热处理对Mg-11Gd-3Y-0.8Ca-0.5Zr合金显微组织及性能的影响Effect of heat treatment on microstructure and properties of Mg-11Gd-3Y-0.8Ca-0.5Zr alloy
张帅,李全安,朱宏喜,陈晓亚,王颂博,关海昆
摘要(Abstract):
采用光学显微镜、扫描电镜、X射线衍射仪、XHB-3000型布氏硬度计和万能电子拉伸实验机等研究了Mg-11Gd-3Y-0.8Ca-0.5Zr合金的最佳热处理工艺和热处理对合金显微组织及性能的影响。结果表明:合金的最佳固溶工艺为485℃×16 h+505℃×16 h,时效工艺为225℃×12 h。铸态合金主要由初生相α-Mg基体和大量处于晶界处网络状的Mg_5Gd、Mg_(24)Y_5、Mg_2Ca相组成。经固溶时效后,相种类没有变化,但晶界变得清晰,第二相的形貌显著改变,呈颗粒状和短棒状均匀分布在基体上,组织得到明显改善,合金的力学性能显著提高,时效态合金的抗拉强度、屈服强度及硬度均显著优于铸态合金,分别由原来的217 MPa、185 MPa和92 HB增加到265 MPa、228 MPa和121 HB,这主要归功于时效沉淀强化的作用。
关键词(KeyWords): Mg-11Gd-3Y-0.8Ca-0.5Zr合金;固溶;时效;显微组织
基金项目(Foundation): 国家自然科学基金(51571084,51171059)
作者(Author): 张帅,李全安,朱宏喜,陈晓亚,王颂博,关海昆
DOI: 10.13289/j.issn.1009-6264.2019-0317
参考文献(References):
- [1] 吴文祥,靳丽,董杰,等.Mg-Gd-Y-Zr高强耐热镁合金的研究进展[J].中国有色金属学报,2011,21(11):2709-2718.WU Wen-xiang,JIN Li,DONG Jie,et al.Research progress of high strength and heat resistant Mg-Gd-Y-Zr alloys[J].The Chinese Journal of Nonferrous Metals,2011,21(11):2709-2718.
- [2] Pan F S,Yang M B,Chen X H,et al.A review on casting magnesium alloys:modification of commercial alloys and development of new alloys[J].Journal of Materials Science & Technology,2016,32 (12):1211-1221.
- [3] Wan Y C,Xiao H C,Jiang S N,et al.Microstructure and mechanical properties of semi-continuous cast Mg-Gd-Y-Zr alloy[J].Materials Science and Engineering A,2014,617:243-248.
- [4] 辛明德,吉泽升.稀土元素在铸造镁合金中应用的研究现状及其发展趋势[J].中国稀土学报,2010,28(6):643-653.XIN Ming-de,JI Ze-sheng.Research situation and application prospects of rare earth in foundry magnesium alloy[J].Journal of the Chinese Rare Earth Society,2010,28(6):643-653.
- [5] Rokhlin L L,Dobatkina T V,Nikitina N I,et al.Constitution and properties of the ternary magnesium alloys containing two rare-earth metals of different Subgroups[J].Materials Science Forum,2003,419:291-296.
- [6] Anyanwu I A,Kamado S,Kojima Y,et al.Aging characteristics and high temperature tensile properties of Mg-Gd-Y-Zr alloys[J].Materials Transations,2001,42 (7):1206-1211.
- [7] 李全安,李克杰,陈君,等.一种耐热稀土镁合金:中国,CN200910064626.8[P].2010-12-08.
- [8] 曹林锋,杜文博,苏学宽,等.Ca合金化在镁合金中的作用[J].铸造技术,2006(2):182-184.CAO Lin-feng,DU Wen-bo,SU Xue-kuan,et al.Role of calcium alloying in magnesium alloys[J].Foundry Technology,2006(2):182-184.
- [9] 刘成龙.添加Ca对Mg-Gd-Zr合金的组织结构和性能的影响[D].重庆:重庆大学,2017.LIU Cheng-long.Effect of Ca additions on microstructure and mechanical properties of Mg-Gd-Zr alloy[D].Chongqing:Chongqing University,2017.
- [10] Lee Y C,Dahle A K,StJohn D H,et al.The role of solute in grain refinement of magnesium[J].Metallurgical and Materials Transactions A,2000,31(11):2895-2906.
- [11] 冯艳,李晓庚,王日初,等.热处理过程中Mg-8Gd-3Y-1Nd-0.5Zr合金的组织演变及性能[J].中国有色金属学报,2017,27(9):1794-1802.FENG Yan,LI Xiao-geng,WANG Ri-chu,et al.Microstructure evolution and performance of Mg-8Gd-3Y-1Nd-0.5Zr alloy during heat treatment[J].The Chinese Journal of Nonferrous Metals,2017,27(9):1794-1802.
- [12] 付三玲,李全安,井晓天,等.热处理对Mg-12Gd-2Y-0.5Sm-0.5Sb-0.5Zr显微组织的影响[J].材料热处理学报,2014,35(4):46-50.FU San-ling,LI Quan-an,JING Xiao-tian,et al.Effects of heat treatment on microstructure of Mg-12Gd-2Y-0.5Sm-0.5Sb-0.5Zr alloy[J].Transactions of Materials and Heat Treatment,2014,35(4):46-50.
- [13] Nie J F,Muddle B C.Characterizations of strengthening precipitate phase in a Mg-Y-Nd alloy[J].Acta Materialia,2000,48(8):1691-1703.
- [14] Cao L,Liu W C,Li Z Q,et al.Effect of heat treatment on microstructures and mechanical properties of sand-cast Mg-10Gd-3Y-0.5Zr magnesium alloy[J].Transactions of Nonferrous Metals Society of China,2014,24(3):611-618.
- [15] 张帅,李全安,朱宏喜,等.Ca对Mg-11Gd-3Y-0.5Zr合金显微组织和耐蚀性的影响[J].材料热处理学报,2019,40(8):17-23.ZHANG Shuai,LI Quan-an,ZHU Hong-xi,et al.Effect of Ca on microstructures and corrosion resistance of Mg-11Gd-3Y-0.5Zr alloy[J].Transactions of Materials and Heat Treatment,2019,40(8):17-23.
- [16] Nie J F,Gao X,Zhu S M,et al.Enhanced age hardening response and creep resistance of Mg-Gd alloys containing Zn[J].Scripta Materialia,2005,53(9):1049-1053.
- [17] 朱利敏,李全安,周耀,等.Sm对Mg-10Gd-0.5Zr合金组织及力学性能的影响[J].稀有金属材料与工程,2019,48(1):171-176.ZHU Li-min,LI Quan-an,ZHOU Yao,et al.Effect of Sm on microstructures and mechanical properties of Mg-10Gd-0.5Zr alloy[J].Rare Metal Materials and Engineering,2019,48(1):171-176.
- [18] 彭卓凯,张新明,陈健美,等.Mn,Zr对Mg-Gd-Y合金组织与力学性能的影响[J].中国有色金属学报,2005(6):917-922.PENG Zhuo-kai,ZHANG Xin-ming,CHEN Jian-mei,et al.Effects of Mn,Zr on microstructure and properties of Mg-Gd-Y alloys[J].The Chinese Journal of Nonferrous Metals,2005(6):917-922.
- [19] 李元东,郝远,陈体军等.等温热处理工艺对AZ91D镁合金半固态组织演变和成形性的影响[J].中国有色金属学报,2002(6):1143-1148.LI Yuan-dong,HAO Yuan,CHEN Ti-jun,et al.Effects of isothermal heat-treatment on microstructure evolution and formability of AZ91D magnesium alloy in semi-solid state[J].The Chinese Journal of Nonferrous Metals,2002(6):1143-1148.
- [20] 唐昌平,李国栋,刘文辉,等.析出相对Mg-Gd-Y-Nd-Zr合金室温压缩行为的影响[J].材料导报,2017,31(16):103-106.TANG Chang-ping,LI Guo-dong,LIU Wen-hui,et al.Effects of precipitates on compression behavior of Mg-Gd-Y-Nd-Zr alloy at ambient temperature[J].Materials Review,2017,31(16):103-106.
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