原位自生TiC-TiB2增强Fe基复合涂层的凝固特性及形成机理Solidification characteristic and formation mechanism of in-situ synthesized TiC-TiB2 reinforced Fe-matrix composite coating
王振廷,周晓辉,张显友,郑维
摘要(Abstract):
以Ti、B4C和Fe粉为原料,利用氩弧熔敷技术在Q235钢基体表面制备出原位自生TiC-TiB2增强Fe基复合涂层。利用扫描电镜(SEM)、X射线衍射仪(XRD)对涂层的显微组织进行了分析。并分析了TiC和TiB2颗粒的形成机理和氩弧熔池的凝固特性。实验结果表明:熔敷层组织为TiC和TiB2弥散分布在α-Fe中,熔敷层与基体呈冶金结合,无裂纹、气孔等缺陷;涂层中TiC和TiB2的体积分数约为68%。形成机理主要是以固态扩散机制为主,TiC以小颗粒状和花瓣状先析出,后析出的TiB2多以六边形、短棒状存在,TiB2的组织比较粗大,TiC颗粒比较细小,TiB2的含量大于TiC含量。
关键词(KeyWords): 氩弧熔敷;TiC-TiB2;形成机理;凝固特性
基金项目(Foundation): 国家自然科学基金资助项目(50075085);; 黑龙江省教育厅科学技术研究项目(11511353)
作者(Author): 王振廷,周晓辉,张显友,郑维
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