氮氢比对AISI 9310齿轮钢渗氮层组织和性能的影响Effect of nitrogen-to-hydrogen ratio on microstructure and properties of nitrided layer on AISI 9310 gear steel surface
孙忠武,李富霖,刘瑞良,吴新宇
摘要(Abstract):
在不同氮氢比下,对AISI 9310齿轮钢进行440℃渗氮处理12 h。利用X射线衍射仪、光学显微镜和扫描电镜等对渗氮层的组织结构进行表征,利用维氏硬度仪、球-盘式摩擦磨损试验机、电化学工作站等对渗氮层硬度、耐磨性和耐蚀性能进行测试和评价。结果表明:渗氮层主要由ε-Fe_(2-3)N、γ-Fe_4N以及含N的过饱和α-Fe相(α_N)组成;随着氮氢比的减小,ε-Fe_(2-3)N相逐渐减少;在不同氮氢比下渗氮试样的表面硬度均在1000 HV0.05左右,有效硬化层厚度均在100μm以上,其中氮氢比为1∶1和1∶3时,有效硬化厚度约为150μm,而氮氢比为1∶5时,有效硬化层厚度可达175μm;经过渗氮处理后,齿轮钢的耐磨性和耐蚀性均得到了显著提升,其中耐磨性最佳的渗氮试样的氮氢比为1∶3,其主要磨损机理是磨粒磨损,其次是氮氢比为1∶5时的渗氮试样,其主要磨损机理是磨粒磨损和黏着磨损;耐腐蚀性能最佳的渗氮试样为氮氢比为1∶1,其次为氮氢比为1∶5。表明可以采用渗氮替代常规渗碳对AISI 9310齿轮钢进行表面改性,并有效提升其综合性能。
关键词(KeyWords): AISI 9310齿轮钢;等离子体渗氮;氮氢比;组织结构;性能
基金项目(Foundation): 国家自然科学基金(52371060);; 黑龙江省自然科学基金(LH2023E060)
作者(Author): 孙忠武,李富霖,刘瑞良,吴新宇
DOI: 10.13289/j.issn.1009-6264.2024-0309
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