Ti含量对耐蚀铜合金冲蚀性能的影响Effect of Ti content on erosion properties of corrosion-resistant copper alloy
乔景振,田保红,张毅,周延军,国秀花,宋克兴
摘要(Abstract):
采用MCF-30型冲蚀磨损试验机,对不同钛含量的耐蚀铜合金在含砂的人工海水中进行冲蚀试验。冲蚀试验前后利用电子分析天平对冲蚀试样称重,利用扫描电镜和透射电镜分析冲蚀试样的冲蚀形貌、微观组织和冲蚀机理,在320HBS-3000型数显布氏硬度计上测量合金硬度。结果表明:添加Ti能显著提高合金在人工海水砂浆冲蚀条件下的冲蚀抗力,其冲蚀机理为砂粒的微切削与人工海水腐蚀综合作用机制;当钛含量为2.0%时,合金的耐冲蚀性能最好;在冲蚀速度为8.79 m·s-1,冲蚀角度为90°时,未加入Ti的合金表面腐蚀特征明显,出现了短的微切削沟槽、砂粒冲击坑及较粗大颗粒硬质相剥落坑;加入0.5%Ti的合金的冲蚀表面出现了较多的犁耕状沟槽和鱼鳞状剥落坑;加入2.0%Ti的合金的冲蚀表面腐蚀明显减轻,冲蚀表面沟槽较浅且比较窄。
关键词(KeyWords): 耐蚀铜合金;冲蚀机理;腐蚀特征;微切削;沟槽
基金项目(Foundation): 国家重点研发计划基金(2016YFB0301400)
作者(Author): 乔景振,田保红,张毅,周延军,国秀花,宋克兴
DOI: 10.13289/j.issn.1009-6264.2017-0554
参考文献(References):
- [1]Daroonparvar M R,Mazar Atabaki M,Vakilipour A.Effect of pre-heat treatment on corrosion behavior of nickel-aluminum bronze alloy[J].Association of Metallurgical Engineers of Serbia,2011,17(4):183-198.
- [2]Bohm J,Linhardt P,Strobl S,et al.Microstructure of a heat treated nickel-aluminum bronze and its corrosion behavior in simulated fresh and sea water[J].Materials Performance and Characterization,2016,5(5):689-700.
- [3]苏娟华,张国军.引线框架铜合金材料与Sn Ag3.0Cu0.5的界面组织[J].材料热处理学报,2011,32(3):25-29.SU Juan-hua,ZHANG Guo-jun.Microstructure of the interfaces between copper alloys for lead frame and Sn Ag3.0Cu0.5 solder alloys[J].Transactions of Materials and Heat Treatment,2011,32(3):25-29.
- [4]孙慧丽,张毅,柴哲,等.Cu-Zr-Nb合金的时效强化和析出动力学[J].材料热处理学报,2016,37(9):86-91.SUN Hui-li,ZHANG Yi,CHAI Zhe,et al.Aging strengthening and precipitation kinetics of Cu-Zr-Nd alloy[J].Transactions of Materials and Heat Treatment,2016,37(9):86-91.
- [5]徐春园,张思成.合金元素对铝青铜组织和性能的影响[J].甘肃科技,2007,23(4):128-129.XU Chun-yuan,ZHANG Si-cheng.Effect of alloying elements on microstructure and properties of aluminium bronze[J].Gansu Science and Technology,2007,23(4):128-129.
- [6]Heydarzadeh S M,Hojjatzadeh S M H,Khodayar A,et al.Liquid phase surface alloying of a nickel aluminum bronze alloy with titanium[J].Surface and Coatings Technology,2017,325(25):617-626.
- [7]Perkins J,Graham K J,Storm G A.Flow effects on corrosion of galvanic couples in sea water[J].Corrosion,1979,35:23-29.
- [8]天华化工机械及自动化研究设计院.腐蚀与防护手册[M].北京:化学工业出版社.2009:288-289.
- [9]张强,余新泉,王书强,等.钛含量对低镍合金显微组织和性能的影响[J].机械工程材料,2014,38(10):9-15.ZHANG Qiang,YU Xin-quan,WANG Shu-qiang,et al.Influence of Ti content on microstructure and properties of low-nickel copper alloy[J].Materials for Mechanical Engineering,2014,38(10):9-15.
- [10]Anees A,Khadom,Aprael S,et al.Mass transfer effect on corrosion inhibition process of copper-nickel alloy in hydrochloric acid by benzotriazole[J].Journal of Saudi Chemical Society,2014,18:214-219.
- [11]田保红.高速电弧喷涂Fe3Al/WC复合涂层高温冲蚀行为研究[D].沈阳:中国科学院金属研究所,2000.TIAN Bao-hong.Solid particle erosion of high velocity wire arc sprayed Fe3Al-based cermet coatings at elevated temperature[D].Shenyang:Institute of Metal Research,Chinese Academy of Sciences,2000.
- [12]李平.酸性液固两相流中不锈钢冲刷腐蚀行为的研究[D].武汉:华中科技大学,2006.LI Ping.Study on erosion corrosion behavior of stainless steel in acid liquid solid two phase flow[D].Wuhan:Huazhong University of Science and Technology,2006.
- [13]丁红燕,戴振东.TC11钛合金在人造海水中的腐蚀磨损特性研究[J].摩擦学学报,2008,28(2):139-144.DING Hong-yan,DAI Zhen-dong.Corrosion wear characteristic of TC11 alloy in artifical sea water[J].Tribology,2008,28(2):139-144.
- [14]郝贠洪,邢永明,杨诗婷.风沙环境下钢结构表面涂层冲蚀行为与侵蚀机理研究[J].摩擦学学报,2010,30(1):26-31.HAO Yun-hong,XING Yong-ming,YANG Shi-ting.Erosion-wear behavior of steel structure coating subject to sandstorm[J].Tribology,2010,30(1):26-31.
- [15]李涌泉,谢发勤,周俊,等.DZ125高温合金表面激光熔覆Co基合金的组织和冲蚀性能研究[J].摩擦学学报,2010,30(1):53-56.LI Yong-quan,XIE Fa-qin,ZHOU Jun,et al.Microstructure and erosion behavior of laser cladding Co-based alloy on DZ125 super alloy[J].Tribology,2010,30(1):53-56.
- [16]郝贠洪,李永.风沙环境下钢结构低角度冲蚀特性研究[J].摩擦学学报,2013,33(4):343-347.HAO Yun-hong,LI Yong.Erosion-wear behaviors of the coating on steel struceure eroded at low erosion-angle in sandstorm[J].Tribology,2013,33(4):343-347.
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