPa和162.76 MPa,伸长率由8.21%升高到15.66%。
关键词(KeyWords): Mg-Y-Zn-Zr合金;LPSO相;微观组织;力学性能;热处理
基金项目(Foundation): 国家自然科学基金(51571084);; 中原英才计划—中原青年拔尖人才(豫组通[2021]44号);; 河南省自然科学基金(222300420435)
作者(Author): 刘明明,李全安,陈晓亚,陈君,陈培军,谭劲峰,李向宇
DOI: 10.13289/j.issn.1009-6264.2021-0607
参考文献(References):
- [1] 任聪林,宽军,曹鑫,等.挤压速度对Mg-2Y-1Zn-0.4Zr合金组织演变、力学性能和动态腐蚀行为的影响[J].材料热处理学报,2020,41(9):117-125.REN Cong-lin,KUAN Jun,CAO Xin,et al.Effect of extrusion speed on microstructure evolution,mechanical properties and dynamic corrosion behavior of Mg-2Y-1Zn-0.4Zr alloy[J].Transactions of Materials and Heat Treatment,2020,41(9):117-125.
- [2] 曾小勤,吴玉娟,彭立明,等.Mg-Gd-Zn-Zr合金中的LPSO结构和时效相[J].金属学报,2010,46(9):1041-1046.ZENG Xiao-qin,WU Yu-juan,PENG Li-ming,et al.LPSO structure and aging phases in Mg-Gd-Zn-Zr alloy[J].Acta Metallurgica Sinica,2010,46(9):1041-1046.
- [3] You S,HuangY,Kainer K U,et al.Recent research and developments on wrought magnesium alloys[J].Journal of Magnesium and Alloys,2017,5(3):239-253.
- [4] 李响,毛萍莉,王峰,等.长周期有序堆垛相(LPSO)的研究现状及在镁合金中的作用[J].材料导报,2019,33(7):1182-1189.LI Xiang,MAO Ping-li,WANG Feng,et al.A literature review on study of long period stacking ordered phase and its effect on magnesium alloys[J].Materials Reports,2019,33(7):1182-1189.
- [5] Lu R P,Wang J F,Chen Y L,et al.Effects of heat treatment on the morphology of long-period stacking ordered phase,the corresponding damping capacities and mechanical properties of Mg-Zn-Y alloys[J].Journal of Alloys and Compounds,2015,639:541-546.
- [6] Li Z,Wan D,Huang Y,et al.Characterization of a Mg95.5Zn1.5Y3 alloy both containing W phase and LPSO phase with or without heat treatment[J].Journal of Magnesium and Alloys,2017,5(2):217-224.
- [7] Zhu Y M,Morton A J,Nie J F.Growth and transformation mechanisms of 18R and 14H in Mg-Y-Zn alloys[J].Acta Materialia,2012,60(19):6562-6572.
- [8] Kawamura Y,Hayashi K,Inoue A,et al.Rapidly solidified powder metallurgy Mg97Zn1Y2 alloys with excellent tensile yield strength above 600 MPa[J].Materials Transactions,2001,42(7):1172-1176.
- [9] Ding Z B,Zhao Y H,Lu R P,et al.Effect of zn addition on microstructure and mechanical properties of cast Mg-Gd-Y-Zr alloys[J].Transactions of Nonferrous Metals Society of China,2019,29(4):722-734.
- [10] Hagihara K,Kinoshita A,Sugino Y,et al.Effect of long-period stacking ordered phase on mechanical properties of Mg97Zn1Y2 extruded alloy[J].Acta Materialia,2010,58(19):6282-6293.
- [11] Liu W,Zhang J S,Xu C X,et al.High-performance extruded Mg89Y4Zn2Li5 alloy with deformed LPSO structures plus fine dynamical recrystallized grains[J].Materials and Design,2016,110:1-9.
- [12] Zhu Y M,Morton A J,Nie J F.The 18R and 14H long-period stacking ordered structures in Mg-Y-Zn alloys[J].Acta Materialia,2010,58(8):2936-2947.
- [13] Zhang Z,Liu X,Hu W,et al.Microstructures,mechanical properties and corrosion behaviors of Mg-Y-Zn-Zr alloys with specific Y/Zn mole ratios[J].Journal of Alloys and Compounds,2015,624:116-125.
- [14] Liao H,Kim J,Lee T,et al.Effect of heat treatment on LPSO morphology and mechanical properties of Mg-Zn-Y-Gd alloys[J].Journal of Magnesium and Alloys,2020,8(4):1120-1127.
- [15] 丁科迪.热处理工艺对Mg-Gd-Y(-Zn)-Zr合金组织及力学性能的影响[D].哈尔滨:哈尔滨工业大学,2017.DING Ke-di.Effect of heat teatment process on microstructure and mechanical properties of Mg-Gd-Y(-Zn)-Zr alloy[D].Harbin:Harbin Institute of Technology,2017.
- [16] Itoi T,Seimiya T,Kawamura Y,et al.Long period stacking structures observed in Mg97Zn1Y2 alloy[J].Scripta Materialia,2004,51(2):107-111.
- [17] Hagihara K,Yokotani N,Umakoshi Y.Plastic deformation behavior of Mg12YZn with 18R long-period stacking ordered structure[J].Intermetallics,2010,18(2):267-276.
- [18] Zhang Y,Zeng X,Liu L,et al.Effects of yttrium on microstructure and mechanical properties of hot-extruded Mg-Zn-Y-Zr alloys[J].Materials Science and Engineering A,2004,373(1/2):320-327.
- [19] Pan F S,Luo S Q,Tang A T,et al.Influence of stacking fault energy on formation of long period stacking ordered structures in Mg-Zn-Y-Zr alloys[J].Progress in Natural Science:Materials International,2011,21(6):485-490.
- [20] Zhou X,Yao Y,Zhang J,et al.Improved workability for Mg-Y-Zn alloys via increased volume fraction of block LPSO phases[J].Materials Science and Engineering A,2020,794:139934.
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