再生屑料制备Al-Ti-B-Ce晶粒细化剂及其细化效果Preparation of Al-Ti-B-Ce grain refiner from recycled chips and its refinement effect
叶翔,赵春芳,余果,刘桐,王飞,胡茂良,吉泽升
摘要(Abstract):
利用机械加工产生的铝屑和TC4(Ti6Al4V)屑为主要原料,采用熔体反应法制备了Al-5Ti-1B-1Ce铝合金用晶粒细化剂,研究熔炼的反应温度和反应时间对Al-Ti-B-Ce微观组织和细化效果的影响。结果表明:制备的Al-5Ti-1B-1Ce晶粒细化剂主要由α-Al、Ti Al_3、Ti_2Al_(20)Ce和Ti B_2构成;随着反应温度的升高,Ti Al_3和Ti_2Al_(20)Ce由块状逐渐向针状转变,直至1000℃几乎全部转变为针状相;Al-5Ti-1B-1Ce的最优制备工艺为在950℃条件下反应60min,添加0.3mass%的Al-5Ti-1B-1Ce可将纯铝平均晶粒尺寸由3000μm细化至185.2μm。
关键词(KeyWords): 铝合金;屑料;晶粒细化;稀土;Al-Ti-B
基金项目(Foundation): 丽水职业技术学院2023年度科研之星人才专项基金(LZRC202406)
作者(Author): 叶翔,赵春芳,余果,刘桐,王飞,胡茂良,吉泽升
DOI: 10.13289/j.issn.1009-6264.2024-0459
参考文献(References):
- [1]史宝良,刘旭亮,孙震,等.乘用车白车身铝合金压铸结构件及材料应用研究进展[J].汽车工艺与材料,2022(12):1-9.SHI Bao-liang,LIU Xu-liang,SUN Zhen,et al. Progress of application research on aluminum structural die casting and materials for passenger car body-in-white[J]. Automobile Technology&Material,2022(12):1-9.
- [2]曹玉凤,郭望,李亨,等.铝合金在汽车轻量化中的研发应用及发展[J].汽车工程学报,2024(10):1-11.CAO Yu-feng,GUO Wang,LI Heng,et al. Research application and development of aluminum alloy in automobile lightweight[J].Chinese Journal of Automotive Engineering,2024(10):1-11.
- [3]曹遴,陈彪,贾振东,等.铝基复合材料研究进展及其航空航天应用[J].铸造技术,2023,44(8):685-705.CAO Lin,CHEN Biao,JIA Zhen-dong,et al. Research progress and aerospace applications of aluminum matrix composite[J].Foundry Technology,2023,44(8):685-705.
- [4]韩逸,钱维锋,朱雯,等.废铝绿色低碳回收利用研究进展与挑战[J].轻合金加工技术,2022,50(10):1-10.HAN Yi,QIAN Wei-feng,ZHU Wen,et al. Research progress and challenges in green and low-carbon recycling of aluminum scraps[J]. Light Alloy Fabrication Technology,2022,50(10):1-10.
- [5]李若宇,王耀武,郭不拘,等.废铝回收再利用的研究现状[J].中国有色冶金,2024,53(4):84-93.LI Ruo-yu,WANG Yao-wu,GUO Bu-ju,et al. Research status of scrap aluminum recycling[J]. China Nonferrous Metallurgy,2024,53(4):84-93.
- [6] Lu X,Zhang Z Y,Hiraki T,et al. A solid-state electrolysis process for upcycling aluminium scrap[J]. Nature,2022,606(7914):511-515.
- [7]李彤,苏松林,安邦,等.高性能低成本钛合金生产应用现状[J].特钢技术,2024,30(3):8-11.LI Tong,SU Song-lin,AN Bang,et al. Current status of production and application of high-performance and low-cost titanium alloys[J]. Special Steel Technology,2024,30(3):8-11.
- [8]洪权,郭萍,周伟.钛合金成形技术与应用[J].钛工业进展,2022,39(5):27-32.HONG Quan,GUO Ping,ZHOU Wei. Forming technique and application of titanium alloy[J]. Titanium Industry Progress,2022,39(5):27-32.
- [9]商国强,王新南,雷云清,等.低成本钛合金在车辆上的工程应用研究[J].现代交通与冶金材料,2024,4(1):75-80.SHANG Guo-qiang,WANG Xin-nan,LEI Yun-qing,et al. Research on engineering application of low cost titanium alloy in vehicle fields[J]. Modern Transportation and Metallurgical Materials,2024,4(1):75-80.
- [10]崔云先,曹凯迪,王浩宇,等.铣削钛合金最高温度及其影响因素研究[J].大连交通大学学报,2023,44(2):50-54.CUI Yun-xian,CAO Kai-di,WANG Hao-yu,et al. Research on maximum temperature of milling titanium alloy and its influencing factors[J]. Journal of Dalian Jiaotong University,2023,44(2):50-54.
- [11]华小珍,彭新元,周贤良,等.热氢处理对TC4钛合金切削加工性的影响[J].材料热处理学报,2011,32(4):43-46.HUA Xiao-zhen,PENG Xin-yuan,ZHOU Xian-liang,et al. Effect of thermohydrogen treatment on machinability of TC4 titanium alloy[J]. Transactions of Materials and Heat Treatment,2011,32(4):43-46.
- [12]刘杰,华俊芳,段慧珍,等. Ti Al Si N/Cr Al Si N纳米多层涂层刀具干切削TC4钛合金切削性能[J].宇航材料工艺,2024,54(4):103-109.LIU Jie,HUA Jun-fang,DUAN Hui-zhen,et al. Cutting performance of Ti Al Si N/Cr Al Si N nano-multilayer coated tools during dry cutting of TC4 titanium alloy[J]. Aerospace Materials&Technology,2024,54(4):103-109.
- [13]杨光,文胜平,雷志国,等.铝合金细化剂细化行为研究现状与展望[J].铸造,2024,73(4):445-452.YANG Guang,WEN Sheng-ping,LEI Zhi-guo,et al. Research status and prospect of refining behavior of aluminum alloy refiners[J]. Foundry,2024,73(4):445-452.
- [14]丁万武,祝江涛,赵文军,等. Al-5Ti-B合金的微观组织演变及其对纯铝的细化作用[J].材料热处理学报,2014,35(S2):40-45.DING Wan-wu,ZHU Jiang-tao,ZHAO Wen-jun,et al. Microstructure evolution and refining performances of Al-5Ti-B alloy on pure aluminum[J]. Transactions of Materials and Heat Treatment,2014,35(S2):40-45.
- [15] Liu G Y, Ren Y S, Ma W H, et al. Development process and future trends of chemical refining agents’ influence on grain refinement in aluminum alloys[J]. Journal of Materials Research and Technology,2024,29:242-257.
- [16] Fan Z,Wang Y,Zhang Y,et al. Grain refining mechanism in the Al/Al-Ti-B system[J]. Acta Materialia,2015,84:292-304.
- [17]黄俊辉,孙明,张燕艳,等. Al-Ti-B在Al-Si合金中的晶粒细化行为的研究进展[J].有色金属材料与工程,2022,43(5):47-60.HUANG Jun-hui,SUN Ming,ZHANG Yan-yan,et al. Research progress of grain refinement behavior of Al-Ti-B in Al-Si alloys[J]. Nonferrous Metal Materials and Engineering,2022,43(5):47-60.
- [18]孙雪迎. Al-Ti-B、Al-Ti-C中间合金细化铝及铝合金机制研究[D].北京:清华大学,2011.SUN Xue-ying. Study on refinement mechanism of Al-Ti-B and Al-Ti-C master alloys in aluminum and its alloys[D]. Beijing:Tsinghua University,2011.
- [19] Wang K,Cui C X,Wang Q,et al. The microstructure and formation mechanism of core-shell-like Ti Al3/Ti2Al20Ce in melt-spun AlTi-B-Re grain refiner[J]. Materials Letters,2012,85:153-156.
- [20] Chen Z Q,Hu W X,Shi L,et al. Effect of rare earth on morphology and dispersion of Ti B2 phase in Al-Ti-B alloy refiner[J]. China Foundry,2023,20(2):115-124.
- [21] Li Y,Hu B,Liu B,et al. Insight into Si poisoning on grain refinement of Al-Si/Al-5Ti-B system[J]. Acta Materialia,2020,187:51-65.
- [22] Qian P P,Tang Z H,Yuan M W,et al. Microstructure and refinement mechanism of Ti B2/Ti Al3in remelted Al-5Ti-1B system[J].Materials Science and Technology,2019,35(13):1563-1571.
- [23]李洋,郭绪强,许磊,等. Al-5Ti-1B合金显微组织与细化机理[J].粉末冶金技术,2022,40(3):251-257.LI Yang,GUO Xu-qiang,XU Lei,et al. Microstructure and refinement mechanism of Al-5Ti-1B alloys[J]. Powder Metallurgy Technology,2022,40(3):251-257.
- [24] Robert F. On the critical radius in ostwald ripening[J]. Langmuir:The ACS Journal of Surfaces&Colloids,2004,20(7):2975-2976.
- [25]王飞. Al屑和Ti屑制备Al-5Ti-0. 25C-1Ce晶粒细化剂工艺及细化效果研究[D].哈尔滨:哈尔滨理工大学,2022.WANG Fei. Preparation of Al-5Ti-0. 25C-1Ce grain refiner from Al and Ti chips and its refining effect[D]. Harbin:Harbin University of Science and Technology,2022.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||