内晶结构复相陶瓷的裂纹扩展行为Crack extension behavior of intragranular ceramic composites
王昕,于薛刚,单妍,刘子峰,尹衍升
摘要(Abstract):
以ZrO2-Al2O3微-纳米复合陶瓷为研究对象,采用跟踪压痕裂纹法测试其裂纹扩展阻力曲线。结果表明,三种微-纳复合ZTA陶瓷的阻力曲线均为显著的上升曲线。成分相同、烧结温度高的试样和烧结温度相同、氧化锆含量少的试样,由于内晶颗粒数量多,阻力曲线的上升趋势更加明显。内晶颗粒附近区域产生位错网、亚晶界甚至微裂纹,使微-纳米复合ZTA陶瓷的断裂方式向穿晶断裂方向变化。裂纹穿晶扩展遇到的阻力大,所需要的裂纹扩展动力也大,形成开裂-止裂交替进行的裂纹扩展过程,故其阻力曲线上升明显。
关键词(KeyWords): 复相陶瓷;ZTA陶瓷;阻力曲线;裂纹扩展
基金项目(Foundation): 国家自然科学基金项目(50542032);; 山东省自然科学基金项目(Y2005F15)
作者(Author): 王昕,于薛刚,单妍,刘子峰,尹衍升
参考文献(References):
- [1]王昕,孙康宁,尹衍升,等.纳米复合陶瓷材料研究进展[J].复合材料学报,1999,16(1):105-110.WANG Xin,SUN Kang-ning,YIN Yan-sheng,et al.Progress of study on ceramic-matrix nanocomposites[J].Acta Materiae Compositae Sinica,1999,16(1):105-110.
- [2]Kathleen B,Alexander,Paul F,et al.Grain growth kinetics in alumina-zirconia(CeZTA)composites[J].Journal of the American Ceramic Society,1994,77(4):939-946.
- [3]Niihara K J.New design concept of structural ceramics:ceramic nano-composites[J].Journal of the American Ceramic Society,1992,75(9):2363-2372.
- [4]王昕,李镇江,杨丰科,等.单分散纳米水合氧化锆的制备[J].化工学报,1999,50(4):519-523.WANG Xin,LI Zhen-jiang,YANG Feng-ke,et al.Preparation of monodispersed hydrous-zirconia nanoparticles[J].Journal of Chemical Industry andEngineering,1999,50(4):519-523.
- [5]王昕,尹衍升,李镇江,等.溶胶-悬浮液混合制备ZrO2(n)-Al2O3纳米复合陶瓷[J].化工学报,1999,50(3):362-366.WANG Xin,YIN Yan-sheng,LI Zhen-jiang,et al.Preparation of ZrO2(n)-Al2O3ceramic nanocmposite by mixing sol with aqueous suspension[J].Journalof Chemical Industry and Engineering,1999,50(3):362-366.
- [6]王昕,张景德,孙康宁,等.均分散纳米复合陶瓷材料制备工艺[J].复合材料学报,1999,16(3):83-87.WANG Xin,ZHANG Jing-de,SUN Kang-ning,et al.Preparation of uniformly mixed ceramic nanocomposites[J].Acta Materiae Compositae Sinica,1999,16(3):83-87.
- [7]Raddatz O,Schneider G A,Mackens W.Bridging stresses and r-curves in ceramics/metal composites[J].Journal of the European Ceramic Society,2000,20:2261-2273.
- [8]Li C W,Lee D J,Lui S C.R-curve behavior and strength for In-situ reinforced silicon nitrides with different microstrcture[J].Journal of the AmericanCeramic Society,1992,75(7):1777-1785.
- [9]Wang Y L,Anandakumar U,Singh R N.Effect of fiber bridging stress on the fracture resistance of silicon-carbide-fiber/Zircon composites[J].Journal of theAmerican Ceramic Society,2000,83(5):1207-1214.
- [10]Meschke F,Raddatz O,Kolleck A,et al.R-curve behavior and crack-closure stresses in barium titanate and(Mg,Y)-PSZ ceramics[J].Journal of theAmerican Ceramic Society,2000,83(2):353-361.
- [11]王昕,单妍,于薛刚,等.纳米ZrO2-微米Al2O3复合陶瓷中“内晶型”结构的形成与机理[J].硅酸盐学报,2003,31(12):1145-1149.WANG Xin,SHAN Yan,YU Xue-gang,et al.Formation and mechanism of intragranular structure in zirconia toughened alumina ceramics with nano-ZrO2and micro Al2O3[J].Journal of the Chinese Ceramic Society,2003,31(12):1145-1149.
- [12]单妍,王昕,于薛刚,等.Al2O3-ZrO2陶瓷体系中晶粒生长模型的研究[J].硅酸盐学报,2003,31(3):278-282.SHAN Yan,WANG Xin,YU Xue-gang,et al.Study on grain growth model in Al2O3-ZrO2ceramic composites[J].Journal of the Chinese Ceramic Society,2003,31(3):278-282.
- [13]龚江宏.陶瓷材料断裂力学[M].北京:清华大学出版社,2001:253-254.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||