基于介电泳微流控技术的碳纳米管分离Separation of carbon nanotubes by dielectrophoresis based on microfluidics
王小冲,安立宝,徐玉坤,龚亮
摘要(Abstract):
介电泳微流控分离碳纳米管是利用在外加特定频率非均匀交变电场的流动介电液中,金属型和半导体型碳纳米管由于自身电学性能不同受到不同介电泳力,进而向不同方向运动实现分离。建立了分离碳纳米管的介电泳数学模型和微流控分离通道及电极几何模型,并对分离过程进行了仿真研究。依据碳纳米管及介电液的电导率和介电常数,确定分离所用的电场频率为1010Hz,由此获得了分离通道内的电场、流场分布和碳纳米管分离运动轨迹。通过研究入口流速和电压变化对分离结果的影响,得出了使碳纳米管成功分离的入口流速和电压的合理参数组合,可指导碳纳米管实际分离过程以缩短分离时间,有利于推进基于单一电学特性碳纳米管在微纳器件中的应用进程。
关键词(KeyWords): 介电泳;微流控;碳纳米管;分离;仿真
基金项目(Foundation): 国家自然科学基金(51172062;51472074);; 河北省引进海外高层次人才“百人计划”资助(E2012100005)
作者(Author): 王小冲,安立宝,徐玉坤,龚亮
DOI: 10.13289/j.issn.1009-6264.2015.s2.038
参考文献(References):
- [1]徐二阳,王昆林,韦进全,等.渐变掺氮碳纳米管场的发射性能[J].材料热处理学报,2011,32(2):1-4.XU Er-yang,WANG Kun-lin,WEI Jin-quan,et al.Field emission property of gradiently nitrogen-doped carbon nanotubes[J].Transactions of Materials and Heat Treatment,2011,32(2):1-4.
- [2]Lee M,Im J,Lee B Y,et al.Linker-free directed assembly of high-performance integrated devices based on nanotubes and nanowires[J].Nature Nanotechnology,2006,1(1):66-71.
- [3]李刚,余宗胜,徐先锋.热CVD制备定向竹节型碳纳米管生长机制分析[J].材料热处理学报,2015,36(6):1-4.LI Gang,YU Zong-sheng,XU Xian-feng.Growth mechanism of aligned bamboo-like CNTs prepared by thermal CVD[J].Transactions of Materials and Heat Treatment,2015,36(6):1-4.
- [4]Hong G,Zhou M,Zhang R,et al.Separation of metallic and semiconducting single-walled carbon nanotube arrays by“scotch tape”[J].Angewandte Chemie,2011,50(30):6819-6823.
- [5]Collins P G,Arnold M S,Avouris P.Engineering carbon nanotubes and nanotube circuits using electrical breakdown[J].Science,2001,292(5517):706-709.
- [6]Li H,Zhou B,Lin Y,et al.Selective interactions of porphyrins with semiconducting single-walled carbon nanotubes[J].Journal of the American Chemical Society,2004,126(4):1014-1015.
- [7]Kim K S,Bae D J,Kim J R,et al.Modification of electronic structures of a carbon nanotube by hydrogen functionalization[J].Advanced Materials,2002,14(24):1818-1821.
- [8]Shin D H,Kim J E,Shim H C,et al.Continuous extraction of highly pure metallic single-walled carbon nanotubes in a microfluidic channel[J].Nano Letters,2008,8(12):4380-4385.
- [9]Oliva A.Dielectrophoretic modeling of the dynamic carbon nanotube network formation in viscous media under alternating current electric fields[J].Carbon,2014,69(4):342-354.
- [10]Cui H,Voldman J,He X,et al.Separation of particles by pulsed dielectrophoresis[J].Lab on A Chip,2009,9(16):2306-2312.
- [11]刘顺东,张鸿雁,沈萍,等.基于介电电泳的微尺度颗粒分离研究进展[J].微纳电子技术,2012,49(4):268-279.LIU Shun-dong,ZHANG Hong-yan,SHEN Ping,et al.Research progress on the microscale particle separation by dielectrophoresis[J].Micronanoelectronic Techology,2012,49(4):268-279.
- [12]Asokan S B,Jawerth L,Carroll R L,et al.Two-dimensional manipulation and orientation of actin-myosin systems with dielectrophoresis[J].Nano Letters,2003,3(4):431-437.
- [13]任玉坤,敖宏瑞,顾建忠,等.面向微系统的介电泳力微纳粒子操控研究[J].物理学报,2009,58(11):7869-7877.REN Yu-kun,AO Hong-rui,GU Jian-zhong,et al.Microparticles manipulation based on dielectrophoresis in microsystem[J].Acta Physica Sinica,2009,58(11):7869-7877.
- [14]Castellanos A,Ramos A,González A,et al.Electrohydrodynamics and dielectrophoresis in microsystems:scaling laws[J].Journal of Physics D Applied Physics,2003,36(20):2584-2597.
- [15]刘德利.基于介电电泳微流控的微粒子连续分离技术研究[D].哈尔滨:哈尔滨工业大学,2012.LIU De-li.Micro particle continuous separation technology research based on dielectric electrophoresis microfluidic[D].Harbin:Harbin Institute of Technology,2012.
- [16]Kim J E,Han C S.Use of dielectrophoresis in the fabrication of an atomic force microscope tip with a carbon nanotube:a numerical analysis[J].Nanotechnology,2005,16(10):2245-2250.
- [17]贾延凯.基于新型3D电极的介电泳微粒分离微流控芯片研究[D].哈尔滨:哈尔滨工业大学,2014.JIA Yan-kai.Microfluidic chip for dielectrophoretic separation of particles based on novel 3D electrodes[D].Harbin:Harbin Institute of Technology,2014.
- [18]An L,Friedrich C R.Process parameters and their relations for the dielectrophoretic assembly of carbon nanotubes[J].Journal of Applied Physics,2009,105(7):367-373.
- [19]Oliva-Avilés A I,Avilés F,Sosa V,et al.Dynamics of carbon nanotube alignment by electric fields[J].Nanotechnology,2012,23(46):465710-465719.
- [20]Burg B R,Bianco V,Schneider J,et al.Electrokinetic framework of dielectrophoretic deposition devices[J].Journal of Applied Physics,2010,107(12):124308-124308.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||