含Mg夹杂物对晶内针状铁素体形核的影响Influence of magnesium inclusions on nucleation of intragranular acicular ferrite
答国宇,黄峰,王勇,岳江波,张华,李利巍,刘静
摘要(Abstract):
采用高温激光共聚焦扫描显微镜(CLSM)原位观察了Mg-Ca复合处理X70 MS管线钢中夹杂物诱导晶内针状铁素体(IAF)的形核行为,探讨了含Mg夹杂物尺寸和化学成分对IAF形核的影响规律及机理。结果表明:含Mg夹杂物诱发IAF形核的最佳尺寸为2~4μm,与化学成分无关;但其诱导和促进IAF形核能力受结构和成分影响显著,即单一Mg-Al-O夹杂物诱导IAF明显优于以Mg-Al-O为核心的复合夹杂物,且主要以应力应变机制为主。
关键词(KeyWords): X70 MS管线钢;含Mg夹杂物;晶内针状铁素体(IAF);应力应变机制
基金项目(Foundation): 国家自然科学基金(U21A20113,52231003)
作者(Author): 答国宇,黄峰,王勇,岳江波,张华,李利巍,刘静
DOI: 10.13289/j.issn.1009-6264.2024-0359
参考文献(References):
- [1]李东,尹立孟,王学军,等.管线钢焊缝中晶内针状铁素体的研究进展[J].焊管,2016,39(2):10-13.LI Dong,YIN Li-meng,WANG Xue-jun,et al. Research progress of intragranular acicular ferrite in pipeline steel weld[J]. Welded Pipe and Tube,2016,39(2):10-13,18.
- [2]舒玮,王学敏,李书瑞,等.焊接热影响区针状铁素体的形核长大及其对组织的细化作用[J].金属学报,2011,47(4):435-441.SHU Wei,WANG Xue-min, LI Shu-rui, et al. Nucleation and growth of intragranular acicular ferrite and its effect on grain refinement of the heat-affected-zone[J]. Acta Metallurgica Sinica,2011,47(4):435-441.
- [3]肖爱达,郑庆,梁亮,等. Ti处理工艺对钢中夹杂物的影响[J].钢铁钒钛,2022,43(1):158-164.XIAO Ai-da,ZHENG Qing,LIANG Liang,et al. Effect of Ti treatment process on inclusions in steel[J]. Iron Steel Vanadium Titanium,2022,43(1):158-164.
- [4]余圣甫,雷毅,黄安国,等.氧化物冶金技术及其应用[J].材料导报,2004,18(8):50-52.YU Sheng-fu,LEI Yi,HUANG An-guo,et al. Oxides metallurgy technology and its application[J]. Materials Review,2004,18(8):50-52.
- [5]舒玮,王学敏,李书瑞,等.含Ti复合第二相粒子对微合金钢焊接热影响区组织和性能的影响[J].金属学报,2010,46(8):997-1003.SHU Wei,WANG Xue-min,LI Shu-rui,et al. Influence of second-phase particles containing Ti on microstructure and properties of weld-heat-affected-zone of a microalloy steel[J]. Acta Metallurgica Sinica,2010,46(8):997-1003.
- [6]王丙兴,朱伏先,王超,等.氧化物冶金在大线能量焊接用钢中的应用[J].钢铁,2019,54(9):12-21.WANG Bing-xing,ZHU Fu-xian,WANG Chao,et al. Application of oxide metallurgy in high heat input welding steels[J]. Iron&Steel,2019,54(9):12-21.
- [7]彭明军,史方杰,安鹏.氧化物冶金技术的应用及其前景[J].化工设计通讯,2016,42(10):36-36.PENG Ming-jun,SHI Fang-jie,AN Peng. Application field and prospect of oxide metallurgy technology[J]. Chemical Engineering Design Communications,2016,42(10):36.
- [8] Kojima A,Kiyose A,Uemori R,et al. Super high HAZ toughness technology with fine microstructure imparted by fine particles[J].Nippon Steel Technical Report,2004,2004(90):2-6.
- [9] Yang J,Zhu K,Wang R Z,et al. Excellent heat affected zone toughness technology improved by use of strong deoxidizers[C]//The2nd International symposium on clean steel.:Journal of Iron and Steel Research,International,Shenyang,2011:141-147.
- [10]杨健,蔡文菁.镁处理对钢中夹杂物以及HAZ组织和性能的影响[J].钢铁,2021,56(7):13-24.YANG Jian,CAI Wen-jing. Effect of magnesium treatment on inclusions and HAZ microstructure and properties of steel plate[J].Iron&Steel,2021,56(7):13-24.
- [11] Madariaga I,Gutierrez I. Role of the particle-matrix interface on the nucleation of acicular ferrite in a medium carbon microalloyed steel[J]. Acta Materialia,1999,47(3):951-960.
- [12] Sarma D S,Karasev A V,Jonsson P G. On the role of non-metallic inclusions in the nucleation of acicular ferrite in steels[J]. ISIJ International,2009,49(7):1063-1074.
- [13] Kong H,Zhou Y H,Lin H,et al. The mechanism of intragranular acicular ferrite nucleation induced by Mg-Al-O inclusions[J].Advances in Materials Science and Engineering,2015,2015:358678.
- [14] Lee T K,Kim H J,Kang B Y,et al. Effect of inclusion size on the nucleation of acicular ferrite in welds[J]. ISIJ International,2000,40(12):1260-1268.
- [15] Wen B,Song B, Pan N, et al. Effect of Si Mg alloy on inclusions and microstructures of 16Mn steel[J]. Ironmaking and Steelmaking,2011,38(8):577-583.
- [16] Kim H S,Chang C H,Lee H G. Evolution of inclusions and resultant microstructural change with Mg addition in Mn/Si/Ti deoxidized steels[J]. Scripta Materialia,2005,53(11):1253-1258.
- [17] Chai F,Yang C F,Su H,et al. Effect of magnesium on inclusion formation in Ti-killed steels and microstructural evolution in welding induced coarse-grained heat affected zone[J]. Journal of Iron and Steel Research(International),2009,16(1):69-74.
- [18] Huang W Q, Li A J, Li Q P, et al. Influence of Ti O2Transactions of the Indian Institute of Metals,2024,77(6):1577-1587.
- [19] Wu X Y,Liu Z X,Wu S J,et al. Investigation of inclusion characteristics and intragranular acicular ferrite nucleation in Mgcontaining low-carbon steel[J]. Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science,2021,52(2):1012-1022.
- [20] Lin C K,Pan Y C,Su Y H F,et al. Effects of Mg-Al-O-Mn-S inclusion on the nucleation of acicular ferrite in magnesiumcontaining low-carbon steel[J]. Materials Characterization,2018,141:318-327.
- [21] Wang X,Wang C,Kang J,et al. An in-situ microscopy study on nucleation and growth of acicular ferrite in Ti-Ca-Zr deoxidized low-carbon steel[J]. Materials Characterization,2020,165:110381.
- [22]肖虎.镁处理夹杂物对管线钢氢捕获及早期腐蚀的影响[D].武汉:武汉科技大学,2024.XIAO Hu. Effect of Mg-treatment inclusion on hydrogen trapping and early corrosion of pipeline steel[D]. Wuhan:Wuhan University of Science and Technology,2024.
- [23]祝凯. Mg处理冶炼工艺对船板钢母材和焊接热影响区影响的研究[D].上海:复旦大学,2011.ZHU Kai. The influences of Mg treatment on the base metal and welding heat affected zone in ship plate steel[D]. Shanghai:Fudan University,2011.
- [24] Yang J,Xu L Y,Zhu K,et al. Improvement of HAZ toughness of steel plate for high heat input welding by inclusion control with Mg deoxidation[J]. Steel Research International,2015,86(6):619-625.
- [25]孙铭延,孙立根,刘云松,等.大线能量焊接船板钢Mg处理效果分析[J].河北冶金,2022(9):15-19.SUN Ming-yan,SUN Li-gen,LIU Yun-song,et al. Analysis of Mg treatment effect of large wire energy welded ship plate steel[J].Hebei Metallurgy,2022(9):15-19.
- [26]张鑫,王博,马振云,等. Mg处理EH36级船板钢的大线能量焊接性分析[J].冶金信息导刊,2021,58(4):21-26.ZHANG Xin,WANG Bo,MA Zhen-yun,et al. Analysis of large heat input welding performance of EH36 shipbuilding steel with Mg treatment[J]. Metallurgical Information Review,2021,58(4):21-26.
- [27] Xu L Y,Yang J,Wang R Z,et al. Effect of Mg addition on formation of intragranular acicular ferrite in heat-affected zone of steel plate after high-heat-input welding[J]. Journal of Iron and Steel Research(International),2018,25(4):433-441.
- [28] Xiao H,Huang F,Qiu Y,et al. Mechano-electrochemical interaction of high-strength pipeline steels with Al-Ti deoxidization and Mg-Ca compound treatment[J]. Corrosion Science,2023,224:111534.
- [29] Xiao H,Huang F,Peng Z X,et al. Sequential kinetic analysis of the influences of non-metallic inclusions on hydrogen diffusion and trapping in high-strength pipeline steel with Al-Ti deoxidisation and Mg treatment[J]. Corrosion Science,2022,195:110006.
- [30]刘学杰,屈健,高丽,等.基于第一性原理研究铌钢中奥氏体与铁素体的力学性能[J].金属热处理,2014,39(7):7-11.LIU Xue-jie,QU Jian,GAO Li,et al. Study on mechanical properties of austenite and ferrite in niobium steel based on firstprinciple method[J]. Heat Treatment of Metals,2014,39(7):7-11.
- [31]朱若林,张利涛,王俭秋,等.核级316LN不锈钢弯管在高温高压水中的应力腐蚀裂纹扩展行为[J].中国腐蚀与防护学报,2018,38(1):54-61.ZHU Ruo-lin,ZHANG Li-tao,WANG Jian-qiu,et al. Stress corrosion crack propagation behavior of elbow pipe of nuclear grade316LN stainless steel in high temperature high pressure water[J]. Journal of Chinese Society for Corrosion and Protection,2018,38(1):54-61.
- [32] Lv Y,Ding Y,Cui H,et al. Investigation of microscopic residual stress and its effects on stress corrosion behavior of Ni Al bronze alloy using in situ neutron diffraction/EBSD/tensile corrosion experiment[J]. Materials Characterization,2020,164:110351.
- [33]潘涛,杨志刚,白秉哲,等.钢中夹杂物与奥氏体基体热膨胀系数差异导致的热应力和应变能研究[J].金属学报,2003,39(10):1037-1042.PAN Tao,YANG Zhi-gang,BAI Bing-zhe,et al. Study of thermal stress and strain energy in γ-Fe matrix around inclusion caused by thermal coefficient difference[J]. Acta Metallurgica Sinica,2003,39(10):1037-1042.
- [34]牛宏波.镀锌基板孔洞原因分析[J].甘肃冶金,2016,38(5):19-20.NIU Hong-bo. Analysis on cavity causes of galvanizing sheet[J]. Gansu Metallurgy,2016,38(5):19-20.
- [35]葛军亮,程子建,程树森,等. CSP热轧过程中夹杂物周围孔洞的演变[J].钢铁研究学报,2015,27(2):24-30.GE Jun-liang,CHENG Zi-jian,CHENG Shu-sen,et al. Evolution of voids around inclusions during CSP hot rolling process[J].Journal of Iron and Steel Research,2015,27(2):24-30.
- [36]周正平. N80Q油管皮下孔洞和表面裂纹产生原因分析[J].钢管,2019,48(4):37-40.ZHOU Zheng-ping. Analysis of causes for subsurface hole and surface crack in N80Q tubing[J]. Steel Pipe,2019,48(4):37-40.
- [37]晁代义,徐仁根,孙学垠,等.奥氏体耐热不锈钢310S动态拉伸变形行为研究[J].烟台大学学报(自然科学与工程版),2013,26(1):58-61.CHAO Dai-yi,XU Ren-gen,SUN Xue-yin,et al. Deformation behavior of 310S austenitic stainless steel during dynamic tensile[J].Journal of Yantai University(Natural Science and Engineering Edition),2013,26(1):58-61.
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