共沉淀强化ODS铁素体合金的热变形行为Hot deformation behavior of co-precipitation ODS ferritic alloy
杜沛南,刘烨,肖文卓,杨思敏,陈旭,贺双,章林
摘要(Abstract):
氧化物弥散强化(ODS)铁素体合金因其优异的高温强度和抗蠕变性能,被广泛应用于核能及高温结构应用中。在高温热变形过程中,ODS铁素体合金中的纳米氧化物颗粒具有优异的高温稳定性,使得其在高温下仍能保持较高的强度。然而,较低的塑性使得ODS合金容易在热变形过程中形成裂纹等缺陷。因此,研究其热变形行为对开发高性能铁素体基合金具有重要的科学意义。通过热模拟实验,研究了机械合金化制备的ODS铁素体合金在不同变形温度(500、600、650和700℃)和应变速率(0.001、0.01和0.1 s~(-1))下的热变形特性。基于不同变形条件下获得的峰值应力,计算了合金的热变形激活能,构建了其本构方程,并使用动态材料模型(DMM)绘制了其在不同应变(0.2、0.3、0.4、0.5)及峰值应力下的热加工图。结果表明:合金适宜的热变形区间主要集中在高于580℃的低应变速率区域,在此区域选择合适的变形温度和应变速率能使基体发生动态再结晶并避免晶粒过分长大,可有效避免热加工过程中缺陷的产生,从而获得性能更优的热变形产品。
关键词(KeyWords): 铁素体基合金;共沉淀强化;氧化物弥散强化;热变形行为
基金项目(Foundation): 国家自然科学基金(52103363,52074032,52474387,52374366,52101152);; 中核集团青年英才项目(NPIC-Z3022024003);; 江西省“双千项目”(203075000041)
作者(Author): 杜沛南,刘烨,肖文卓,杨思敏,陈旭,贺双,章林
DOI: 10.13289/j.issn.1009-6264.2024-0598
参考文献(References):
- [1] Chen X,Peng S,Liu Y,et al.Ductility deterioration induced by L21 phase in ferritic alloy through Ti addition[J].Journal of Materials Research and Technology,2023,25:3273-3284.
- [2] Jiang S,Wang H,Wu Y,et al.Ultrastrong steel via minimal lattice misfit and high-density nanoprecipitation[J].Nature,2017,544(7651):460-464.
- [3] Teng Z K,Zhang F,Miller M K,et al.New NiAl-strengthened ferritic steels with balanced creep resistance and ductility designed by coupling thermodynamic calculations with focused experiments[J].Intermetallics,2012,29:110-115.
- [4] Liu Y,Pang X,He S,et al.In-situ formation of AlN nanoparticles in NiAl-strengthened ferritic alloy with enhanced high-temperature mechanical properties via SLM fabrication[J].Materials Science and Engineering A,2024,899:146460.
- [5] Ukai S,Harada M,Okada H,et al.Alloying design of oxide dispersion strengthened ferritic steel for long life FBRs core materials[J].Journal of Nuclear Materials,1993,204:65-73.
- [6] Zhang L,Liu Y,Wang S,et al.ODS alloy with ferritic-austenitic duplex matrix and NiAl precipitation prepared by master alloy approach[J].Journal of Alloys and Compounds,2019,811:152066.
- [7] Edahiro T,Kouzai K,Yasuda H Y.Mechanical properties and hardening mechanism of Fe-Al-Ni single crystals containing NiAl precipitates[J].Acta Materialia,2013,61(5):1716-1725.
- [8] Kim S H,Kim H,Kim N J.Brittle intermetallic compound makes ultrastrong low-density steel with large ductility[J].Nature,2015,518(7537):77-79.
- [9] Huang D,Yan J,Zuo X.Co-precipitation kinetics,microstructural evolution and interfacial segregation in multicomponent nano-precipitated steels[J].Materials Characterization,2019,155:109786.
- [10] Zhang L,Wen Y,Liu Y,et al.Cr-promoted formation of B2+L21 composite nanoprecipitates and enhanced mechanical properties in ferritic alloy[J].Acta Materialia,2023,243:118506.
- [11] Jiao Z B,Luan J H,Miller M K,et al.Precipitation mechanism and mechanical properties of an ultra-high strength steel hardened by nanoscale NiAl and Cu particles[J].Acta Materialia,2015,97:58-67.
- [12] Yan J,Xu H,Zuo X,et al.Strategies for strengthening-ductility and hierarchical co-precipitation in multicomponent nano-precipitated steels by Cu partitioning[J].Materials Science and Engineering A,2019,739:225-234.
- [13] Schnitzer R,Schober M,Zinner S,et al.Effect of Cu on the evolution of precipitation in an Fe-Cr-Ni-Al-Ti maraging steel[J].Acta Materialia,2010,58(10):3733-3741.
- [14] Stallybrass C,Sauthoff G.Ferritic Fe-Al-Ni-Cr alloys with coherent precipitates for high-temperature applications[J].Materials Science and Engineering A,2004,387-389:985-990.
- [15] Kapoor M,Isheim D,Ghosh G,et al.Aging characteristics and mechanical properties of 1600MPa body-centered cubic Cu and B2-NiAl precipitation-strengthened ferritic steel[J].Acta Materialia,2014,73:56-74.
- [16] Calderon H A,Fine M E,Weertman J R.Coarsening and morphology of β′ particles in Fe-Ni-Al-Mo ferritic alloys[J].Metallurgical Transactions A,1988,19:1135-1146.
- [17] Lee T H,Kim Y O,Kim S J.Crystallographic model for bcc-to-9R martensitic transformation of Cu precipitates in ferritic steel[J].Philosophical Magazine,2007,87(2):209-224.
- [18] Wen Y R,Hirata A,Zhang Z W,et al.Microstructure characterization of Cu-rich nanoprecipitates in a Fe-2.5 Cu-1.5 Mn-4.0 Ni-1.0 Al multicomponent ferritic alloy[J].Acta Materialia,2013,61(6):2133-2147.
- [19] Zaguliaev D.Microstructure and micro-hardness behavior of Ti-Y2O3-Al-Si composite coatings prepared in electron-plasma alloying[J].Materials Characterization,2019,158:109934.
- [20] Zhou X,Li G,Shen X,et al.Tensile strength improvement of martensitic ODS steels with Zr and Hf additions[J].Materials Science and Engineering A,2022,829:142071.
- [21] Wang S,Liu Y,Zhang L,et al.Strengthening by hierarchical-structured nanoparticles in powder metallurgy manufactured ODS ferritic alloy[J].Journal of Alloys and Compounds,2020,842:155846.
- [22] Prasad Y V R K,Rao K P.Processing maps and rate controlling mechanisms of hot deformation of electrolytic tough pitch copper in the temperature range 300-950 ℃[J].Materials Science and Engineering A,2005,391(1/2):141-150.
- [23] Che B,Lu L,Kang W,et al.Hot deformation behavior and processing map of a new type Mg-6Zn-1Gd-1Er alloy[J].Journal of Alloys and Compounds,2021,862:158700.
- [24] Momeni A,Dehghani K.Hot working behavior of 2205 austenite-ferrite duplex stainless steel characterized by constitutive equations and processing maps[J].Materials Science and Engineering A,2011,528(3):1448-1454.
- [25] Zhang G,Zhou Z,Sun H,et al.Hot deformation behavior and processing map of a 9Cr ferritic/martensitic ODS steel[J].Journal of Nuclear Materials,2014,455(1/3):139-144.
- [26] Han J,Sun J P,Han Y,et al.Hot workability of the as-cast 21Cr economical duplex stainless steel through processing map and microstructural studies using different instability criteria[J].Acta Metallurgica Sinica (English Letters),2017,30(11):1080-1088.
- [27] Han Y,Qiao G,Sun Y,et al.Modeling the constitutive relationship of Cr20Ni25Mo4Cu superaustenitic stainless steel during elevated temperature[J].Materials Science and Engineering A,2012,539:61-67.
- [28] 郭丽娜,黄英,刘立明,等.12Cr-ODS铁素体钢的热塑性变形行为和热加工图[J].热加工工艺,2019,48(9):135-139.GUO Li-na,HUANG Ying,LIU Li-ming,et al.Thermoplastic deformation behavior and hot processing map of 12Cr-ODS ferritic steel[J].Hot Working Technology,2019,48(9):135-139.
- [29] 权国政,陈涛,石或,等.退火20MnNiMo合金高温流变行为的一种本构描述[J].材料热处理学报,2012,33(7):147-152.QUAN Guo-zheng,CHEN Tao,SHI Huo et al.A constitutive description for hot flow behavior of as-annealed 20MnNiMo alloy[J].Transactions of Materials and Heat Treatment,2012,33(7):147-152.
- [30] 户赫龙,周张健,王曼,等.14Cr-ODS铁素体钢的热变形行为及热加工图[J].粉末冶金材料科学与工程,2012,17(5):541-547.HU He-long,ZHOU Zhang-jian,WANG Man,et al.Hot deformation behavior and processing map of a 14Cr-ODS ferritic steel[J].Materials Science and Engineering of Powder Metallurgy,2012,17(5):541-547.
- [31] Liu W B,Liu Z,Luo W,et al.Understanding roles of Zr and W on hot/warm deformation behavior of FeCrAl alloy:Grain boundary features and dynamic precipitation of Laves phase[J].Intermetallics,2022,140:107387.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||