Ti6Al4V合金表面等电位空心阴极辉光放电W-Mo共渗层耐冲刷腐蚀性能Erosion corrsion of the W-Mo modified layer on Ti6Al4V alloy surface by the equal potential hollow-cathode glow discharge
赵云,张玉林,陈飞
摘要(Abstract):
利用针状等电位空心阴极放电技术,在低于钛合金Ti6Al4V相变温度下,对其表面进行W-Mo共渗。利用扫描电子显微镜、X射线衍射仪、显微硬度计、球-盘摩擦磨损试验仪等分析了改性层的表面及截面形貌、相组成、显微硬度;及在室温干摩擦条件下的耐磨性能;利用冲刷腐蚀试验机研究了W-Mo合金渗层在单相流和双相流冲刷腐蚀条件下,在Na Cl腐蚀介质中的耐蚀性能。结果表明:Ti6Al4V基体经过W-Mo共渗处理后,在其表面形成了厚度约为25.0μm的合金改性层。合金层由Al MoTi_2和Ti_xW_(1-x)相组成。改性层的显微硬度高达850 HV0.1,较基体(450 HV0.1)显著提高,改性层的平均摩擦系数也从基体的0.30降到0.14。W-Mo合金渗层良好的表面力学性能有效的保护了基体材料不受外力的冲刷,在单相流冲蚀下,W-Mo合金渗层的腐蚀速度只是基体Ti6Al4V的1/19;在双相流冲蚀条件下,只是基体Ti6Al4V的1/37。
关键词(KeyWords): Ti6Al4V合金;辉光放电;共渗层;冲刷腐蚀
基金项目(Foundation): 北京石油化工学院优秀学科带头人培育计划(BIPTBPOAL-2013)
作者(Author): 赵云,张玉林,陈飞
DOI: 10.13289/j.issn.1009-6264.2015.s2.031
参考文献(References):
- [1]Leyens C,Peters M.Titanium and Titanium Alloy[M].Translated by Chen Zhenhua.Beijing:Chemical Industry Press,2005.
- [2]周廉,赵永庆,王向东,等.中国钛合金材料及应用发展战略研究[M].北京:化学工业出版社,2012.
- [3]蒋成禹,徐济进,严铿,等.俄罗斯海军用钛情况及我们的思考[J].钛工业进展,2003,20(6):32-36.JIANG Cheng-yu,XUE Ji-jin,YAN Keng,et al.Titanium application for navy in Russia and our suggestions[J].Titanium Industry Progress,2003,20(6):32-36.
- [4]李争显,刘瑞斌,华云峰,等.钛表面薄膜技术的应用现状及发展[J].钛工业进展,2014,31(1):1-5.LI Zheng-xian,LIU Rui-bin,HUA Yun-feng,et al.Progress in research of film technology for titanium alloys[J].Titanium Industry Progress,2014,31(1):1-5.
- [5]Pang W,Man H C,Yue T M.Laser surface coating of Mo-WC metal matrix composite on Ti6Al4V alloy[J].Materials Science and Engineering,2005,390(4):144-153.
- [6]Avelar-Batista J C,Spain E,Fuentes G G,et al.Triode plasma nitriding and PVD coating:A successful pre-treatment combination to improve the wear resistance of DLC coatings on Ti6Al4V alloy[J].Surface and Coatings Technology,2006,201(7):4335-4340.
- [7]李争显,周廉,徐重.等离子钛表面冶金技术[J].稀有金属快报,2004,23(2):26-28.LI Zheng-xian,ZHOU Lian,XU Zhong.Titanium plasma surface metallurgy technology[J].Rare Metals Letters,2004,23(2):26-28.
- [8]高原,张维,王成磊,等.W-Mo-Y等离子共渗合金层的研究[J].材料热处理学报,2011,32(7):130-133.GAO Yuan,ZHANG Wei,WANG Cheng-lei,et al.Research on W-Mo-Y co-diffusion alloy layer prepared by plasma surface alloying process[J].Transactions of Materials and Heat Treatment,2011,32(7):130-133.
- [9]陈飞,周海,潘俊德.钛合金表面辉光等离子渗钽的研究[J].材料热处理学报,2009,30(4):156-159.CHEN Fei,ZHOU Hai,PAN Jun-de.Study on double-glow discharge plasma tantalizing on titanium alloy surface[J].Transactions of Materials and Heat Treatment,2009,30(4):156-159.
- [10]王健云,周育英,周清木,等.工业纯钛和00Cr25Ni22Mo2不锈钢的冲刷腐蚀[J].中国腐蚀与防护学报,2000,20(2):123-127.WANG Jian-yun,ZHOU Yu-ying,ZHOU Qing-mu,et al.Study on erosion-corrosion of titanium and 00Cr25Ni22Mo2 stainless steel[J].Journal of Chinese Society for Corrosion and Protection,2000,20(2):123-127.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||