熔盐环境下热障涂层的等温热腐蚀行为研究Isothermal corrosion behavior of thermal barrier coatings in molten salt environments
白致铭,郭磊,梁天权,郭洪波,宫声凯
摘要(Abstract):
采用电子束物理气相沉积(EB-PVD)在镍基高温合金表面制备了YSZ/NiCoCrAlY双层结构热障涂层,研究了其在熔盐环境下的等温热腐蚀行为。结果表明,涂层在加热过程中发生相变引起体积收缩,导致涂层内部产生微裂纹。熔盐填充涂层内微裂纹和柱状晶间隙,降低了涂层的应变容限,引起涂层内应力升高。同时,熔盐促使热生长氧化层(TGO)碱性溶解,产生疏松多孔的氧化物层,导致TGO层加速增厚。在热应力作用下,疏松层氧化物破碎,最终导致涂层剥落。
关键词(KeyWords): 热障涂层;电子束物理气相沉积;熔盐;等温热腐蚀;热生长氧化层(TGO)
基金项目(Foundation): 国家重点基础研究发展计划资助(2010CB631200)
作者(Author): 白致铭,郭磊,梁天权,郭洪波,宫声凯
DOI: 10.13289/j.issn.1009-6264.2011.11.024
参考文献(References):
- [1]Padture N P,Gell M,Jordan E H.Thermal barrier coatings for gas-turbine engine applications[J].Science,2002,296:280-284.
- [2]Kool G A.Current and future materials in advanced gas turbine engines[J].Journal of Thermal Spray Technology,1996,5(1):31-32.
- [3]Guo H B,Kuroda S,Murakami H.Microstructures and properties of plasma-sprayed segmented thermal barrier coatings[J].Journal of the AmericanCeramic Society,2006,89(4):1432-1439.
- [4]Peter M,Leyens C,Schulz U,et al.EB-PVD thermal barrier coatings for aeroengines and gas turbines[J].Advanced Engineering Materials,2001,3(4):193-204.
- [5]张显程,徐滨士,王海斗.ZrO2/NiCoCrAlY功能梯度涂层残余应力分析[J].材料热处理学报,2005,26(2):86-92.ZHANG Xian-cheng,XU Bin-shi,WANG Hai-dou.Analysis on the residual stresses in functionally gradient ZrO2/NiCoCrAlY coatings[J].Transactions of Materials and Heat Treatment,2005,26(2):86-92.
- [6]徐惠彬,宫声凯,刘福顺.航空发动机热障涂层材料体系研究[J].航空学报,2000,21(1):7-12.XU Hui-bin,GONG Sheng-kai,LIU Fu-shun.Recent development in materials design of thermal barrier coatings for gas turbine[J].Acta Aeronauticaet Astronautica Sinica,2001,21(1):7-12.
- [7]Stringer J.High-temperature corrosion of superalloys[J].Materials Science and Technology,1987,3(7):482-493.
- [8]Goward G W.Progress in coatings for gas turbine airfoils[J].Surface and Coatings Technology,1998,108-109:73-79.
- [9]沈文雁,霍晓.EB-PVD热障涂层的失效行为研究[J].材料工程,1998(1):35-37.SHEN Wen-yan,HUO Xiao.The failure behavior of EB-PVD thermal barrier coatings[J].Journal of Materials Engineering,1998(1):35-37.
- [10]Meier S M,Nissley D M,Sheffler K D.Thermal barrier coating life prediction model development[J].Journal of Engineering for Gas Turbines andPower,1992,114(2):258-263.
- [11]Jones R L.Development of hot-corrosion-resistant zirconia thermal barrier coatings[J].Materials at High Temperatures,1991,9(4):228-236.
- [12]Godlewski K,Godlewska E.Effect of chromium on the protective properties of aluminide coatings[J].Oxidation of Metals,1986,26(1-2):125-138.
- [13]刘春波,林锋,蒋显亮.热障涂层的研究现状与发展趋势[J].中国有色金属学报,2007,17(1):1-13.LIU Chun-bo,LIN Feng,JIANG Xian-liang.Current state and future development of thermal barrier coating[J].The Chinese Journal of NonferrousMetals,2007,17(1):1-13.
- [14]Toscano J,Vaβen R,Gil A,et al.Parameters affecting TGO growth and adherence on MCrAlY-bond coats for TBC's[J].Surface and CoatingsTechnology,2006,201(7):3906-3910.
- [15]Brandl W,Grabke H J,Toma D,et al.The oxidation behavior of sprayed NiCoCrAlY coatings[J].Surface and Coatings Technology,1996,86-87:41-47.
- [16]Strangman T,Raybould D,Jameel A,et al.Damage mechanisms,life prediction,and development of EB-PVD thermal barrier coatings for turbineairfoils[J].Surface and Coatings Technology,2007,202(4-7):658-664.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||