镀铜石墨对铜基制动闸片组织及性能的影响Effect of copper-coated graphite on microstructure and properties of copper matrix brake pad
周亚军,张鑫,张永振,张玉娟,申凯
摘要(Abstract):
采用化学镀的方式在鳞片状石墨表面镀铜来改善铜基制动闸片中石墨和铜基体的界面结合,制定了化学镀铜配方及工艺,并研究了4种不同镀液温度对镀铜效果的影响。对镀铜后的石墨进行显微组织观察和能谱分析可知:随镀液温度的升高,镀铜效果先升后降,最好的施镀温度为50℃。用热压烧结法制备出镀铜石墨/铜基制动闸片(FM1)与非镀铜石墨/铜基制动闸片(FM0),并对其进行力学性能、物理性能测试以及制动测试,并采用扫描电镜和能谱仪对制动闸片在制动前后的表面形貌进行观察及分析。结果表明:与FM0相比,FM1中石墨分布更细小均匀,因此样品的致密度较高,硬度、抗压强度和热导率也随之增大。在不同制动初速度下,随制动初速度的提高,两种闸片的摩擦系数均出现先略微增高、后平稳,然后显著降低的趋势,但FM1的摩擦系数总体比FM0的摩擦系数更高且稳定,线磨损率也相对较小。在350 km/h高速制动条件下,由于摩擦热引起的材料表面软化,两种制动闸片的摩擦系数差别不大,都呈现显著下降趋势。
关键词(KeyWords): 镀铜石墨;化学镀;铜基制动闸片;施镀温度;摩擦系数
基金项目(Foundation): 国家自然科学基金(92266205 E0505);; 河南省教育厅骨干教师项目(2020GGJS271);河南省教育厅科技攻关项目(21A460020);; 郑州市科技攻关项目(ZZSZX202105)
作者(Author): 周亚军,张鑫,张永振,张玉娟,申凯
DOI: 10.13289/j.issn.1009-6264.2024-0031
参考文献(References):
- [1] 殷缶,梅深.2022年交通运输行业发展统计公报[J].水道港口,2023,44(6):1002-1006.
- [2] Zhang P,Zhang L,Wei D,et al.A high-performance copper-based brake pad for high-speed railway trains and its surface substance evolution and wear mechanism at high temperature[J].Wear,2020,444-445:203182.
- [3] Beyerlein I J,Demkowicz M J,Misra A,et al.Defect-interface interactions[J].Progress in Materials Science,2015,74:125-210.
- [4] Gong T,Yao P,Xiong X,et al.Microstructure and tribological behavior of interfaces in Cu-SiO2 and Cu-Cr metal matrix composites[J].Journal of Alloys and Compounds,2019,786:975-985.
- [5] Zhan Y,Zhang G.The role of graphite particles in the high-temperature wear of copper hybrid composites against steel[J].Materials & Design,2006,27(1):79-84.
- [6] Chikova O A,Vityunin M A,Chentsov V P,et al.Separation of Fe-Cu melts upon graphite wetting[J].Colloid Journal,2010,72(2):255-261.
- [7] Yan Y F,Kou S Q,Yang H Y,et al.Ceramic particles reinforced copper matrix composites manufactured by advanced powder metallurgy:preparation,performance,and mechanisms[J].International Journal of Extreme Manufacturing,2023,5(3):1-35.
- [8] Zhang J,He L,Zhou Y.Highly conductive and strengthened copper matrix composite reinforced by Zr2Al3C4 particulates[J].Scripta Materialia,2009,60(11):976-979.
- [9] 陈贞睿,刘超,谢炎崇,等.高导热金属基复合材料的制备与研究进展[J].粉末冶金技术,2022,40(1):40-52.CHEN Zhen-rui,LIU Chao,XIE Yan-chong,et al.Preparation and research process of high thermal conductivity metal matrix composites[J].Powder Metallurgy Technology,2022,40(1):40-52.
- [10] 朱英彬.石墨鳞片/Cu复合材料热性能及力学性能研究[D].昆明:昆明理工大学,2018.
- [11] 刘骞.非连续石墨/铜复合材料的制备与热性能研究[D].北京:北京科技大学,2016.LIU Qian.Research of preparation and thermal properties of discontinuous graphite/copper composites[D].Beijing:University of Science and Technology Beijing,2016.
- [12] 徐俊.金刚石盐浴镀钛对金刚石/铝复合材料组织及性能的影响[D].南京:东南大学,2019.XU Jun.Effect of salt bath plating Ti on diamond particles on the microstructure and properties of diamond/Al composites[D].Nanjing:Southeast University,2019.
- [13] 张忍,王旭磊,何新波.石墨鳞片表面镀铬对石墨鳞片/铜复合材料组织和性能的影响[J].粉末冶金技术,2019,37(4):248-254.ZHANG Ren,WANG Xu-lei,HE Xin-bo.Effect of Cr coating on microstructure and properties of graphite flake/Cu composites[J].Powder Metallurgy Technology,2019,37(4):248-54.
- [14] 王俊伟.镀层石墨/铝复合材料的热传导机制与力学性能研究[D].新乡:河南师范大学,2017.WANG Jun-wei.Thermal transfer mechanism and mechanical property of graphite/Al composites with graphite surface coated[D].Xinxiang:Henan Normal University,2017.
- [15] Lo H H,Wei T C.Controlling magnetism of diamond powder metallization using electroless cobalt/nickel plating[C]//2020 15th International Microsystems,Packaging,Assembly and Circuits Technology Conference (IMPACT).IEEE,Taipei,2020:177-180.
- [16] 范洪远.物理气相沉积(PVD)制备石墨类薄膜[D].大连:大连交通大学,2015.FAN Hong-yuan.Physical vapor deposition graphite type of film[D].Dalian:Dalian Jiaotong University,2015.
- [17] 段涛,金利华,梁明,等.石墨烯化学镀铜及增强铜基复合块材的制备[J].材料导报,2022,36(S2):308-311.DUAN Tao,JIN Li-hua,LIANG Ming,et al.Electroless copper plating on graphene and preparation of reinforced copper based composite block[J].Materials Reports,2022,36(S2):308-311.
- [18] Jiang R,Zhou X,Liu Z.Electroless Ni-plated graphene for tensile strength enhancement of copper[J].Materials Science and Engineering A,2017,679:323-328.
- [19] Sahraei A A,Saeed H N,Fathi A,et al.Formation of homogenous copper film on MWCNTs by an efficient electroless deposition process[J].Science and Engineering of Composite Materials,2017,24(3):345-352.
- [20] Peng Y T,Chen Q F.Ultrasonic-assisted fabrication of highly dispersed copper/multi-walled carbon nanotube nanowires[J].Colloids and Surfaces A-Physicochemical and Engineering Aspects,2009,342(1/3):132-135.
- [21] 张鑫,刘军锋,单硕,等.石墨排列取向对铜基粉末冶金材料制动摩擦学行为的影响[J].材料热处理学报,2023,44(10):21-32.ZHANG Xin,LIU Jun-feng,SHAN Shuo,et al.Effect of graphite orientation on braking tribological behavior of copper-based powder metallurgical materials[J].Transactions of Materials and Heat Treatment,2023,44(10):21-32.
- [22] 舒鑫,刘洋赈,曾大海,等.铜镀层对石墨-铜复合材料摩擦磨损性能的影响[J].材料热处理学报,2021,42(12):142-150.SHU Xin,LIU Yang-zhen,ZENG Da-hai,et al.Effect of copper plating on friction and wear properties of graphite-copper composites[J].Transactions of Materials and Heat Treatment,2021,42(12):142-150.
- [23] 石佩洛,王月友,郭鸿俊,等.炭纤维/鳞片石墨/氰酸酯复合材料的导热和力学性能[J].新型炭材料,2019,34(1):110-114.SHI Pei-luo,WANG Yue-you,GUO Hong-jun,et al.The thermal and mechanical properties of carbon fiber/flake graphite/cyanate ester composites[J].New Carbon Materials,2019,34(1):110-114.
- [24] Sohn J R,Park W C.Characterization of nickel sulfate supported on γ-Al2O3 and its relationship to acidic properties[J].Korean Journal of Chemical Engineering,2002,19:580-586.
- [25] 卢建红.基于二元络合剂的化学镀铜与表面自组装技术[D].北京:北京科技大学,2019.LU Jian-hong.Research on electroless copper based on dual complexant and self-assembly technology[D].Beijing:University of Science and Technology Beijing,2019.
- [26] Wei L,Wang Y,Xie C,et al.Preparation and photocatalytic activity of Ti(I/S) catalyst etched by different acids and alkalis[J].Optical Materials,2023,146:114587.
- [27] Hanna F,Hamid Z A,Aal A A.Controlling factors affecting the stability and rate of electroless copper plating[J].Materials Letters,2004,58(1/2):104-109.
- [28] 中国机械工业联合会.干式烧结金属摩擦材料摩擦性能试验方法:JB/T 7269-2007[S].北京:中国标准出版社,2008.
- [29] Suleiman B M.Effective thermal conduction in composite materials[J].Applied Physics A,2009,99:223-228.
- [30] Gnecco E,Meyer E.Elements of Friction Theory and Nanotribology[M].Cambridge:Cambridge University Press,2015.
- [31] Peng T,Yan Q,Zhang X.Stability of metal matrix composite pads during high-speed braking[J].Tribology Letters,2018,66:1-13.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||